Stabilizer system for the stabilisation of halogenated polymers

    公开(公告)号:US20060235124A1

    公开(公告)日:2006-10-19

    申请号:US10555021

    申请日:2004-04-02

    IPC分类号: C08K5/36

    CPC分类号: C08K5/17 C08K5/41 C08L57/08

    摘要: The invention relates to a mixture of stabilisers for the stabilisation of chlorinated polymers, comprising at least a) a sulphate ester salt and/or a sulphonate salt of formula (I): [R(O)aSO3]1M and b) an alkanolamine of formula (II), where M=alkali, earth alkali, lanthanide (Cer) or aluminium cation, t=metal cation valence of 1, 2 or 3; s=0 or 1, R=C1-C22 a phenyl, C7-C10 phenylalkyl, C7 -C24 alkylphenyl, x=1, 2 or 3: y=1, 2, 3, 4, 5 or 6; n=1-10. R1, R2 independently=H. C1-C22 alkyl, —[—(CHR3a)y—CHR3b—O—]a—H, —[—(CHR3a)y—CHR3b—O-]n-CO—R4, C2-C20 alkenyl, C2-C18 acyl, C4-C8 cycloalkyl, optionally substituted at the B-position by OH, C6-C10 aryl, C7-C10 alkaryl or C7-C10 aralkyl, or when x=1, R1 and R2 together with the N can form a closed 4-10 membered ring of carbon atoms with optionally up to 2 heteroatoms, or when x=2, R1 also=C2-C18 alkylene, optionally substituted at both B-carbon atoms with OH and/or interrupted by 1 or more O atoms and/or 1 or more NR2 groups, or dihydroxysubstituted tetrahydrodicyclopentadienylene, dihydroxysubstituted ethylcyclohexanylene, dihydroyxsubstituted 4,4′-bisphenol-A-dipropylether)ylene, isophoronylene, dimethylcyclohexanylene, dicyclohoxylmethanylene or 3,3′-dimethyldicyclohexylmethanylene and when x=3, R1 also=trihydroxysubstituted (tri-N-propylisocyanurate)triyl, R3a, R3b independently=C1-C22 alkyl, C2-C6 alkenyl) C6-C10 aryl, H or CH2—X—R5, where X═O, S, —O—CO— or —CO—O—; R4═C1-C18 alkyl/alkenyl or phenyl and R5═H, C1-C22 alkyl, C2-C22 alkenyl or C6-C10 aryl.

    Cyanoacetylureas for stabilizing halogenated polymers
    5.
    发明授权
    Cyanoacetylureas for stabilizing halogenated polymers 失效
    用于稳定卤化聚合物的氰基乙酰脲

    公开(公告)号:US06211270B1

    公开(公告)日:2001-04-03

    申请号:US09323975

    申请日:1999-06-02

    IPC分类号: C08K521

    CPC分类号: C08K5/315 C08K5/405 C08L27/06

    摘要: A description is given of compositions comprising a chlorine-containing polymer and at least one compound of the general formula I where x is oxygen or sulfur, and R is C2-C22-acyloxyalkyl or C1-C12-alkyl which may be interrupted by 1 to 3 oxygen atoms and/or substituted by 1 to 3 OH groups, or is C3-C8-alkenyl, C7-C10-phenylalkyl, C5-C8-cycloalkyl, C7-C10-alkylphenyl, phenyl or naphthyl, where the aromatic radical in each case may be substituted by —OH, C1-C12-alkyl and/or OC1-C4-alkyl, and R1 is hydrogen or is as defined for R.

    摘要翻译: 给出了包含含氯聚合物和至少一种通式I的化合物的组合物的描述,其中x是氧或硫,R是可被1至3个氧原子间隔的C 2 -C 22 - 酰氧基烷基或C 1 -C 12 - 烷基 或/或被1至3个OH基取代,或为C 3 -C 8 - 烯基,C 7 -C 10 - 苯基烷基,C 5 -C 8 - 环烷基,C 7 -C 10 - 烷基苯基,苯基或萘基,其中每种情况下的芳族基团可以是 被-OH,C 1 -C 12烷基和/或OC 1 -C 4烷基取代,R 1是氢或根据R定义。

    Stabiliser combinations for chlorine-containing polymers
    6.
    发明授权
    Stabiliser combinations for chlorine-containing polymers 失效
    含氯聚合物的稳定剂组合

