公开(公告)号：US20050054865A1

公开(公告)日：2005-03-10

申请号：US10938604

申请日：2004-09-13

申请人： Ulrich Muller ,  Georg Krug ,  Peter Bassler ,  Hans-Georg Gobbel ,  Peter Rudolf ,  Joaquim Teles

发明人： Ulrich Muller ,  Georg Krug ,  Peter Bassler ,  Hans-Georg Gobbel ,  Peter Rudolf ,  Joaquim Teles

IPC分类号： C07D303/04 ,  B01J29/89 ,  B01J37/04 ,  C01B39/06 ,  C01B39/40 ,  C07B61/00 ,  C07D301/12 ,  C07D301/06 ,  B01J29/04 ,  B01J29/87

CPC分类号： C07D301/12 ,  B01J29/89

摘要： The present invention relates to the manufacture of solid materials or shaped bodies containing at least one zeolite and being at least partly crystalline. Furthermore, the present invention relates to the solid materials or shaped bodies as such and to the use of these materials for reactions of compounds having at least one C—C double bond with at least one hydroperoxide. Specifically, the present invention relates to a process for the manufacture of a solid material containing at least one zeolite and being at least partly crystalline, wherein the synthesis of the said solid material involves at least one partial step of contacting at least one transition metal oxide source with at least one epoxide or hydrolysate thereof prior to or during the at least partial crystallization of said solid material.

公开(公告)号：US20070043226A1

公开(公告)日：2007-02-22

申请号：US10555961

申请日：2004-05-10

申请人： Ulrich Muller ,  Georg Krug ,  Peter Rudolf ,  Joaquim Teles ,  Hans-Georg Gobbel ,  Peter Bassler

发明人： Ulrich Muller ,  Georg Krug ,  Peter Rudolf ,  Joaquim Teles ,  Hans-Georg Gobbel ,  Peter Bassler

IPC分类号： C07D301/19

CPC分类号： C07D301/12 ,  Y02P20/52

摘要： Process for preparing propylene oxide, which comprises at least the steps (i) and (ii): (i) providing a catalyst comprising at least one porous oxidic material; (ii) reacting propene with a hydroperoxide in at least one nitrile as solvent or in a solvent mixture comprising at least one nitrile in the presence of the catalyst of (i), wherein the at least one porous oxidic material is a zeolite which is assigned X-ray-crystallographically to the MWW type.

摘要翻译： 制备环氧丙烷的方法，其至少包括步骤（i）和（ii）：（i）提供包含至少一种多孔氧化物质的催化剂; （ii）使丙烯与至少一种腈作为溶剂中的氢过氧化物反应或在包含至少一种腈的溶剂混合物中，在（i）的催化剂存在下反应，其中所述至少一种多孔氧化物质是被分配的沸石 X射线晶体学到MWW型。

公开(公告)号：US20050085646A1

公开(公告)日：2005-04-21

申请号：US10960989

申请日：2004-10-12

申请人： Ulrich Muller ,  Georg Krug ,  Peter Bassler ,  Hans-Georg Gobbel ,  Peter Rudolf ,  Joaquim Teles

发明人： Ulrich Muller ,  Georg Krug ,  Peter Bassler ,  Hans-Georg Gobbel ,  Peter Rudolf ,  Joaquim Teles

IPC分类号： B01J29/89 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  B01J37/10 ,  C07B61/00 ,  C07D301/03 ,  C07D301/12 ,  C07D301/19 ,  C07D303/04 ,  C01B33/36 ,  C01B39/00 ,  C01F7/00

CPC分类号： C07D301/19 ,  B01J29/89 ,  B01J37/10 ,  B01J2229/36 ,  B01J2229/40 ,  C07D301/12 ,  Y02P20/125

摘要： The present invention relates to a process for treating a solid material containing at least one zeolite and being at least partly crystalline or treating a shaped body obtained from said solid material wherein said solid material or shaped body is brought in contact with a composition containing water after at least one of the following steps of an integrated process for producing a solid material or a shaped body containing at least one zeolite: (i) after step (II) of separating the at least partly crystalline solid material from its mother liquor or (ii) after step (S) of shaping said solid material into a shaped body or (iii) after a step (C) of calcining said solid material or said shaped body. The present invention furthermore relates to the solid material obtainable by the inventive process and the shaped body obtainable by the inventive process. The present invention finally relates to the use of the solid material or the shaped body as mentioned above as a catalyst in chemical reactions, in particular in reactions of compounds containing at least one C—C double bond with at least one hydroperoxide.

