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公开(公告)号：US07393887B2
公开(公告)日：2008-07-01
申请号：US11395272
申请日：2006-04-03
摘要： A composition and process is disclosed for the stabilization of halogen-containing polymers. In particular, chlorine-containing polymers such as poly vinyl chloride (PVC) are stabilized by incorporating of a stabilizer mixture having at least a perchlorate salt and an alkanolamine.
摘要翻译： 公开了用于稳定含卤聚合物的组合物和方法。 特别地，通过加入至少含有高氯酸盐和链烷醇胺的稳定剂混合物来稳定含氯聚合物如聚氯乙烯（PVC）。
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公开(公告)号：US20060270765A1
公开(公告)日：2006-11-30
申请号：US10552917
申请日：2004-04-07
IPC分类号： C08K5/34
摘要： The invention relates to stabilising systems for stabilising chlorinated polymers. The inventive stabilising systems contain a) at least one type of perfluoroalkane sulfonate salt and b) at least one or several indoles of general formula (I) and/or urea of general formula (II) and/or alcanolamines of general formula (III) and/or amonouracils.
摘要翻译： 本发明涉及用于稳定氯化聚合物的稳定体系。 本发明的稳定体系包含a）至少一种类型的全氟烷基磺酸盐和b）至少一种或几种通式（I）和/或通式（II）的脲和/或通式（III）的烷醇胺）的吲哚， 和/或氨our酸。
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公开(公告)号：US5859100A
公开(公告)日：1999-01-12
申请号：US934986
申请日：1997-09-22
CPC分类号： C08K5/3462
摘要： Compositions are described, comprisingA) rigid or semi-rigid PVC having a plasticiser content of up to 20%, andB) at least one compound of formula 1, ##STR1## wherein X is O or S, and R is H or phenyl, with the proviso that compounds from the groups of the perchlorate compounds, glycidyl compounds, beta-diketones, beta-keto esters, dihydropyridines, polydihydro-pyridines, polyols, disaccharide alcohols, sterically hindered amines (tetraalkylpiperidine compounds), alkali alumosilicates (zeolites), hydrotalcites, alkali alumocarbonates (dawsonites) are not present.
摘要翻译： 描述了组合物，其包括A）具有高达20％的增塑剂含量的刚性或半刚性PVC，和B）至少一种式1化合物，其中X是O或S，R是H或苯基 条件是来自高氯酸盐化合物，缩水甘油基化合物，β-二酮，β-酮酯，二氢吡啶，聚二氢吡啶，多元醇，二糖醇，空间位阻胺（四烷基哌啶化合物），碱铝硅酸盐（沸石） ，水滑石，碱性碳酸铝（片钠土）不存在。
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4.发明授权
公开(公告)号：US5770643A
公开(公告)日：1998-06-23
申请号：US618591
申请日：1996-03-20
IPC分类号： C07D487/04 , C08K5/1515 , C08K5/34 , C08K5/3415 , C08K5/3462 , C08K5/52 , C08K5/524 , C08L27/06 , C08K5/04 , C08K5/09
CPC分类号： C07D487/04 , C08K5/3462
摘要： The invention relates to compositions comprising a) a chlorine-containing polymer and b) at least one compound containing at least one radical of the formula I ##STR1## in which A is the additional groups or atoms necessary to form an unsubstituted or substituted six-membered heterocyclic ring containing two nitrogen ring atoms.
摘要翻译： 本发明涉及包含a）含氯聚合物和b）至少一种含至少一个式I（I）的基团的化合物，其中A是形成未取代的或 含有两个氮环原子的取代的六元杂环。
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公开(公告)号：US5550276A
公开(公告)日：1996-08-27
申请号：US483624
申请日：1995-06-07
IPC分类号： C07F9/40 , C07F9/44 , C07F9/6518 , C07F9/6539 , C07F9/6541 , C07F9/6571 , C07F9/141 , C07F9/201
CPC分类号： C07F9/657181 , C07F9/4006 , C07F9/65182 , C07F9/6539 , C07F9/6541
摘要： Compounds of the general formula I ##STR1## in which n is 1, 2 or 3 and in which X is oxygen or sulfur, T has the meaning of --S--, --S--S--, --S--S--, --S--S--S--S--, --S--S--S--S--S--, ##STR2## and Y has the meaning of ##STR3## in which Z has the meaning of --H, --COR.sup.13, --COOR.sup.13 or --CONHR.sup.13, and Q has the meaning of oxygen or --NR.sup.0 --, and R.sup.1, R.sup.2, R.sup.0, R.sup.4 and R.sup.13 are as defined in claim 1, with the proviso that the compound of the formula C.sub.2 H.sub.5 --S--CH.sub.2 CH(OH)--P(OC.sub.2 H.sub.5).sub.2 is excepted.The invention also relates to compositions containing the compounds of the formula I and organic materials, for example functional liquids and, in particular, lubricants.
