公开(公告)号：US20180273463A1

公开(公告)日：2018-09-27

申请号：US15996394

申请日：2018-06-01

Applicant: UOP LLC

Inventor： Raelynn M. Miller ,  Alakananda Bhattacharyya ,  David S. Lafyatis ,  Amanda L. Stolarski ,  Rodrigo Lobo ,  Madan Bhasin

IPC: C07C51/487 ,  C07C51/255 ,  C07C63/26 ,  B01J23/44 ,  B01J27/224 ,  B01J21/06 ,  B01J35/10

CPC classification number: C07C51/487 ,  B01J21/06 ,  B01J23/44 ,  B01J27/224 ,  B01J35/006 ,  B01J35/1009 ,  B01J37/12 ,  B01J37/16 ,  B01J37/18 ,  C07C51/255 ,  C07C63/26

Abstract: Impure aromatic carboxylic acids such as are obtained by liquid phase oxidation of feed materials comprising aromatic compounds with substituent groups oxidizable to carboxylic acid groups, or comprising aromatic carboxylic acid and one or more aromatic carbonyl impurities that form hydrogenated species more soluble in aqueous solvents or with less color or color-forming tendencies than the aromatic carbonyl impurity, are purified to an aromatic carboxylic acid product with lower levels of impurities by a process comprising contacting an aqueous solution comprising the impure aromatic carboxylic acid with hydrogen at elevated temperature and pressure with an attrition-resistance, acid stable catalyst composition comprising at least one hydrogenation catalyst metal and a support comprising relatively high surface area of high porosity silicon carbide with low levels of iron and alkali metal impurities. The support may further contain titanium or rare earth metals.