-
1.发明申请ALKYLIDENE COMPLEXES OF RUTHENIUM CONTAINING N-HETEROCYCLIC CARBENE LIGANDS; USE AS HIGHLY ACTIVE, SELECTIVE CATALYSTS FOR OLEFIN METATHESIS 审中-公开含有N-杂环碳酸酯配位体的亚甲基二胺的复合物; 用作高活性选择性催化剂，用于烯烃METATHESIS公开(公告)号：US20080207911A1
公开(公告)日：2008-08-28
申请号：US12115139
申请日：2008-05-05
CPC分类号： C07F15/0046 , B01J31/18 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/2404 , B01J31/26 , B01J2231/14 , B01J2231/54 , B01J2231/543 , B01J2531/0263 , B01J2531/821 , C07C2/32 , C07C6/04 , C07C67/313 , C07C67/475 , C07C2531/22 , C07C2531/24 , C08G61/08 , C07C69/593 , C07C13/20 , C07C11/02
摘要： The invention relates to a complex of ruthenium of the structural formula I, where X1 and X2 are identical or different and are each an anionic ligand, R1 and R2 are identical or different and can also contain a ring, and R1 and R2 are each hydrogen or/and a hydrocarbon group, the ligand L1 is an N-heterocyclic carbene and the ligand L2 is an uncharged electron donor, in particular an N-heterocyclic carbene or an amine, imine, phosphine, phosphate, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, where R1, R2, R3 and R4 are hydrogen or/and hydrocarbon groups. The invention further relates to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by an olefin metathesis reaction in the presence of at least one catalyst, wherein a complex is used as catalyst and R′1, R′2, R′3 and R′4 are hydrogen or/and hydrocarbon groups.
摘要翻译： 本发明涉及结构式I的钌络合物，其中X 1和X 2 2相同或不同，并且各自为阴离子配体，R 1 R 2和R 2相同或不同，也可以含有环，R 1和R 2各自为氢或/ 和烃基，配体L 1是N-杂环卡宾，配体L 2是不带电子的电子给体，特别是N-杂环卡宾或胺 ，亚胺，膦，磷酸盐，锑，胂，羰基化合物，羧基化合物，腈，醇，醚，硫醇或硫醚，其中R 1，R 2， SUP> 3和R 4是氢或/和烃基。 本发明还涉及一种制备具有两个或多个碳原子的非环烯烃或/或具有四个以上碳原子的环烯烃的环烯烃的方法，所述环烯烃具有两个或更多个碳原子的无环烯烃和/或具有四个以上碳原子的环状烯烃， 在至少一种催化剂存在下进行烯烃复分解反应，其中使用络合物作为催化剂，R'1，R'2，R'3， R 4和R 4是氢或/和烃基。
-
2.发明申请ALKYLIDENE COMPLEXES OF RUTHENIUM CONTAINING N-HETEROCYCLIC CARBENE LIGANDS; USE AS HIGHLY ACTIVE, SELECTIVE CATALYSTS FOR OLEFIN METATHESIS 有权含有N-杂环碳酸酯配位体的亚甲基二胺的复合物; 用作高活性选择性催化剂，用于烯烃METATHESIS公开(公告)号：US20110282068A1
公开(公告)日：2011-11-17
申请号：US13090688
申请日：2011-04-20
CPC分类号： C07F15/0046 , B01J31/18 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/2404 , B01J31/26 , B01J2231/14 , B01J2231/54 , B01J2231/543 , B01J2531/0263 , B01J2531/821 , C07C2/32 , C07C6/04 , C07C67/313 , C07C67/475 , C07C2531/22 , C07C2531/24 , C08G61/08 , C07C69/593 , C07C13/20 , C07C11/02
摘要： The invention relates to a complex of ruthenium of the structural formula I, where X1 and X2 are identical or different and are each an anionic ligand, R1 and R2 are identical or different and can also contain a ring, and R1 and R2 are each hydrogen or/and a hydrocarbon group, the ligand L1 is an N-heterocyclic carbene and the ligand L2 is an uncharged electron donor, in particular an N-heterocyclic carbene or an amine, imine, phosphine, phosphate, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, where R1, R2, R3 and R4 are hydrogen or/and hydrocarbon groups. The invention further relates to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by an olefin metathesis reaction in the presence of at least one catalyst, wherein a complex is used as catalyst and R1, R′2, R′3 and R′4 are hydrogen or/and hydrocarbon groups.