摘要翻译： 其中n为1,2或3并且其中X为氧或硫的通式I（I）化合物为T，具有-S-，-SS-，-SS-，-SSSS- ，-SSSSS-，
和Y具有 的含义，其中Z具有-H，-COR 13，-COOR 13或-CONHR 13的含义，Q具有氧或-NRO-的含义，并且R 1 ，R 2，R 0，R 4和R 13如权利要求1中所定义，条件是式C 2 H 5 -S-CH 2 CH（OH）-P（OC 2 H 5）2的化合物除外。 本发明还涉及含有式I化合物和有机材料（例如功能性液体，特别是润滑剂）的组合物。 -
公开(公告)号：US5344992A
公开(公告)日：1994-09-06
申请号：US60461
申请日：1993-05-11
IPC分类号： C07C45/45 , C07C49/76 , C07C49/782 , C07C49/82 , C07C49/835 , C07C319/20 , C07C323/22
CPC分类号： C07C49/76 , C07C319/20 , C07C45/455 , C07C49/782 , C07C49/82 , C07C49/835
摘要： There is disclosed a process for the preparation of 1,3-diketones of formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other C.sub.1 -C.sub.20 alkyl, phenyl or phenyl which is substituted by halogen, hydroxy, NO.sub.2, C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, C.sub.7 -C.sub.9 phenylalkyl or a radical of formula II--A--X--R.sub.4 (II) whereinA is C.sub.1 -C.sub.12 alkylene, phenylene or phenylene which is substituted by halogen, hydroxy, NO.sub.2, C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.12 alkylene which is substituted by hydroxy, halogen and/or alkoxy,X is oxygen or sulfur, andR.sub.4 is hydrogen, C.sub.1 -C.sub.18 alkyl, phenyl or phenyl which is substituted by halogen, hydroxy,C.sub.1 -C.sub.4 alkyl, NO.sub.2 and/or C.sub.1 -C.sub.4 alkoxy, or is C.sub.7 -C.sub.9 phenylalkyl, andR.sub.3 is hydrogen, C.sub.1 -C.sub.20 alkyl, phenyl or phenyl which is substituted by halogen, hydroxy, C.sub.1 -C.sub.4 alkyl, NO.sub.2 and/or C.sub.1 -C.sub.4 alkoxy, or is C.sub.7 -C.sub.9 phenylalkyl.The process comprises carrying out a Claisen condensation of a ketone of formula III ##STR2## and an ester of formula IV ##STR3## wherein R.sub.5 is C.sub.1 -C.sub.5 alkyl, phenyl or phenyl which is substituted by halogen, C.sub.1 -C.sub.4 alkyl or hydroxy, the reaction being carried out with the base used as catalyst, a hydride of an alkali metal or alkaline earth metal or an alcoholate of C.sub.1 -C.sub.5 alkali metal or C.sub.1 -C.sub.5 alkaline earth metal, in a mixture of dimethyl sulfoxide and at least one organic solvent which is inert under the reaction conditions.