摘要翻译： 本发明涉及一种用于处理含有至少一种沸石并且至少部分结晶的固体材料或处理由所述固体材料获得的成形体的方法，其中所述固体材料或成形体与含有水的组合物接触 用于生产固体材料或含有至少一种沸石的成形体的整合方法中的至少一个步骤：（i）在从母液中分离出至少部分结晶固体材料的步骤（II）之后，或（ii ）在将所述固体材料成形为成形体的步骤（S）之后或（iii）在煅烧所述固体材料或所述成形体的步骤（C）之后。 本发明还涉及可通过本发明方法获得的固体材料和通过本发明方法获得的成形体。 本发明最终涉及如上所述的固体材料或成形体作为化学反应中的催化剂，特别是在含有至少一个C-C双键的化合物与至少一种氢过氧化物的反应中的应用。

公开(公告)号：US20060167286A1

公开(公告)日：2006-07-27

申请号：US10526939

申请日：2003-09-16

申请人： Ulrich Mueller ,  Georg Krug ,  Peter Bassler ,  Hans-Georg Gobbel ,  Peter Rudolf ,  Joaquim Teles

发明人： Ulrich Mueller ,  Georg Krug ,  Peter Bassler ,  Hans-Georg Gobbel ,  Peter Rudolf ,  Joaquim Teles

IPC分类号： B01J29/04 ,  C07D301/19

CPC分类号： C07D301/19 ,  B01J29/89 ,  B01J37/10 ,  B01J2229/36 ,  B01J2229/40 ,  C07D301/12 ,  Y02P20/125

摘要： The present invention relates to a process for treating a solid material containing at least one zeolite and being at least partly crystalline or treating a shaped body obtained from said solid material wherein said solid material or shaped body is brought in contact with a composition containing water after at least one of the following steps of an integrated process for producing a solid material or a shaped body containing at least one zeolite: (i) after step (II) of separating the at least partly crystalline solid material from its mother liquor or (ii) after step (S) of shaping said solid material into a shaped body or (iii) after a step (C) of calcining said solid material or said shaped body. The present invention furthermore relates to the solid material obtainable by the inventive process and the shaped body obtainable by the inventive process. The present invention also relates to the use of the solid material or the shaped body as mentioned above as a catalyst in chemical reactions, in particular in reactions of compounds containing at least one C-C double bond with at least one hydroperoxide.

摘要翻译： 本发明涉及一种用于处理含有至少一种沸石并且至少部分结晶的固体材料或处理由所述固体材料获得的成形体的方法，其中所述固体材料或成形体与含有水的组合物接触 用于生产固体材料或含有至少一种沸石的成形体的整合方法中的至少一个步骤：（i）在从母液中分离出至少部分结晶固体材料的步骤（II）之后，或（ii ）在将所述固体材料成形为成形体的步骤（S）之后或（iii）在煅烧所述固体材料或所述成形体的步骤（C）之后。 本发明还涉及可通过本发明方法获得的固体材料和通过本发明方法获得的成形体。 本发明还涉及如上所述的固体材料或成形体作为化学反应中的催化剂，特别是在含有至少一个C-C双键的化合物与至少一种氢过氧化物的反应中的用途。

公开(公告)号：US20060205964A1

公开(公告)日：2006-09-14

申请号：US10553441

申请日：2004-04-16

申请人： Hans-Georg Gobbel ,  Peter Bassler ,  Joaquim Teles ,  Peter Rudolf

发明人： Hans-Georg Gobbel ,  Peter Bassler ,  Joaquim Teles ,  Peter Rudolf

IPC分类号： C07D301/03

CPC分类号： C07D301/12

摘要： Process for preparing propylene oxide, which comprises at least the steps (iii) and (iv) (iii) separating off propylene oxide from a mixture (M1) comprising propylene oxide and at least one solvent by distillation in a distillation column, giving a bottom stream and a vapor stream consisting essentially of propylene oxide; (iv) compressing the vapor stream obtained in (iii) by means of at least one compressor to give a compressed vapor.

摘要翻译： 制备环氧丙烷的方法，其至少包括步骤（iii）和（iv）（iii）通过在蒸馏塔中蒸馏从包含环氧丙烷和至少一种溶剂的混合物（M1）中分离环氧丙烷，得到底部 气流和基本上由环氧丙烷组成的蒸气流; （iv）通过至少一个压缩机压缩（iii）中获得的蒸气流，得到压缩蒸气。

公开(公告)号：US20060014969A1

公开(公告)日：2006-01-19

申请号：US10521790

申请日：2003-07-22

申请人： Peter Bassler ,  Hans-Georg Gobbel ,  Joaquim Teles ,  Peter Rudolf

发明人： Peter Bassler ,  Hans-Georg Gobbel ,  Joaquim Teles ,  Peter Rudolf

IPC分类号： C07D301/19

CPC分类号： C07D301/12 ,  Y02P20/582

摘要： Continuously operated process for the intermediate isolation of the oxirane formed by reaction of a hydroperoxide with an organic compound in the oxirane synthesis, wherein the product mixture formed in the synthesis is fractionated in a dividing wall column to give a low-boiling fraction, an intermediate-boiling fraction and a high-boiling fraction and the oxirane is taken off in the intermediate-boiling fraction at the side offtake and the hydroperoxide is taken off in the high-boiling fraction at the bottom of the column.