摘要翻译： 本发明涉及结构式I的钌络合物，其中X1和X2相同或不同并且各自为阴离子配体，R 1和R 2相同或不同，并且还可以含有环，R 1和R 2各自为氢 或/或烃基，配体L1为N-杂环卡宾，配体L2为不带电子的电子给体，特别是N-杂环卡宾或胺，亚胺，膦，磷酸，锑，胂，羰基化合物， 羧基化合物，腈，醇，醚，硫醇或硫醚，其中R 1，R 2，R 3和R 4是氢或/和烃基。 本发明还涉及一种制备具有两个或多个碳原子的非环烯烃或/或具有四个以上碳原子的环烯烃的环烯烃的方法，所述环烯烃具有两个或更多个碳原子的无环烯烃和/或具有四个以上碳原子的环状烯烃， 在至少一种催化剂存在下进行烯烃复分解反应，其中使用络合物作为催化剂，R 1，R'2，R'3和R'4是氢或/或烃基。
-
3.发明授权Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis 有权含有N-杂环卡宾配体的钌亚烷基络合物; 用作烯烃复分解的高活性选择性催化剂公开(公告)号：US07652145B2
公开(公告)日：2010-01-26
申请号：US11021967
申请日：2004-12-23
CPC分类号： C07F15/0046 , B01J31/18 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/2404 , B01J31/26 , B01J2231/14 , B01J2231/54 , B01J2231/543 , B01J2531/0263 , B01J2531/821 , C07C2/32 , C07C6/04 , C07C67/313 , C07C67/475 , C07C2531/22 , C07C2531/24 , C08G61/08 , C07C69/593 , C07C13/20 , C07C11/02
摘要： The invention relates to a complex compound of ruthenium of the general structural formula I in which X1 and X2 may be identical or different and represent an anionic ligand, in which R1 and R2 are identical or different, but may also have a ring, in which R1 and R2 represent hydrogen or/and a hydrocarbon group, in which the ligand L1 is a N-heterocyclic carbene and in which the ligand L2 is a neutral electron donor, especially a N-heterocyclic carbene or an amine, imine, phosphane, phosphite, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, wherein R1, R2, R3 and R4 represent hydrogen or/and hydrocarbon groups. The invention relates also to a process for the preparation of acyclic olefins having two or more carbon atoms or/and of cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by olefin metathesis reaction in the presence of at least one catalyst, wherein such a complex compound is used as catalyst and wherein R′1, R′2, R′3 and R′4 hydrogen or/and hydrocarbon groups.
摘要翻译： 本发明涉及一般结构式I的钌络合物，其中X1和X2可以相同或不同，表示阴离子配体，其中R1和R2相同或不同，但也可以具有环，其中 R1和R2表示氢或/和烃基，其中配体L1是N-杂环卡宾，其中配体L2是中性电子给体，特别是N-杂环卡宾或胺，亚胺，膦，亚磷酸酯 ，锑，胂，羰基化合物，羧基化合物，腈，醇，醚，硫醇或硫醚，其中R 1，R 2，R 3和R 4表示氢或/或烃基。 本发明还涉及一种制备具有两个或更多个碳原子的非环烯烃和/或具有四个或更多个碳原子的具有两个或更多个碳原子的无环烯烃的环状烯烃和/或具有四个或更多个碳原子的环烯烃的环烯烃的方法 碳原子在至少一种催化剂存在下通过烯烃复分解反应，其中这种配位化合物用作催化剂，并且其中R'1，R'2，R'3和R'4氢或/和烃基。
-
4.发明授权Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis 有权含有N-杂环卡宾配体的钌亚烷基络合物; 用作烯烃复分解的高活性选择性催化剂公开(公告)号：US07378528B2
公开(公告)日：2008-05-27
申请号：US11828828
申请日：2007-07-26
CPC分类号： C07F15/0046 , B01J31/18 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/2404 , B01J31/26 , B01J2231/14 , B01J2231/54 , B01J2231/543 , B01J2531/0263 , B01J2531/821 , C07C2/32 , C07C6/04 , C07C67/313 , C07C67/475 , C07C2531/22 , C07C2531/24 , C08G61/08 , C07C69/593 , C07C13/20 , C07C11/02
摘要： The invention relates to a complex of ruthenium of the structural formula I, where X1 and X2 are identical or different and are each an anionic ligand, R1 and R2 are identical or different and can also contain a ring, and R1 and R2 are each hydrogen or/and a hydrocarbon group, the ligand L1 is an N-heterocyclic carbene and the ligand L2 is an uncharged electron donor, in particular an N-heterocyclic carbene or an amine, imine, phosphine, phosphate, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, where R1, R2, R3 and R4 are hydrogen or/and hydrocarbon groups. The invention further relates to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by an olefin metathesis reaction in the presence of at least one catalyst, wherein a complex is used as catalyst and R′1, R′2, R′3 and R′4 are hydrogen or/and hydrocarbon groups.