摘要翻译： 公开了制备式I（I）的1,3-二酮的方法，其中R 1和R 2各自独立地为C 1 -C 20烷基，苯基或被卤素，羟基，NO 2取代的苯基， C 1 -C 4烷基和/或C 1 -C 4烷氧基，C 7 -C 9苯基烷基或式II -AX-R4（II）基团，其中A是被C 1 -C 12亚烷基取代的苯基或亚苯基，被卤素，羟基，NO 2，C 1 -C 4烷基和 或C 1 -C 4烷氧基，或者是被羟基，卤素和/或烷氧基取代的C 1 -C 12亚烷基，X是氧或硫，R 4是氢，C 1 -C 18烷基，苯基或被卤素取代的苯基，羟基，C 1 C 4烷基，NO 2和/或C 1 -C 4烷氧基，或者是C 7 -C 9苯基烷基，R 3是氢，C 1 -C 20烷基，苯基或被卤素，羟基，C 1 -C 4烷基，NO 2和/或C 1 -C 4烷氧基取代的苯基或 是C7-C9苯基烷基。 该方法包括进行式III的酮（III）和式IV的酯（IV）的酯或其中R 5是C 1 -C 5烷基的苯基或苯基的Claisen缩合 被卤素，C 1 -C 4烷基或羟基取代，所述反应用碱作为催化剂，碱金属或碱土金属的氢化物或C 1 -C 5碱金属或C 1 -C 5碱土金属的醇化物在 二甲基亚砜与至少一种在反应条件下为惰性的有机溶剂的混合物。
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公开(公告)号：US4931576A
公开(公告)日：1990-06-05
申请号：US213509
申请日：1988-06-28
IPC分类号： B01J31/02 , C07B61/00 , C07D207/26 , C07D207/27 , C07D213/70 , C07D215/36 , C07D277/36 , C07D277/74 , C07D285/12 , C07D285/125 , C07D301/27 , C07D303/34 , C10M135/24 , C10M135/26 , C10M135/28 , C10M135/32 , C10M137/10
CPC分类号： C07D207/27 , C07D213/70 , C07D215/36 , C07D277/36 , C07D277/74 , C07D285/125 , C07D303/34 , C10M135/24 , C10M135/26 , C10M135/28 , C10M135/32 , C10M137/105 , C10M2219/084 , C10M2219/085 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2223/047 , C10N2240/08
摘要： A process for producing glycidylthio ethers of the formula I ##STR1## which process comprises reacting epichlorohydrin with a mercaptan of the formula IIR--SH (II)in which R can be a radical ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 independently of one another are each C.sub.1 -C.sub.18 -alkyl, and together contain no more than 22 C atoms, and R.sup.2 and R.sup.3 are in addition hydrogen, or wherein R is C.sub.5 -C.sub.6 -cycloalkyl, phenyl or naphthyl unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, or is benzyl or furfuryl, or wherein R is C.sub.2 -C.sub.8 -alkylene which is substituted by --SH and which can be interrupted by 1 or 2 ether-O atoms, in an equimolar amount, without organic solvent and in the presence of a base, the reaction being performed by the phase-transfer catalysis process, wherein a phase-transfer catalyst is used, at a temperature of -30.degree. C. to +20.degree. C. The glycidyl thioethers thus obtained are compounds that play an important part in the synthesis of organic sulfur compounds, which are used for example as lubricant additives.
摘要翻译： 制备式I的缩水甘油硫醚的方法（I）该方法包括使表氯醇与式II R-SH（II）的硫醇反应，其中R可以是基团，其中R1，R2和R3 彼此独立地为C 1 -C 18 - 烷基，并且一起含有不超过22个C原子，并且R 2和R 3为氢，或其中R为C 5 -C 6 - 环烷基，未被取代或被C 1 -C 18取代的苯基或萘基， 或者是苄基或糠基，或其中R是被-SH取代且可以被1或2个醚-O原子间隔的C 2 -C 8 - 亚烷基等摩尔量，不含有机溶剂， 在-30℃〜+ 20℃的温度下，使用相转移催化剂进行相转移催化反应，由此得到的缩水甘油基硫醚为化合物 有机硫化合物的合成中的重要组成部分，例如用作润滑剂 nt添加剂。
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8.发明授权Lubricant compositions, novel glucamine derivatives and complex compounds containing same 失效润滑剂组合物，新型葡糖胺衍生物和含有它们的络合物
公开(公告)号：US4886610A
公开(公告)日：1989-12-12
申请号：US284582
申请日：1988-12-15
IPC分类号： C07C215/12 , C07C67/00 , C07C213/00 , C07C217/28 , C07C217/30 , C07C219/04 , C07C219/08 , C07C313/00 , C07C323/25 , C07C323/26 , C07C323/32 , C07F1/00 , C07F1/08 , C07F3/00 , C07F5/00 , C07F15/04 , C08K5/17 , C08K5/36 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C10M133/08 , C10M135/24 , C10M135/30 , C10M137/04 , C10M139/00 , C10M159/18 , C10N10/00 , C10N10/02 , C10N10/04 , C10N10/06 , C10N10/08 , C10N10/12 , C10N10/14 , C10N10/16 , C10N30/00 , C10N30/06 , C10N30/08 , C10N30/10 , C10N40/00 , C10N40/04 , C10N40/08 , C10N40/25 , C10N60/00
