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公开(公告)号：US07740826B2
公开(公告)日：2010-06-22
申请号：US11585368
申请日：2006-10-24
申请人： Valery N. Khabashesku , Haiqing Peng , John L. Margrave , Mary Lou Margrave, legal representative , Wilbur Edward Billups , Yunming Ying
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/06 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10T428/25
摘要： A method for functionalizing the wall of single-wall or multi-wall carbon nanotubes involves the use of acyl peroxides to generate carbon-centered free radicals. The method allows for the chemical attachment of a variety of functional groups to the wall or end cap of carbon nanotubes through covalent carbon bonds without destroying the wall or endcap structure of the nanotube. Carbon-centered radicals generated from acyl peroxides can have terminal functional groups that provide sites for further reaction with other compounds. Organic groups with terminal carboxylic acid functionality can be converted to an acyl chloride and further reacted with an amine to form an amide or with a diamine to form an amide with terminal amine. The reactive functional groups attached to the nanotubes provide improved solvent dispersibility and provide reaction sites for monomers for incorporation in polymer structures. The nanotubes can also be functionalized by generating free radicals from organic sulfoxides.
摘要翻译： 用于官能化单壁或多壁碳纳米管的壁的方法涉及使用酰基过氧化物以产生碳中心的自由基。 该方法允许通过共价碳键将各种官能团化学连接到碳纳米管的壁或端盖上，而不破坏纳米管的壁或端帽结构。 由酰基过氧化物产生的碳中心基团可以具有提供与其它化合物进一步反应的位点的末端官能团。 具有末端羧酸官能团的有机基团可以转化为酰氯，并进一步与胺反应形成酰胺或与二胺反应以与末端胺形成酰胺。 连接到纳米管的反应性官能团提供改进的溶剂分散性，并为单体提供用于掺入聚合物结构的反应位点。 纳米管也可以通过产生有机亚砜的自由基来官能化。
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公开(公告)号：US20100222536A1
公开(公告)日：2010-09-02
申请号：US12778775
申请日：2010-05-12
申请人： Valery N. Khabashesku , Haiqing Peng , John L. Margrave , Mary Lou Margrave , Wilbur Edward Billups , Yunming Ying
发明人： Valery N. Khabashesku , Haiqing Peng , John L. Margrave , Mary Lou Margrave , Wilbur Edward Billups , Yunming Ying
IPC分类号： C08F210/00 , C07C409/30 , C07C317/04 , C07C55/12 , C07C43/11 , C08G18/00 , C08G63/00
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/06 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10T428/25
摘要： A method for functionalizing the wall of single-wall or multi-wall carbon nanotubes involves the use of acyl peroxides to generate carbon-centered free radicals. The method allows for the chemical attachment of a variety of functional groups to the wall or end cap of carbon nanotubes through covalent carbon bonds without destroying the wall or endcap structure of the nanotube. Carbon-centered radicals generated from acyl peroxides can have terminal functional groups that provide sites for further reaction with other compounds. Organic groups with terminal carboxylic acid functionality can be converted to an acyl chloride and further reacted with an amine to form an amide or with a diamine to form an amide with terminal amine. The reactive functional groups attached to the nanotubes provide improved solvent dispersibility and provide reaction sites for monomers for incorporation in polymer structures. The nanotubes can also be functionalized by generating free radicals from organic sulfoxides.
摘要翻译： 用于官能化单壁或多壁碳纳米管的壁的方法涉及使用酰基过氧化物以产生碳中心的自由基。 该方法允许通过共价碳键将各种官能团化学连接到碳纳米管的壁或端盖上，而不破坏纳米管的壁或端帽结构。 由酰基过氧化物产生的碳中心基团可以具有提供与其它化合物进一步反应的位点的末端官能团。 具有末端羧酸官能团的有机基团可以转化为酰氯，并进一步与胺反应形成酰胺或与二胺反应以与末端胺形成酰胺。 连接到纳米管的反应性官能团提供改进的溶剂分散性，并为单体提供用于掺入聚合物结构的反应位点。 纳米管也可以通过产生有机亚砜的自由基来官能化。
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公开(公告)号：US07976816B2
公开(公告)日：2011-07-12
申请号：US12778775
申请日：2010-05-12
申请人： Valery N. Khabashesku , Haiqing Peng , John L. Margrave , Mary Lou Margrave, legal representative , Wilbur Edward Billups , Yunming Ying
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/06 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10T428/25
摘要： A method for functionalizing the wall of single-wall or multi-wall carbon nanotubes involves the use of acyl peroxides to generate carbon-centered free radicals. The method allows for the chemical attachment of a variety of functional groups to the wall or end cap of carbon nanotubes through covalent carbon bonds without destroying the wall or endcap structure of the nanotube. Carbon-centered radicals generated from acyl peroxides can have terminal functional groups that provide sites for further reaction with other compounds. Organic groups with terminal carboxylic acid functionality can be converted to an acyl chloride and further reacted with an amine to form an amide or with a diamine to form an amide with terminal amine. The reactive functional groups attached to the nanotubes provide improved solvent dispersibility and provide reaction sites for monomers for incorporation in polymer structures. The nanotubes can also be functionalized by generating free radicals from organic sulfoxides.