摘要翻译： 本发明涉及结构式I的钌络合物，其中X 1和X 2 2相同或不同，并且各自为阴离子配体，R 1 R 2和R 2相同或不同，也可以含有环，R 1和R 2各自为氢或/ 和烃基，配体L 1是N-杂环卡宾，配体L 2是不带电子的电子给体，特别是N-杂环卡宾或胺 ，亚胺，膦，磷酸盐，锑，胂，羰基化合物，羧基化合物，腈，醇，醚，硫醇或硫醚，其中R 1，R 2， SUP> 3和R 4是氢或/和烃基。 本发明还涉及一种制备具有两个或多个碳原子的非环烯烃或/或具有四个以上碳原子的环烯烃的环烯烃的方法，所述环烯烃具有两个或更多个碳原子的无环烯烃和/或具有四个以上碳原子的环状烯烃， 在至少一种催化剂存在下进行烯烃复分解反应，其中使用络合物作为催化剂，R 1，R 2，R 3， / SUP>和R 4'是氢或/和烃基。
-
5.发明授权Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis 有权含有N-杂环卡宾配体的钌亚烷基络合物; 用作烯烃复分解的高活性选择性催化剂公开(公告)号：US07294717B2
公开(公告)日：2007-11-13
申请号：US10630552
申请日：2003-07-29
CPC分类号： C07F15/0046 , B01J31/18 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/2404 , B01J31/26 , B01J2231/14 , B01J2231/54 , B01J2231/543 , B01J2531/0263 , B01J2531/821 , C07C2/32 , C07C6/04 , C07C67/313 , C07C67/475 , C07C2531/22 , C07C2531/24 , C08G61/08 , C07C69/593 , C07C13/20 , C07C11/02
摘要： Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands and their use as highly active, selective catalysts for olefin metathesisThe invention relates to a complex of ruthenium of the structural formula I, where X1 and X2 are identical or different and are each an anionic ligand, R1 and R2 are identical or different and can also contain a ring, and R1 and R2 are each hydrogen or/and a hydrocarbon group, the ligand L1 is an N-heterocyclic carbene and the ligand L2 is an uncharged electron donor, in particular an N-heterocyclic carbene or an amine, imine, phosphine, phosphite, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, where R1, R2, R3 and R4 are hydrogen or/and hydrocarbon groups. The invention further relates to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by an olefin metathesis reaction in the presence of at least one catalyst, wherein a complex is used as catalyst and R′1, R′2, R′3 and R′4 are hydrogen or/and hydrocarbon groups.
摘要翻译： 含有N-杂环卡宾配体的钌的亚烷基配合物及其作为烯烃复分解的高活性选择性催化剂的用途本发明涉及结构式I的钌络合物，其中X 1和X 2 > 2相同或不同，各自为阴离子配体，R 1和R 2相同或不同，并且还可以含有环， SUP 1和R 2各自为氢或/和烃基，配体L 1为N-杂环卡宾，配体L为SUP > 2 是不带电荷的电子给体，特别是N-杂环卡宾或胺，亚胺，膦，亚磷酸酯，锑，胂，羰基化合物，羧基化合物，腈，醇，醚，硫醇或硫醚，其中 R 1，R 2，R 3和R 4是氢或/或烃基。 本发明还涉及一种制备具有两个或多个碳原子的非环烯烃或/或具有四个以上碳原子的环烯烃的环烯烃的方法，所述环烯烃具有两个或更多个碳原子的无环烯烃和/或具有四个以上碳原子的环状烯烃， 在至少一种催化剂存在下进行烯烃复分解反应，其中使用络合物作为催化剂，R'1，R'2，R'3， R 4和R 4是氢或/和烃基。
-
6.发明授权Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis 有权含有N-杂环卡宾配体的钌亚烷基络合物; 用作烯烃复分解的高活性选择性催化剂公开(公告)号：US08153810B2
公开(公告)日：2012-04-10
申请号：US13090688
申请日：2011-04-20
CPC分类号： C07F15/0046 , B01J31/18 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/2404 , B01J31/26 , B01J2231/14 , B01J2231/54 , B01J2231/543 , B01J2531/0263 , B01J2531/821 , C07C2/32 , C07C6/04 , C07C67/313 , C07C67/475 , C07C2531/22 , C07C2531/24 , C08G61/08 , C07C69/593 , C07C13/20 , C07C11/02
摘要： The invention relates to a complex of ruthenium of the structural formula I, where X1 and X2 are identical or different and are each an anionic ligand, R1 and R2 are identical or different and can also contain a ring, and R1 and R2 are each hydrogen or/and a hydrocarbon group, the ligand L1 is an N-heterocyclic carbene and the ligand L2 is an uncharged electron donor, in particular an N-heterocyclic carbene or an amine, imine, phosphine, phosphate, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, where R1, R2, R3 and R4 are hydrogen or/and hydrocarbon groups. The invention further relates to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by an olefin metathesis reaction in the presence of at least one catalyst, wherein a complex is used as catalyst and R′1, R′2, R′3 and R′4 are hydrogen or/and hydrocarbon groups.
