公开(公告)号：US06268415B1

公开(公告)日：2001-07-31

申请号：US09303582

申请日：1999-05-03

申请人： Walter Renz ,  Joseph Suhadolnik ,  Mervin Gale Wood, Jr. ,  Ramanathan Ravichandran ,  Revathi Iyengar ,  Luther A. R. Hall

发明人： Walter Renz ,  Joseph Suhadolnik ,  Mervin Gale Wood, Jr. ,  Ramanathan Ravichandran ,  Revathi Iyengar ,  Luther A. R. Hall

IPC分类号： C08K534

CPC分类号： B32B17/10761 ,  C08K5/3475 ,  C09J11/06 ,  F24S23/82 ,  Y02E10/40 ,  Y10T428/31551 ,  Y10T428/31786 ,  Y10T428/31855

摘要： Adhesive compositions are rendered stable against degradation caused by ultraviolet light through the incorporation of a highly soluble, photostable benzotriazole UV absorber which is substituted in the ortho position of the hydroxyphenyl ring by &agr;-cumyl or phenyl. Examples of such compounds are 2-(2-hydroxy-3-&agr;-cumyl-5-tert-octylphenyl)-2H-benzotriazole, 5-chloro-2-(2-hydroxy-3-&agr;-cumyl-5-tert-octylphenyl)-2H-benzotriazole, 5-fluoro-2-(2-hydroxy-3-&agr;-cumyl-5-tert-octylphenyl)-2H-benzotriazole, 2-(2-hydroxy-3-&agr;-cumyl-5-tert-butylphenyl)-2H-benzotriazole, 5-chloro-2-(2-hydroxy-3-&agr;-cumyl-5-tert-butylphenyl)-2H-benzotriazole and 5-fluoro-2-(2-hydroxy-3-&agr;-cumyl-5-tert-butylphenyl)-2H-benzotriazole. These compounds exhibit excellent photostability and are highly soluble in adhesive formulations. The laminated articles derived from these compositions include, for example, solar control films, films and glazings, UV absorbing glasses and glass coatings, windscreens, retroreflective sheetings and signs, solar reflectors, optical films and the like.

摘要翻译： 粘合剂组合物通过并入通过α-枯基或苯基在羟基苯基的邻位被取代的高度可溶的光稳定的苯并三唑UV吸收剂而使紫外线引起的降解变得稳定。 这些化合物的实例是2-（2-羟基-3-α-枯基-5-叔辛基苯基）-2H-苯并三唑，5-氯-2-（2-羟基-3-α-枯基-5-叔丁基苯基） 辛基苯基）-2H-苯并三唑，5-氟-2-（2-羟基-3-α-枯基-5-叔辛基苯基）-2H-苯并三唑，2-（2-羟基-3-α-枯基-5- 叔丁基苯基）-2H-苯并三唑，5-氯-2-（2-羟基-3-α-枯基-5-叔丁基苯基）-2H-苯并三唑和5-氟-2-（2-羟基-3- α-枯基-5-叔丁基苯基）-2H-苯并三唑。 这些化合物表现出优异的光稳定性，并且在粘合剂制剂中高度可溶。 衍生自这些组合物的层压制品包括例如太阳能控制薄膜，薄膜和玻璃，紫外线吸收玻璃和玻璃涂层，挡风玻璃，反光片和标志，太阳能反射器，光学膜等。

公开(公告)号：US06187845B1

公开(公告)日：2001-02-13

申请号：US09303583

申请日：1999-05-03

申请人： Walter Renz ,  Mervin Gale Wood, Jr. ,  Joseph Suhadolnik ,  Ramanathan Ravichandran ,  Revathi Iyengar

发明人： Walter Renz ,  Mervin Gale Wood, Jr. ,  Joseph Suhadolnik ,  Ramanathan Ravichandran ,  Revathi Iyengar

IPC分类号： C08K53472

CPC分类号： B32B17/10743 ,  B32B17/10678 ,  C08K5/3475 ,  C09J11/06 ,  F24S23/82 ,  F24S2025/601 ,  Y02E10/40

摘要： Adhesive compositions are rendered stable against degradation caused by ultraviolet light through the incorporation of selected highly soluble, red-shifted, photostable benzotriazole UV absorbers which absorb light strongly in the 350 to 400 nm range. These UV absorbers exhibit excellent photostability and are highly soluble in adhesive formulations. The laminated articles derived from these compositions include, for example, solar control films, films and glazings, UV absorbing glasses and glass coatings, windscreens, retroreflective sheetings and signs, solar reflectors, optical films and the like.