摘要翻译： 用于官能化单壁或多壁碳纳米管的壁的方法涉及使用酰基过氧化物以产生碳中心的自由基。 该方法允许通过共价碳键将各种官能团化学连接到碳纳米管的壁或端盖上，而不破坏纳米管的壁或端帽结构。 由酰基过氧化物产生的碳中心基团可以具有提供与其它化合物进一步反应的位点的末端官能团。 具有末端羧酸官能团的有机基团可以转化为酰氯，并进一步与胺反应形成酰胺或与二胺反应以与末端胺形成酰胺。 连接到纳米管的反应性官能团提供改进的溶剂分散性，并为单体提供用于掺入聚合物结构的反应位点。 纳米管也可以通过产生有机亚砜的自由基来官能化。
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4.发明授权Fabrication of carbon nanotube reinforced epoxy polymer composites using functionalized carbon nanotubes 有权使用官能化碳纳米管制备碳纳米管增强环氧聚合物复合材料公开(公告)号：US07601421B2
公开(公告)日：2009-10-13
申请号：US10559905
申请日：2004-06-16
申请人： Valery N. Khabashesku , Jiang Zhu , Haiqing Peng , Enrique V. Barrera , John L. Margrave , Mary Lou Margrave, legal representative
CPC分类号： D06M13/11 , B82Y30/00 , B82Y40/00 , C01B32/152 , C01B32/174 , C01B2202/02 , C01B2202/04 , C01B2202/06 , C08J5/005 , C08J5/06 , C08J2363/00 , D06M11/09 , D06M11/52 , D06M13/148 , D06M13/196 , D06M15/55 , D06M2101/40 , Y10S977/742 , Y10S977/745 , Y10S977/746 , Y10S977/748 , Y10S977/75 , Y10S977/752 , Y10S977/753 , Y10S977/778 , Y10S977/847 , Y10T428/24994 , Y10T428/30 , Y10T428/31511
摘要： The present invention is directed to methods of integrating carbon nanotubes into epoxy polymer composites via chemical functionalization of carbon nanotubes, and to the carbon nanotube-epoxy polymer composites produced by such methods. Integration is enhanced through improved dispersion and/or covalent bonding with the epoxy matrix during the curing process. In general, such methods involve the attachment of chemical moieties (i.e., functional groups) to the sidewall and/or end-cap of carbon nanotubes such that the chemical moieties react with either the epoxy precursor(s) or the curing agent(s) (or both) during the curing process. Additionally, in some embodiments, these or additional chemical moieties can function to facilitate dispersion of the carbon nanotubes by decreasing the van der Waals attractive forces between the nanotubes.
摘要翻译： 本发明涉及通过碳纳米管的化学官能化将碳纳米管整合到环氧聚合物复合材料中的方法，以及通过这些方法生产的碳纳米管 - 环氧聚合物复合材料。 通过在固化过程中改进与环氧基质的分散和/或共价键合来增强集成。 通常，这种方法包括将化学部分（即官能团）连接到碳纳米管的侧壁和/或端盖上，使得化学部分与环氧前体或固化剂反应， （或两者）。 另外，在一些实施方案中，这些或其它化学部分可以通过降低纳米管之间的范德华力吸引力来起到促进碳纳米管分散的作用。
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5.发明授权Fiber-reinforced polymer composites containing functionalized carbon nanotubes 有权含有官能化碳纳米管的纤维增强聚合物复合材料公开(公告)号：US08187703B2
公开(公告)日：2012-05-29
申请号：US12553721
申请日：2009-09-03
申请人： Jiang Zhu , Valery N. Khabashesku , Haiqing Peng , Enrique V. Barrera , John L. Margrave , Mary Lou Margrave, legal representative
CPC分类号： B29C70/081 , B82Y30/00 , C08J5/005 , C08J5/06 , C08J5/24 , C08J2363/00 , D06M11/73 , D06M15/285 , D06M15/327 , D06M15/55 , D06M23/08 , D06M2101/36 , D06M2101/40 , Y10S977/745 , Y10S977/746 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10T428/24994 , Y10T428/25 , Y10T428/31511
摘要： The present invention is directed to methods of integrating carbon nanotubes into epoxy polymer composites via chemical functionalization of carbon nanotubes, and to the carbon nanotube-epoxy polymer composites produced by such methods. Integration is enhanced through improved dispersion and/or covalent bonding with the epoxy matrix during the curing process. In general, such methods involve the attachment of chemical moieties (i.e., functional groups) to the sidewall and/or end-cap of carbon nanotubes such that the chemical moieties react with either the epoxy precursor(s) or the curing agent(s) (or both) during the curing process. Additionally, in some embodiments, these or additional chemical moieties can function to facilitate dispersion of the carbon nanotubes by decreasing the van der Waals attractive forces between the nanotubes.