    公开(公告)号:US06194494B1

    公开(公告)日:2001-02-27

    申请号:US09107848

    申请日:1998-06-30

    IPC分类号: C08K534

    摘要: A stabiliser combination, mainly for PVC, is described, comprising A) at least one compound of formula I  wherein R*1 and R*2 are each independently of the other C1-C12alkyl, C3-C6lkenyl, C5-C8cycloalkyl that is unsubstituted or substituted by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or by chlorine atoms, or C7-C9phenylalkyl that is unsubstituted or substituted at the phenyl ring by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or chlorine atoms, and R*1 and R*2 may additionally be hydrogen and C1-C12alkyl, and Y is S or O, and B) at least one compound from the following groups: B1) perchlorate compounds, B2) glycidyl compounds, B3) beta-diketones and beta-keto esters, B4) dihydropyridines and polydihydropyridines, B5) polyols and disaccharide alcohols, B6) sterically hindered amines (tetraalkylpiperidine compounds), B7) alkali aluminosilicates (zeolites), B8) hydrotalcites, B9) alkali aluminocarbonates (dawsonites), B10) alkali- (or alkaline earth-) carboxylates,-(bi)carbonates or -hydroxides, B11) antioxidants and lubricants and B12) organotin stabilisers.

    摘要翻译: 描述了主要用于PVC的稳定剂组合物,其包含A)至少一种式I化合物,其中R * 1和R * 2各自独立地为未取代或取代的其它C 1 -C 12烷基,C 3 -C 6烯基,C 5 -C 8环烷基 C1-C4烷基,C1-C4烷氧基,C5-C8环烷基或羟基或氯原子,或未被取代或在苯环被1至3个C 1 -C 4烷基取代的C 7 -C 9苯基烷基,C 1 -C 4烷氧基 ,C 5 -C 8环烷基或羟基或氯原子,R * 1和R * 2可以另外是氢和C 1 -C 12烷基,Y是S或O,和B)至少一种下列化合物:B1)高氯酸盐化合物 ,B2)缩水甘油基化合物,B3)β-二酮和β-酮​​酯,B4)二氢吡啶和聚二氢吡啶,B5)多元醇和二糖醇,B6)空间位阻胺(四烷基哌啶化合物),B7)碱铝硅酸盐(沸石),B8) 水滑石,B9)碱金属铝酸盐(片钠铝石),B10)碱 - (或碱) (b)抗氧化剂和润滑剂和B12)有机锡稳定剂。

    Novel stabilizer system for halogenous polymers
    8.
    发明申请
    Novel stabilizer system for halogenous polymers 审中-公开
    用于卤素聚合物的新型稳定剂体系

    公开(公告)号:US20060270765A1

    公开(公告)日:2006-11-30

    申请号:US10552917

    申请日:2004-04-07

    IPC分类号: C08K5/34

    CPC分类号: C08K5/16 C08K5/42 C08L57/08

    摘要: The invention relates to stabilising systems for stabilising chlorinated polymers. The inventive stabilising systems contain a) at least one type of perfluoroalkane sulfonate salt and b) at least one or several indoles of general formula (I) and/or urea of general formula (II) and/or alcanolamines of general formula (III) and/or amonouracils.

    摘要翻译: 本发明涉及用于稳定氯化聚合物的稳定体系。 本发明的稳定体系包含a)至少一种类型的全氟烷基磺酸盐和b)至少一种或几种通式(I)和/或通式(II)的脲和/或通式(III)的烷醇胺)的吲哚, 和/或氨our酸。

    Rigid PVC stabilised with N,N-dimethyl-6-aminouracils
    9.
    发明授权
    Rigid PVC stabilised with N,N-dimethyl-6-aminouracils 失效
    用N,N-二甲基-6-氨基尿嘧啶稳定的刚性PVC

    公开(公告)号:US5859100A

    公开(公告)日:1999-01-12

    申请号:US934986

    申请日:1997-09-22

    CPC分类号: C08K5/3462

    摘要: Compositions are described, comprisingA) rigid or semi-rigid PVC having a plasticiser content of up to 20%, andB) at least one compound of formula 1, ##STR1## wherein X is O or S, and R is H or phenyl, with the proviso that compounds from the groups of the perchlorate compounds, glycidyl compounds, beta-diketones, beta-keto esters, dihydropyridines, polydihydro-pyridines, polyols, disaccharide alcohols, sterically hindered amines (tetraalkylpiperidine compounds), alkali alumosilicates (zeolites), hydrotalcites, alkali alumocarbonates (dawsonites) are not present.

    摘要翻译: 描述了组合物,其包括A)具有高达20%的增塑剂含量的刚性或半刚性PVC,和B)至少一种式1化合物,其中X是O或S,R是H或苯基 条件是来自高氯酸盐化合物,缩水甘油基化合物,β-二酮,β-酮酯,二氢吡啶,聚二氢吡啶,多元醇,二糖醇,空间位阻胺(四烷基哌啶化合物),碱铝硅酸盐(沸石) ,水滑石,碱性碳酸铝(片钠土)不存在。