摘要翻译： 粘合剂组合物通过引入在350至400nm范围内强烈吸收光的所选择的高度可溶性，红移，光稳定的苯并三唑UV吸收剂而使紫外线引起的降解变得稳定。 这些UV吸收剂表现出优异的光稳定性，并且在粘合剂配方中高度可溶。 衍生自这些组合物的层压制品包括例如太阳能控制薄膜，薄膜和玻璃，紫外线吸收玻璃和玻璃涂层，挡风玻璃，反光片和标志，太阳能反射器，光学膜等。

公开(公告)号：US06191199B1

公开(公告)日：2001-02-20

申请号：US09303581

申请日：1999-05-03

申请人： Walter Renz ,  Mervin Gale Wood, Jr. ,  Joseph Suhadolnik ,  Ramanathan Ravichandran ,  Revathi Iyengar

发明人： Walter Renz ,  Mervin Gale Wood, Jr. ,  Joseph Suhadolnik ,  Ramanathan Ravichandran ,  Revathi Iyengar

IPC分类号： C08K534

CPC分类号： B32B7/12 ,  B32B17/10678 ,  B32B17/10743 ,  B32B27/18 ,  B32B2307/40 ,  C09J11/06 ,  C09J11/08

摘要： Adhesive compositions are rendered stable against degradation caused by ultraviolet light through the incorporation of a highly soluble, high extinction, photostable hydroxyphenyl-s-triazine UV absorber. An example of such compounds is 2,4-bis(2,4-dimethylphenyl)-6-[2-hydroxy-4-(3-nonyloxy*-2-hydroxypropyloxy)-5-&agr;-cumylphenyl]-s-triazine (* denotes a mixture of octyloxy, nonyloxy and decyloxy groups). Such compounds exhibit high extinction, excellent photostability and are highly soluble in adhesive formulations. The laminated articles derived from these compositions include, for example, solar control films, films and glazings, UV absorbing glasses and glass coatings, windscreens, retroreflective sheetings and signs, solar reflectors, optical films and the like.

摘要翻译： 粘合剂组合物通过引入高度可溶的高消光，光稳定的羟基苯基-s-三嗪UV吸收剂而使紫外线引起的降解变得稳定。 这种化合物的实例是2,4-双（2,4-二甲基苯基）-6- [2-羟基-4-（3-壬基氧基-2-羟基丙氧基）-5-α-枯基苯基] -s-三嗪（ *表示辛氧基，壬氧基和癸氧基的混合物）。 这些化合物具有高消光性，优异的光稳定性，并且在粘合剂制剂中高度可溶。 衍生自这些组合物的层压制品包括例如太阳能控制薄膜，薄膜和玻璃，紫外线吸收玻璃和玻璃涂层，挡风玻璃，反光片和标志，太阳能反射器，光学膜等。

公开(公告)号：US5977219A

公开(公告)日：1999-11-02

申请号：US961127

申请日：1997-10-30

申请人： Ramanathan Ravichandran ,  Anthony David Debellis ,  Revathi Iyengar ,  Joseph Suhadolnik ,  Jean-Pierre Wolf ,  Robert Edward Detlefsen ,  Mervin Gale Wood

发明人： Ramanathan Ravichandran ,  Anthony David Debellis ,  Revathi Iyengar ,  Joseph Suhadolnik ,  Jean-Pierre Wolf ,  Robert Edward Detlefsen ,  Mervin Gale Wood

IPC分类号： C08K5/3475 ,  C08K5/34 ,  C08K5/09 ,  C08K5/36

CPC分类号： C08K5/3475 ,  B41M5/124 ,  B41M5/3375

摘要： Benzotriazole UV absorbers which are substituted at the 5-position of the benzo ring by an electron withdrawing group exhibit enhanced durability and very low loss rates when incorporated into automotive coatings.