摘要翻译： 本发明涉及通过碳纳米管的化学官能化将碳纳米管整合到环氧聚合物复合材料中的方法，以及通过这些方法生产的碳纳米管 - 环氧聚合物复合材料。 通过在固化过程中改进与环氧基质的分散和/或共价键合来增强集成。 通常，这种方法包括将化学部分（即官能团）连接到碳纳米管的侧壁和/或端盖上，使得化学部分与环氧前体或固化剂反应， （或两者）。 另外，在一些实施方案中，这些或其它化学部分可以通过降低纳米管之间的范德华力吸引力来起到促进碳纳米管分散的作用。
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公开(公告)号：US20100047575A1
公开(公告)日：2010-02-25
申请号：US10585591
申请日：2005-01-18
IPC分类号： C07C229/06 , D02G3/00
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/174 , C01B2202/02 , C01B2202/36 , Y10S977/75 , Y10T428/298 , Y10T428/2982
摘要： The present invention is directed toward compositions comprising carbon nanotubes (CNTs) that are sidewall-functionalized with amino acid groups, and to amino acid compositions comprising carbon nanotubes. The present invention is also directed to simple and relatively inexpensive methods for the preparation of such compositions. Such compositions are expected to greatly extend the bio-medical applications of CNTs.
摘要翻译： 本发明涉及包含用氨基酸侧壁官能化的碳纳米管（CNT）和包含碳纳米管的氨基酸组合物的组合物。 本发明还涉及用于制备这种组合物的简单且相对便宜的方法。 预期这种组合物将大大延长CNT的生物医学应用。
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公开(公告)号：US08092774B2
公开(公告)日：2012-01-10
申请号：US10585591
申请日：2005-01-18
申请人： Valery N. Khabashesku , Haiqing Peng , John L. Margrave , Mary Lou Margrave, legal representative
IPC分类号： D01F9/12
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/174 , C01B2202/02 , C01B2202/36 , Y10S977/75 , Y10T428/298 , Y10T428/2982
摘要： The present invention is directed toward compositions comprising carbon nanotubes (CNTs) that are sidewall-functionalized with amino acid groups, and to amino acid compositions comprising carbon nanotubes. The present invention is also directed to simple and relatively inexpensive methods for the preparation of such compositions. Such compositions are expected to greatly extend the bio-medical applications of CNTs.
摘要翻译： 本发明涉及包含用氨基酸侧壁官能化的碳纳米管（CNT）和包含碳纳米管的氨基酸组合物的组合物。 本发明还涉及用于制备这种组合物的简单且相对便宜的方法。 预期这种组合物将大大延长CNT的生物医学应用。
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8.发明申请Fiber-Reinforced Polymer Composites Containing Functionalized Carbon Nanotubes 有权含有官能化碳纳米管的纤维增强聚合物复合材料公开(公告)号：US20100143701A1
公开(公告)日：2010-06-10
申请号：US12553721
申请日：2009-09-03
申请人： Jiang Zhu , Valery N. Khabashesku , Haiqing Peng , Enrique V. Barrera , John L. Margrave , Mary Lou Margrave
发明人： Jiang Zhu , Valery N. Khabashesku , Haiqing Peng , Enrique V. Barrera , John L. Margrave , Mary Lou Margrave
CPC分类号： B29C70/081 , B82Y30/00 , C08J5/005 , C08J5/06 , C08J5/24 , C08J2363/00 , D06M11/73 , D06M15/285 , D06M15/327 , D06M15/55 , D06M23/08 , D06M2101/36 , D06M2101/40 , Y10S977/745 , Y10S977/746 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10T428/24994 , Y10T428/25 , Y10T428/31511
摘要： The present invention is directed to methods of integrating carbon nanotubes into epoxy polymer composites via chemical functionalization of carbon nanotubes, and to the carbon nanotube-epoxy polymer composites produced by such methods. Integration is enhanced through improved dispersion and/or covalent bonding with the epoxy matrix during the curing process. In general, such methods involve the attachment of chemical moieties (i.e., functional groups) to the sidewall and/or end-cap of carbon nanotubes such that the chemical moieties react with either the epoxy precursor(s) or the curing agent(s) (or both) during the curing process. Additionally, in some embodiments, these or additional chemical moieties can function to facilitate dispersion of the carbon nanotubes by decreasing the van der Waals attractive forces between the nanotubes.