摘要翻译： 本发明涉及结构式I的钌络合物，其中X1和X2相同或不同并且各自为阴离子配体，R 1和R 2相同或不同，并且还可以含有环，R 1和R 2各自为氢 或/或烃基，配体L1为N-杂环卡宾，配体L2为不带电子的电子给体，特别是N-杂环卡宾或胺，亚胺，膦，磷酸，锑，胂，羰基化合物， 羧基化合物，腈，醇，醚，硫醇或硫醚，其中R 1，R 2，R 3和R 4是氢或/和烃基。 本发明还涉及一种制备具有两个或多个碳原子的非环烯烃或/或具有四个以上碳原子的环烯烃的环烯烃的方法，所述环烯烃具有两个或更多个碳原子的无环烯烃和/或具有四个以上碳原子的环状烯烃， 在至少一种催化剂存在下进行烯烃复分解反应，其中使用络合物作为催化剂，R'1，R'2，R'3和R'4是氢或/和烃基。
-
7.发明授权Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis 有权含有N-杂环卡宾配体的钌亚烷基络合物; 用作烯烃复分解的高活性选择性催化剂公开(公告)号：US06635768B1
公开(公告)日：2003-10-21
申请号：US09647742
申请日：2000-11-27
IPC分类号： C07F1500
CPC分类号： C07F15/0046 , B01J31/18 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/2404 , B01J31/26 , B01J2231/14 , B01J2231/54 , B01J2231/543 , B01J2531/0263 , B01J2531/821 , C07C2/32 , C07C6/04 , C07C67/313 , C07C67/475 , C07C2531/22 , C07C2531/24 , C08G61/08 , C07C69/593 , C07C13/20 , C07C11/02
摘要： The invention relates to a complex of ruthenium of the structural formula I, where X1 and X2 are identical or different and are each an anionic ligand, R1 and R2 are identical or different and can also contain a ring, and R1 and R2 are each hydrogen or/and a hydrocarbon group, the ligand L1 is an N-heterocyclic carbene and the ligand L2 is an uncharged electron donor, in particular an N-heterocyclic carbene or an amine, imine, phosphine, phosphite, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, where R1, R2, R3 and R4 are hydrogen or/and hydrocarbon groups. The invention further relates to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by an olefin metathesis reaction in the presence of at least one catalyst, wherein a complex is used as catalyst and R′1, R′2, R′3 and R′4 are hydrogen or/and hydrocarbon groups.