摘要翻译： 通过吸电子基团在苯环的5位被取代的苯并三唑UV吸收剂在掺入汽车涂料中时表现出增强的耐久性和非常低的损失率。

公开(公告)号：US06515051B2

公开(公告)日：2003-02-04

申请号：US10023257

申请日：2001-12-18

申请人： Ramanathan Ravichandran ,  Joseph Suhadolnik ,  Mervin G. Wood ,  Anthony Debellis ,  Robert E. Detlefsen ,  Revathi Iyengar ,  Jean-Pierre Wolf

发明人： Ramanathan Ravichandran ,  Joseph Suhadolnik ,  Mervin G. Wood ,  Anthony Debellis ,  Robert E. Detlefsen ,  Revathi Iyengar ,  Jean-Pierre Wolf

IPC分类号： C08K534

CPC分类号： C07F9/65188 ,  B41M5/124 ,  B41M5/3375 ,  B41M5/392 ,  C07D249/20 ,  C08K5/3475 ,  C09D7/48 ,  Y10S430/132

摘要： Benzotriazole UV absorbers which are substituted at the 5-position of the benzo ring by an electron withdrawing group exhibit enhanced durability and very low loss rates when incorporated into automotive coatings. This is particularly the case when the 3-position of the phenyl ring is also substituted by phenyl or phenylalkyl such as &agr;-cumyl. Compounds where the 5-position of the benzo ring are substituted by perfluoroalkyl such as trifluoromethyl are particularly of interest for both their enhanced durability and for their excellent solubility and excellent color properties in some thermoplastic compositions when the phenyl ring is substituted at the 3-position by hydrogen or tert-alkyl.

公开(公告)号：US06458872B1

公开(公告)日：2002-10-01

申请号：US09851453

申请日：2001-05-08

申请人： Ramanathan Ravichandran ,  Joseph Suhadolnik ,  Mervin G. Wood ,  Anthony Debellis ,  Robert E. Detlefsen ,  Revathi Iyengar ,  Jean-Pierre Wolf

发明人： Ramanathan Ravichandran ,  Joseph Suhadolnik ,  Mervin G. Wood ,  Anthony Debellis ,  Robert E. Detlefsen ,  Revathi Iyengar ,  Jean-Pierre Wolf

IPC分类号： C08K53475

CPC分类号： C07F9/65188 ,  B41M5/124 ,  B41M5/3375 ,  B41M5/392 ,  C07D249/20 ,  C08K5/3475 ,  C09D7/48 ,  Y10S430/132

摘要： Benzotriazole UV absorbers which are substituted at the 5-position of the benzo ring by an electron withdrawing group exhibit enhanced durability and very low loss rates when incorporated into automotive coatings. This is particularly the case when the 3-position of the phenyl ring is also substituted by phenyl or phenylalkyl such as &agr;-cumyl. Compounds where the 5-position of the benzo ring are substituted by perfluoroalkyl such as trifluoromethyl are particularly of interest for both their enhanced durability and for their excellent solubility and excellent color properties in some thermoplastic compositions when the phenyl ring is substituted at the 3-position by hydrogen or tert-alkyl.

