PROCESS FOR PREPARING 3-METHYLBUT-1-ENE
    4.
    发明申请
    PROCESS FOR PREPARING 3-METHYLBUT-1-ENE 有权
    制备3-甲基-1-环己烯的方法

    公开(公告)号:US20090163687A1

    公开(公告)日:2009-06-25

    申请号:US12300224

    申请日:2007-05-11

    IPC分类号: C08F110/08 C07C5/27

    CPC分类号: C07C1/24 Y02P20/127 C07C11/10

    摘要: The present invention relates to the preparation of 3-methylbut-1-ene from a hydrocarbon stream I comprising isobutene by feeding a hydrocarbon stream II which comprises at least 70% by mass of isobutene in relation to the olefins present in the hydrocarbon stream and which has been obtained from hydrocarbon stream I or is identical to it to a process step for hydroformylation in which isobutene is hydroformylated in the presence of a rhodium catalyst, hydrogenating the aldehyde obtained from the hydroformylation of isobutene to the corresponding alcohol and preparing 3-methylbut-1-ene by water elimination from the alcohol.

    摘要翻译: 本发明涉及从包含异丁烯的烃流I中制备3-甲基丁-1-烯,该烃流包含相对于存在于烃流中的烯烃至少70质量%的异丁烯的烃流II,其中 已经从烃流I获得或者与加氢甲酰化的方法步骤相同,其中异丁烯在铑催化剂的存在下被加氢甲酰化,氢化从异丁烯的加氢甲酰化得到的醛到相应的醇,并制备3-甲基丁酸, 1-ene由酒精消除水分。