摘要翻译： 本发明涉及结构式I的钌络合物，其中X 1和X 2相同或不同，并且各自为阴离子配体，R 1和R 2相同或不同，并且可以 还含有环，R 1和R 2各自为氢或/或烃基，配体L 1为N-杂环卡宾，配体L 2为不带电子的电子给体， 特别是N-杂环卡宾或胺，亚胺，膦，亚磷酸酯，锑，胂，羰基化合物，羧基化合物，腈，醇，醚，硫醇或硫醚，其中R 1，R 2， 3>和R 4是氢或/和烃基。本发明还涉及一种制备具有两个或更多个碳原子的非环烯烃或/或具有四个或更多碳原子的环烯烃的方法，所述环烯烃具有两个或更多个无环烯烃 碳原子和/或具有四个或更多个碳原子的环状烯烃，通过在至少一种催化剂的存在下进行烯烃复分解反应，其中完全 x用作催化剂，R''，R'2，R'3和R'4是氢或/或烃基。
-
8.发明申请ALKYLIDENE COMPLEXES OF RUTHENIUM CONTAINING N-HETEROCYCLIC CARBENE LIGANDS; USE AS HIGHLY ACTIVE, SELECTIVE CATALYSTS FOR OLEFIN METATHESIS 有权含有N-杂环碳酸酯配位体的亚甲基二胺的复合物; 用作高活性选择性催化剂，用于烯烃METATHESIS公开(公告)号：US20080009598A1
公开(公告)日：2008-01-10
申请号：US11828828
申请日：2007-07-26
CPC分类号： C07F15/0046 , B01J31/18 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/2404 , B01J31/26 , B01J2231/14 , B01J2231/54 , B01J2231/543 , B01J2531/0263 , B01J2531/821 , C07C2/32 , C07C6/04 , C07C67/313 , C07C67/475 , C07C2531/22 , C07C2531/24 , C08G61/08 , C07C69/593 , C07C13/20 , C07C11/02
摘要： The invention relates to a complex of ruthenium of the structural formula I, where X1 and X2 are identical or different and are each an anionic ligand, R1 and R2 are identical or different and can also contain a ring, and R1 and R2 are each hydrogen or/and a hydrocarbon group, the ligand L1 is an N-heterocyclic carbene and the ligand L2 is an uncharged electron donor, in particular an N-heterocyclic carbene or an amine, imine, phosphine, phosphate, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, where R1, R2, R3 and R4 are hydrogen or/and hydrocarbon groups. The invention further relates to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by an olefin metathesis reaction in the presence of at least one catalyst, wherein a complex is used as catalyst and R′1, R′2, R′3 and R′4 are hydrogen or/and hydrocarbon groups.
摘要翻译： 本发明涉及结构式I的钌络合物，其中X 1和X 2 2相同或不同，并且各自为阴离子配体，R 1 R 2和R 2相同或不同，也可以含有环，R 1和R 2各自为氢或/ 和烃基，配体L 1是N-杂环卡宾，配体L 2是不带电子的电子给体，特别是N-杂环卡宾或胺 ，亚胺，膦，磷酸盐，锑，胂，羰基化合物，羧基化合物，腈，醇，醚，硫醇或硫醚，其中R 1，R 2， SUP> 3和R 4是氢或/和烃基。 本发明还涉及一种制备具有两个或多个碳原子的非环烯烃或/或具有四个以上碳原子的环烯烃的环烯烃的方法，所述环烯烃具有两个或更多个碳原子的无环烯烃和/或具有四个以上碳原子的环状烯烃， 在至少一种催化剂的存在下进行烯烃复分解反应，其中使用络合物作为催化剂，R 1，R 2，R 3， / SUP>和R 4'是氢或/和烃基。
-
9.发明申请Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis 有权含有N-杂环卡宾配体的钌亚烷基络合物; 用作烯烃复分解的高活性选择性催化剂公开(公告)号：US20050107626A1
公开(公告)日：2005-05-19
申请号：US11021967
申请日：2004-12-23
IPC分类号： B01J31/22 , C07C2/32 , C07C67/313 , C07C67/475 , C07F15/00 , C08F2/60 , C08F4/80 , C08G61/06 , C07F17/02
CPC分类号： C07F15/0046 , B01J31/18 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/2404 , B01J31/26 , B01J2231/14 , B01J2231/54 , B01J2231/543 , B01J2531/0263 , B01J2531/821 , C07C2/32 , C07C6/04 , C07C67/313 , C07C67/475 , C07C2531/22 , C07C2531/24 , C08G61/08 , C07C69/593 , C07C13/20 , C07C11/02
摘要： The invention relates to a complex compound of ruthenium of the general structural formula I in which X1 and X2 may be identical or different and represent an anionic ligand, in which R1 and R2 are identical or different, but may also have a ring, in which R1 and R2 represent hydrogen or/and a hydrocarbon group, in which the ligand L1 is a N-heterocyclic carbene and in which the ligand L2 is a neutral electron donor, especially a N-heterocyclic carbene or an amine, imine, phosphane, phosphite, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, wherein R1, R2, R3 and R4 represent hydrogen or/and hydrocarbon groups. The invention relates also to a process for the preparation of acyclic olefins having two or more carbon atoms or/and of cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by olefin metathesis reaction in the presence of at least one catalyst, wherein such a complex compound is used as catalyst and wherein R′1, R′2, R′3 and R′4 hydrogen or/and hydrocarbon groups.