公开(公告)号：US06262151B1

公开(公告)日：2001-07-17

申请号：US09614527

申请日：2000-07-12

申请人： Ramanathan Ravichandran ,  Joseph Suhadolnik ,  Mervin G. Wood ,  Anthony Debellis ,  Robert E. Detlefsen ,  Revathi Iyengar ,  Jean-Pierre Wolf

发明人： Ramanathan Ravichandran ,  Joseph Suhadolnik ,  Mervin G. Wood ,  Anthony Debellis ,  Robert E. Detlefsen ,  Revathi Iyengar ,  Jean-Pierre Wolf

IPC分类号： C08K53475

CPC分类号： C07F9/65188 ,  B41M5/124 ,  B41M5/3375 ,  B41M5/392 ,  C07D249/20 ,  C08K5/3475 ,  C09D7/48 ,  Y10S430/132

摘要： Benzotriazole UV absorbers which are substituted at the 5-position of the benzo ring by an electron withdrawing group exhibit enhanced durability and very low loss rates when incorporated into automotive coatings. This is particularly the case when the 3-position of the phenyl ring is also substituted by phenyl or phenylalkyl such as &agr;-cumyl. Compounds where the 5-position of the benzo ring are substituted by perfluoroalkyl such as trifluoromethyl are particularly of interest for both their enhanced durability and for their excellent solubility and excellent color properties in some thermoplastic compositions when the phenyl ring is substituted at the 3-position by hydrogen or tert-alkyl.

摘要翻译： 通过吸电子基团在苯环的5位被取代的苯并三唑UV吸收剂在掺入汽车涂料中时表现出增强的耐久性和非常低的损失率。 当苯环的3-位也被苯基或苯基烷基如α-枯基取代时，情况尤其如此。 苯并环的5-位被全氟烷基取代的化合物，例如三氟甲基，特别是当苯环在3位被取代时，它们的耐久性提高和在一些热塑性组合物中优异的溶解度和优异的着色性能是令人感兴趣的 通过氢或叔烷基。

公开(公告)号：US6166218A

公开(公告)日：2000-12-26

申请号：US234880

申请日：1999-01-21

申请人： Ramanathan Ravichandran ,  Joseph Suhadolnik ,  Mervin G. Wood ,  Anthony Debellis ,  Robert E. Detlefsen ,  Revathi Iyengar ,  Jean-Pierre Wolf

发明人： Ramanathan Ravichandran ,  Joseph Suhadolnik ,  Mervin G. Wood ,  Anthony Debellis ,  Robert E. Detlefsen ,  Revathi Iyengar ,  Jean-Pierre Wolf

IPC分类号： C07D249/20 ,  C07F9/6518 ,  C08K5/3475 ,  C09D7/12 ,  C09D201/00 ,  C09K3/00 ,  C07D403/10

CPC分类号： C07F9/65188 ,  B41M5/124 ,  B41M5/3375 ,  B41M5/392 ,  C07D249/20 ,  C08K5/3475 ,  C09D7/48 ,  Y10S430/132

摘要： Benzotriazole UV absorbers which are substituted at the 5-position of the benzo ring by an electron withdrawing group exhibit enhanced durability and very low loss rates when incorporated into automotive coatings. This is particularly the case when the 3-position of the phenyl ring is also substituted by phenyl or phenylalkyl such as .alpha.-cumyl. Compounds where the 5-position of the benzo ring are substituted by perfluoroalkyl such as trifluoromethyl are particularly of interest for both their enhanced durability and for their excellent solubility and excellent color properties in some thermoplastic compositions when the phenyl ring is substituted at the 3-position by hydrogen or tert-alkyl.

摘要翻译： 通过吸电子基团在苯环的5位被取代的苯并三唑UV吸收剂在掺入汽车涂料中时表现出增强的耐久性和非常低的损失率。 当苯环的3-位也被苯基或苯基烷基如α-枯烯基所取代时，情况尤其如此。 苯并环的5-位被全氟烷基取代的化合物，例如三氟甲基，特别是当苯环在3位被取代时，它们的耐久性提高和在一些热塑性组合物中优异的溶解度和优异的着色性能是令人感兴趣的 通过氢或叔烷基。

公开(公告)号：US20050019507A1

公开(公告)日：2005-01-27

申请号：US10499854

申请日：2002-12-16

申请人： Walter Renz ,  Ramanathan Ravichandran ,  Andrew Naisby ,  Joseph Suhadolnik ,  Mervin Wood ,  Rong Xiong