摘要翻译： 本发明涉及通过碳纳米管的化学官能化将碳纳米管整合到环氧聚合物复合材料中的方法，以及通过这些方法生产的碳纳米管 - 环氧聚合物复合材料。 通过在固化过程中改进与环氧基质的分散和/或共价键合来增强集成。 通常，这种方法包括将化学部分（即官能团）连接到碳纳米管的侧壁和/或端盖上，使得化学部分与环氧前体或固化剂反应， （或两者）。 另外，在一些实施方案中，这些或其它化学部分可以通过降低纳米管之间的范德华力吸引力来起到促进碳纳米管分散的作用。
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9.发明授权Functionalization of nanodiamond powder through fluorination and subsequent derivatization reactions 有权通过氟化和随后的衍生化反应使纳米金刚石粉末官能化公开(公告)号：US07820130B2
公开(公告)日：2010-10-26
申请号：US10996869
申请日：2004-11-24
发明人： Valery N. Khabashesku , Yu Liu , John L. Margrave
IPC分类号： C01B31/06
CPC分类号： C01B32/28 , Y10T428/2991
摘要： The present invention is directed to functionalized nanoscale diamond powders, methods for making such powders, applications for using such powders, and articles of manufacture comprising such powders. Methods for making such functionalized nanodiamond powders generally comprise a fluorination of nanodiamond powder. In some embodiments, such methods comprise reacting fluorinated nanodiamond powder with a subsequent derivatization agent, such as a strong nucleophile.
摘要翻译： 本发明涉及功能化纳米级金刚石粉末，制备这种粉末的方法，使用这种粉末的应用，以及包含这种粉末的制品。 制备这种官能化纳米金刚石粉末的方法通常包括纳米金刚石粉末的氟化。 在一些实施方案中，这种方法包括使氟化纳米金刚石粉末与随后的衍生化试剂如强亲核试剂反应。
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10.发明授权公开(公告)号：US07632481B2
公开(公告)日：2009-12-15
申请号：US10560351
申请日：2004-06-16
CPC分类号： D06M13/11 , B82Y30/00 , B82Y40/00 , C01B32/152 , C01B32/174 , C01B2202/02 , C01B2202/04 , C01B2202/06 , C08J5/005 , C08J5/06 , C08J2363/00 , D06M11/09 , D06M11/52 , D06M13/148 , D06M13/196 , D06M15/55 , D06M2101/40 , Y10S977/742 , Y10S977/745 , Y10S977/746 , Y10S977/748 , Y10S977/75 , Y10S977/752 , Y10S977/753 , Y10S977/778 , Y10S977/847 , Y10T428/24994 , Y10T428/30 , Y10T428/31511
摘要： The present invention is directed to methods of forming sidewall-functionalized carbon nanotubes, wherein such functionalized carbon nanotubes have hydroxyl-terminated moieties covalently attached to their sidewalls. Generally, such methods involve chemistry on carbon nanotubes that have first been fluorinated. In some embodiments, fluorinated carbon nanotubes (“fluoronanotubes”) are reacted with mono-metal salts of a dialcohol, MO—R—OH, where M is a metal and R is hydrocarbon or other organic chain and/or ring structural unit. In such embodiments, —O—R—OH displaces —F on the nanotube, the fluorine leaving as MF. Generally, such mono-metal salts are formed in situ by the addition of MOH to one or more dialcohols in which the fluoronanotubes have been dispersed. In some embodiments, fluoronanotubes are reacted with amino alcohols, such as being of the type H2N—R—OH, wherein —N(H)—R—OH displaces —F on the nanotube, the fluorine leaving as HF.
摘要翻译： 本发明涉及形成侧壁官能化碳纳米管的方法，其中这种官能化碳纳米管具有共价连接到其侧壁上的羟基封端的部分。 通常，这些方法涉及首先被氟化的碳纳米管上的化学。 在一些实施方案中，氟化碳纳米管（“氟硼腈”）与二醇的单金属盐MO-R-OH反应，其中M是金属，R是烃或其它有机链和/或环结构单元。 在这样的实施方案中，-O-R-OH置换在纳米管上，氟离开为MF。 通常，通过向其中分散有氟尼龙管的一种或多种二醇中添加MOH而原位形成这种单金属盐。 在一些实施方案中，氟烟管与氨基醇反应，例如H2N-R-OH型，其中-N（H）-R-OH置换在纳米管上，氟离去为HF。
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