摘要翻译： 本发明涉及一般结构式I的钌络合物，其中X 1和X 2可以相同或不同，表示阴离子配体，其中R R 1和R 2相同或不同，但也可以具有环，其中R 1和R 2都是 >表示氢或/和烃基，其中配体L 1为N-杂环卡宾，其中配体L 2为中性电子给体，特别是 N-杂环卡宾或胺，亚胺，膦，亚磷酸酯，锑，胂，羰基化合物，羧基化合物，腈，醇，醚，硫醇或硫醚，其中R 1， 2，R 3和R 4代表氢或/和烃基。 本发明还涉及一种制备具有两个或更多个碳原子的非环烯烃和/或具有四个或更多个碳原子的具有两个或更多个碳原子的无环烯烃的环状烯烃和/或具有四个或更多个碳原子的环烯烃的环烯烃的方法 碳原子通过在至少一种催化剂的存在下进行烯烃复分解反应，其中这种配位化合物用作催化剂，并且其中R'1，R'2，R' 氢和/或氢和/或烃基。
-
10.发明申请ALKYLIDENE COMPLEXES OF RUTHENIUM CONTAINING N-HETEROCYCLIC CARBENE LIGANDS; USE AS HIGHLY ACTIVE, SELECTIVE CATALYSTS FOR OLEFIN METATHESIS 有权含有N-杂环碳酸酯配位体的亚甲基二胺的复合物; 用作高活性选择性催化剂，用于烯烃METATHESIS公开(公告)号：US20050013150A2
公开(公告)日：2005-01-20
申请号：US10630552
申请日：2003-07-29
IPC分类号： B01J31/22 , C07C2/32 , C07C67/313 , C07C67/475 , C07F15/00 , C08F2/60 , C08F4/80 , C08G61/06 , G11C19/08
CPC分类号： C07F15/0046 , B01J31/18 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/2404 , B01J31/26 , B01J2231/14 , B01J2231/54 , B01J2231/543 , B01J2531/0263 , B01J2531/821 , C07C2/32 , C07C6/04 , C07C67/313 , C07C67/475 , C07C2531/22 , C07C2531/24 , C08G61/08 , C07C69/593 , C07C13/20 , C07C11/02
摘要： Abstract of the Disclosure Akylidene complexes of ruthenium containing N-heterocyclic carbene ligands and their use as highly active, selective catalysts for olefin metathesisThe invention relates to a complex of ruthenium of the structural formula I, where X1 and X2 are identical or different and are each an anionic ligand, R1 and R2 are identical or different and can also contain a ring, and R1 and R2 are each hydrogen or/and a hydrocarbon group, the ligand L1 is an N-heterocyclic carbene and the ligand L2 is an uncharged electron donor, in particular an N-heterocyclic carbene or an amine, imine, phosphine, phosphite, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether,where R1, R2, R3 and R4 are hydrogen or/and hydrocarbon groups.The invention further relates to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by an olefin metathesis reaction in the presence of at least one catalyst, wherein a complex is used as catalyst and R'1, R'2, R'3 and R'4 are hydrogen or/and hydrocarbon groups.
摘要翻译： 公开摘要含有N-杂环卡宾配体的钌的亚甲基络合物及其作为烯烃复分解的高活性选择性催化剂的用途本发明涉及结构式I的钌络合物，其中X 1和X 2均为 相同或不同，并且各自为阴离子配体，R 1和R 2相同或不同，并且还可以含有环，R 1和R 2各自为氢或/或烃基， 配体L 1是N-杂环卡宾，配体L 2是不带电子的电子给体，特别是N-杂环卡宾或胺，亚胺，膦，亚磷酸酯，锑，胂，羰基化合物，羧基 化合物，腈，醇，醚，硫醇或硫醚，其中R 1，R 2，R 3和R 4是氢或/或烃基。本发明还涉及制备无环 具有两个或更多个碳原子的烯烃和/或具有四个或更多个碳原子的环烯烃从无环烯烃中浸出 在至少一种催化剂的存在下，通过烯烃复分解反应，使两个或更多个碳原子或/或具有四个以上碳原子的环状烯烃，其中使用络合物作为催化剂，R'1，R'2 >，R'3和R'4是氢或/和烃基。
-
-
-
-
-
-
-
-
-
搜索结果
19 条记录 (耗时 0.021 秒)