发明人： Walter Renz ,  Ramanathan Ravichandran ,  Andrew Naisby ,  Joseph Suhadolnik ,  Mervin Wood ,  Rong Xiong

IPC分类号： B41J2/01 ,  B41M5/00 ,  B41M5/50 ,  B41M5/52 ,  C08F8/00 ,  C08F8/12 ,  C09D11/00 ,  B32B5/16

CPC分类号： C08F8/00 ,  B41M5/506 ,  B41M5/508 ,  B41M5/52 ,  B41M5/5218 ,  B41M5/5227 ,  B41M5/5236 ,  B41M5/5254 ,  B41M5/5281 ,  C08F8/12 ,  C09D11/30 ,  Y10T428/252 ,  Y10T428/254 ,  Y10T428/256 ,  Y10T428/258 ,  Y10T428/259 ,  Y10T428/31576 ,  Y10T428/31591 ,  Y10T428/31895 ,  C08F226/02 ,  C08F216/06 ,  C08F218/08

摘要： Disclosed are ink jet recording media systems that comprise a poly(vinyl alcohol)-co-poly(N-vinyl formamide) copolymer of the formula, wherein n is between 0 and about 20 mole percent, m is between about 50 and about 97 mole percent, x is between 0 and about 20 mole percent, y is between 0 and about 20 mole percent, z is between 0 and about 2 mole percent and x+y is between about 3 and about 20 mole percent, R1 and R3 are independently H; 3-propionic add or C1-C6 alkyl ester thereof; or is 2-methyl-3-propionic acid or C1-C6 alkyl ester thereof, and R2 and R4 are independently H or C1-C6 alkyl.

摘要翻译： 公开了包含下式的聚（乙烯醇） - 共 - （N-乙烯基甲酰胺）共聚物的喷墨记录介质体系，其中n为0至约20摩尔％，m为约50至约97摩尔 x为0至约20摩尔％，y为0至约20摩尔％，z为0至约2摩尔％，x + y为约3至约20摩尔％，R1和R3独立地为 H; 3-丙酸加成或其C1-C6烷基酯; 或者是2-甲基-3-丙酸或其C1-C6烷基酯，R2和R4独立地是H或C1-C6烷基。

公开(公告)号：US07173071B2

公开(公告)日：2007-02-06

申请号：US10838473

申请日：2004-05-04

申请人： Joseph Suhadolnik ,  Mervin Wood ,  Ramanathan Ravichandran ,  Walter Renz ,  Andrea Roberts ,  Nancy Cliff ,  Eugene Sitzman ,  David Bramer

发明人： Joseph Suhadolnik ,  Mervin Wood ,  Ramanathan Ravichandran ,  Walter Renz ,  Andrea Roberts ,  Nancy Cliff ,  Eugene Sitzman ,  David Bramer

IPC分类号： C08J3/28 ,  C08K5/3475 ,  C08F2/50 ,  C09D4/02 ,  C09D175/16

CPC分类号： C09D4/06 ,  C09D4/00

摘要： Photo-curable coating formulations which comprise a durable and/or red-shifted reactable hydroxyphenylbenzotriazole ultraviolet light absorber (UVA) are effectively photocured employing a combination of α-hydroxy ketone and bisacylphosphine oxide photoinitiators. The reactable UVA's are reacted into the coating upon curing. The combination of the photoinitiators bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide and 1-hydroxycyclohexylphenylketone is especially effective for this purpose.

摘要翻译： 使用α-羟基酮和双酰基氧化膦光引发剂的组合，有效地光固化包含耐久和/或红移反应性羟基苯基苯并三唑紫外光吸收剂（UVA）的光固化涂料制剂。 固化后可反应的UVA反应成涂层。 光引发剂双（2,4,6-三甲基苯甲酰基）苯基氧化膦和1-羟基环己基苯基酮的组合对于此目的是特别有效的。