公开(公告)号：US20160195480A1

公开(公告)日：2016-07-07

申请号：US14125104

申请日：2012-06-08

申请人： Werner Maas ,  Mélanie Rosay ,  Christophe Coperet ,  David Gajan ,  Lyndon Emsley ,  Moreno Lelli ,  Anne Lesage ,  Aaron Rossini ,  Alexandre Zagdoun ,  Paul Tordo ,  Olivier Ouari

发明人： Werner Maas ,  Mélanie Rosay ,  Christophe Coperet ,  David Gajan ,  Lyndon Emsley ,  Moreno Lelli ,  Anne Lesage ,  Aaron Rossini ,  Alexandre Zagdoun ,  Paul Tordo ,  Olivier Ouari

IPC分类号： G01N24/12 ,  G01R33/46 ,  G01R33/28

CPC分类号： G01N24/12 ,  G01R33/282 ,  G01R33/46 ,  G01R33/62

摘要： Non aqueous solvents or mixtures for DNP NMR spectroscopy, method to prepare said solvents or mixtures and use of said solvents or mixtures The present invention concerns a method to determine the efficiency of a solvent to impregnate a sample material for use in a dynamic nuclear polarization (DNP) nuclear magnetic resonance (NMR) experiments, characterized in that the method comprising: —selecting a non-aqueous solvent, —providing a polarizing agent that is soluble in the non-aqueous solvent, —dissolving the polarizing agent in the non-aqueous solvent, —impregnating or dissolving the sample material with the non-aqueous solvent containing the polarizing agent, —performing a solid state DNP NMR experiment on the impregnated sample material, —determining a DNP enhancement factor of the DNP NMR experiment.

摘要翻译： 用于DNP NMR光谱的非水溶剂或混合物，制备所述溶剂或混合物的方法以及所述溶剂或混合物的使用本发明涉及确定溶剂浸渍用于动态核极化的样品材料的效率的方法（ DNP）核磁共振（NMR）实验，其特征在于该方法包括：选择非水溶剂，提供可溶于非水溶剂的偏光剂，将偏振剂溶解在非水溶剂 溶剂，用含有偏振剂的非水溶剂浸渍或溶解样品材料， - 对浸渍的样品材料进行固态DNP NMR实验，确定DNP NMR实验的DNP增强因子。