摘要翻译： 在环氧乙烷合成中通过氢过氧化物与有机化合物的反应形成的环氧乙烷的中间分离的连续操作方法，其中在合成中形成的产物混合物在分隔壁塔中分馏得到低沸点馏分，中间体 沸腾馏分和高沸点馏分，环氧乙烷在中间馏分馏出物的一侧取出，氢过氧化物在柱底部的高沸点馏分中取出。

公开(公告)号：US20060216216A1

公开(公告)日：2006-09-28

申请号：US11441153

申请日：2006-05-26

申请人： Peter Bassler ,  Hans-Georg Gobbel ,  Joaquim Teles ,  Peter Rudolf

发明人： Peter Bassler ,  Hans-Georg Gobbel ,  Joaquim Teles ,  Peter Rudolf

IPC分类号： B01J8/04 ,  C07C41/03

CPC分类号： B01D3/141 ,  B01D3/143 ,  C07C29/106 ,  C07D301/12 ,  C07C31/205

摘要： An apparatus for carrying out a continuous process for preparing propylene glycols.

摘要翻译： 用于进行用于制备丙二醇的连续方法的装置。

公开(公告)号：US20050250965A1

公开(公告)日：2005-11-10

申请号：US10521783

申请日：2003-07-22

申请人： Peter Bassler ,  Hans-Georg Gobbel ,  Joaquim Teles ,  Peter Rudolf

发明人： Peter Bassler ,  Hans-Georg Gobbel ,  Joaquim Teles ,  Peter Rudolf

IPC分类号： B01D3/14 ,  C07D301/32 ,  C07C29/74

CPC分类号： B01D3/141 ,  B01D3/143 ,  C07D301/32

摘要： The invention relates to a continuously operated process for the purification by distillation of the 1,2-propylene glycol formed as by-product in the synthesis of propylene oxide, wherein the mixture formed in the synthesis which contains the 1,2-propylene glycol is separated in a dividing wall column into low-, intermediate, and high-boiling fractions and the 1,2-propylene glycol is taken off as intermediate boiler at the side offtake of the column.

摘要翻译： 本发明涉及通过蒸馏在合成环氧丙烷中作为副产物形成的1,2-丙二醇进行纯化的连续操作方法，其中在含有1,2-丙二醇的合成中形成的混合物是 在分隔壁塔中分离成低，中和高沸点馏分，并将1,2-丙二醇作为塔的出料侧的中间锅炉取出。

公开(公告)号：US20050211541A1

公开(公告)日：2005-09-29

申请号：US10517368

申请日：2003-07-23

申请人： Peter Bassler ,  Hans-Georg Gobbel ,  Joaquim Teles ,  Peter Rudolf

发明人： Peter Bassler ,  Hans-Georg Gobbel ,  Joaquim Teles ,  Peter Rudolf

IPC分类号： B01D3/14 ,  B01D3/42 ,  C07D301/32 ,  B01D3/34

CPC分类号： B01D3/141 ,  B01D3/14 ,  B01D3/4222 ,  C07D301/32 ,  Y10S203/20

摘要： The invention relates to a continuously operated process for the purification by distillation of the oxirane formed in the oxirane synthesis by reaction of a hydroperoxide with an organic compound, wherein the crude oxirane is separated in a dividing wall column into low-, intermediate- and high-boiling fractions and the oxirane is taken off as intermediate boiler at the side offtake in a concentration of at least 99.9%.

摘要翻译： 本发明涉及通过氢过氧化物与有机化合物的反应蒸馏在环氧乙烷合成中形成的环氧乙烷进行纯化的连续操作方法，其中将粗环氧乙烷在分隔壁塔中分离成低，中，高 - 沸腾馏分，环氧乙烷作为中间锅炉在浓度为99.9％以上的出口侧取出。

公开(公告)号：US20050252762A1

公开(公告)日：2005-11-17

申请号：US10516939

申请日：2003-07-22

申请人： Peter Bassler ,  Hans-Georg Gobbel ,  Joaquim Teles ,  Peter Rudolf

发明人： Peter Bassler ,  Hans-Georg Gobbel ,  Joaquim Teles ,  Peter Rudolf

IPC分类号： C07D301/12 ,  B01D3/38

CPC分类号： B01D3/141 ,  C07D301/12

摘要： Continuously operated process for the purification by distillation of the methanol used as solvent in the synthesis of propylene oxide by reaction of a hydroperoxide with propylene, with the methoxypropanols, as azcotrope with water, and the low boilers and high boilers simultaneously being separated off, wherein the solvent mixture obtained in the synthesis is fractionated in a dividing wall column.

摘要翻译： 在氢过氧化物与丙烯的反应合成环氧丙烷中作为溶剂使用的甲醇与甲醇与水反应的惰性气体，同时分离低沸点锅炉和高锅炉，进行纯化的连续操作方法，其中 在合成中获得的溶剂混合物在分隔壁塔中分馏。