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    Continuously operable method for producing carbonyl compounds by means of a catalyst containing a nitroxyl radical
    4.
    发明授权
    Continuously operable method for producing carbonyl compounds by means of a catalyst containing a nitroxyl radical 有权
    通过含有硝酰自由基的催化剂生产羰基化合物的连续可操作的方法

    公开(公告)号：US08981159B2

    公开(公告)日：2015-03-17

    申请号：US14110450

    申请日：2011-12-06

    申请人： Florian Klasovsky ,  Thomas Haas ,  Thomas Tacke ,  Jan Christoph Pfeffer ,  Michael Rimbach ,  Michael Volland ,  Michiel Janssen ,  Roger Sheldon ,  Juergen Haberland

    发明人： Florian Klasovsky ,  Thomas Haas ,  Thomas Tacke ,  Jan Christoph Pfeffer ,  Michael Rimbach ,  Michael Volland ,  Michiel Janssen ,  Roger Sheldon ,  Juergen Haberland

    IPC分类号： C07C45/59 ,  C07D493/04

    CPC分类号： C07C45/59 ,  C07D493/04

    摘要： The invention relates to a method for the oxidation of a primary or secondary alcohol, preferably to form an aldehyde or ketone, comprising the following steps: a) providing a catalyst composition comprising at least one compound containing a nitroxyl radical, at least one NO source, at least one carbon or mineral acid or an anhydride of a carbon or mineral acid; b) producing a reaction mixture by adding at least one primary or secondary alcohol and a gas comprising oxygen and optionally one or more than one solvent to the catalyst composition from step a) or step e); c) incubating the reaction mixture from step b) at a temperature of between 0 and 100° C. or at the boiling point of the solvent; d) simultaneously with or subsequent to step c): crystallizing the reaction product; and e) recovering the catalyst composition by removing the crystallized reaction product from the reaction mixture obtained in step d).

    摘要翻译： 本发明涉及氧化伯醇或仲醇，优选形成醛或酮的方法，包括以下步骤：a）提供包含至少一种含有硝酰基的化合物的催化剂组合物，至少一种NO源 ，至少一种碳或无机酸或碳或无机酸的酸酐; b）通过从步骤a）或步骤e）向催化剂组合物中加入至少一种伯醇或仲醇和包含氧气和任选的一种或多种溶剂的气体产生反应混合物; c）在0-100℃的温度或溶剂的沸点下温育来自步骤b）的反应混合物; d）与步骤c）同时或之后步骤：使反应产物结晶; 和e）通过从步骤d）中获得的反应混合物中除去结晶的反应产物来回收催化剂组合物。

    CONTINUOUSLY OPERABLE METHOD FOR PRODUCING CARBONYL COMPOUNDS BY MEANS OF A CATALYST CONTAINING A NITROXYL RADICAL
    5.
    发明申请
    CONTINUOUSLY OPERABLE METHOD FOR PRODUCING CARBONYL COMPOUNDS BY MEANS OF A CATALYST CONTAINING A NITROXYL RADICAL 有权
    通过含有硝基吡咯的催化剂生产碳化合物的连续可操作方法

    公开(公告)号：US20140039223A1

    公开(公告)日：2014-02-06

    申请号：US14110450

    申请日：2011-12-06

    申请人： Florian Klasovsky ,  Thomas Haas ,  Thomas Tacke ,  Jan Christoph Pfeffer ,  Michael Rimbach ,  Michael Volland ,  Michiel Janssen ,  Roger Sheldon ,  Juergen Haberland

    发明人： Florian Klasovsky ,  Thomas Haas ,  Thomas Tacke ,  Jan Christoph Pfeffer ,  Michael Rimbach ,  Michael Volland ,  Michiel Janssen ,  Roger Sheldon ,  Juergen Haberland

    IPC分类号： C07C45/59

    CPC分类号： C07C45/59 ,  C07D493/04

    摘要： The invention relates to a method for the oxidation of a primary or secondary alcohol, preferably to form an aldehyde or ketone, comprising the following steps: a) providing a catalyst composition comprising at least one compound containing a nitroxyl radical, at least one NO source, at least one carbon or mineral acid or an anhydride of a carbon or mineral acid; b) producing a reaction mixture by adding at least one primary or secondary alcohol and a gas comprising oxygen and optionally one or more than one solvent to the catalyst composition from step a) or step e); c) incubating the reaction mixture from step b) at a temperature of between 0 and 100° C. or at the boiling point of the solvent; d) simultaneously with or subsequent to step c): crystallizing the reaction product; and e) recovering the catalyst composition by removing the crystallized reaction product from the reaction mixture obtained in step d).

    摘要翻译： 本发明涉及氧化伯醇或仲醇，优选形成醛或酮的方法，包括以下步骤：a）提供包含至少一种含有硝酰基的化合物的催化剂组合物，至少一种NO源 ，至少一种碳或无机酸或碳或无机酸的酸酐; b）通过从步骤a）或步骤e）向催化剂组合物中加入至少一种伯醇或仲醇和包含氧气和任选的一种或多种溶剂的气体产生反应混合物; c）在0-100℃的温度或溶剂的沸点下温育来自步骤b）的反应混合物; d）与步骤c）同时或之后步骤：使反应产物结晶; 和e）通过从步骤d）中获得的反应混合物中除去结晶的反应产物来回收催化剂组合物。