CPC分类号： C10M133/08 , C07F1/005 , C07F15/045 , C07F3/003 , C10M135/24 , C10M159/18 , C10M2215/042 , C10M2219/084 , C10M2227/09 , C10N2240/08
摘要： The invention relates to compositions comprising a lubricant or a hydraulic fluid and at least one compound of the general formula ##STR1## wherein n is 2, 3 or 4, X is --S--, --O--, --O--CO--or --CH.sub.2 --, R.sup.1 is C.sub.1 -C.sub.22 alkyl, C.sub.5 -C.sub.6 cycloalkyl or phenyl, and R.sup.2 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.2 -C.sub.4 alkyl which is substituted by an --OH group, or a group of the formula --CH.sub.2 --CH(OH)--CH.sub.2 --X--R.sup.1, wherein X and R.sup.1 have the given meanings, and to novel compounds of the formula indicated above. The glucamine derivatives of formula I are especially suitable for use as antiwear agents and as extreme pressure additives for mineral and synthetic lubricant oils and hydraulic fluids, and also as amphipolar ligands for imparting lipophilic properties to intrinsically hydrophilic metal salts, metal oxides, metal hydroxides and to protic acids. The complex compounds so obtained of the formulaM.sub.n.sup.m .multidot.X.sub.m.sup.n .multidot.pY.multidot.qZ,wherein M is a cation of valency m or a proton, X is an anion of valency n, Z is a compound of formula I, Y is water or a neutral organic molecule, p is a value from 0 to 2, q is a value from 1 to 8, m is an integer from 1 to 6 and n is an integer from 1 to 4, are also disclosed.
摘要翻译： 本发明涉及包含润滑剂或液压流体和至少一种通式（I）的化合物的组合物，其中n为2,3或4，X为-S-，-O-，-O-CO - 或-CH 2 - ，R 1是C 1 -C 22烷基，C 5 -C 6环烷基或苯基，R 2是氢，C 1 -C 8 - 烷基，被-OH基团取代的C 2 -C 4烷基， CH2-CH（OH）-CH2-X-R1，其中X和R1具有给定的含义，以及新的上述式化合物。 式I的葡糖胺衍生物特别适合用作抗磨剂和用作矿物和合成润滑油和液压油的极压添加剂，以及用作赋予亲水性亲水性质的本征亲水金属盐，金属氧化物，金属氢氧化物和 到质子酸。 如下得到的式MnmxXmnxpYxqZ的络合物，其中M是价态m或质子的阳离子，X是化合价n的阴离子，Z是式I化合物，Y是水或中性有机分子，p是 值为0〜2，q为1〜8的数，m为1〜6的整数，n为1〜4的整数。
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公开(公告)号：US4863621A
公开(公告)日：1989-09-05
申请号：US1783
申请日：1987-01-09
IPC分类号： C07D295/08 , C07C67/00 , C07C313/00 , C07C323/25 , C07D207/34 , C07D209/08 , C07D213/74 , C07D215/06 , C07D223/10 , C07D233/72 , C07D249/08 , C07D249/14 , C07D263/28 , C07D277/20 , C07D277/36 , C07D295/088 , C10M135/24 , C10M135/28 , C10M135/30 , C10M135/32 , C10M135/34 , C10M135/36 , C10N30/06 , C10N40/08 , C10N40/20
CPC分类号： C07D213/74 , C07C323/25 , C07D249/14 , C07D295/088 , C10M135/24 , C10M135/28 , C10M135/32 , C10M135/34 , C10M135/36 , C10M2201/02 , C10M2219/084 , C10M2219/086 , C10M2219/09 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10N2240/08 , C10N2240/40
摘要： Compositions containing a lubricant, a hydraulic fluid or a metal-working fluid and at least one compound of the formula I ##STR1## in which R, R.sup.4, R.sup.5 and n are as defined in claim 1, are described. The compounds of the formula I are suitable for use as anti-wear agents and as extreme-pressure additives for lubricants, hydraulic fluids and metal-working fluids. Novel compounds of the formula I are also described.
摘要翻译： 描述了含有润滑剂，液压油或金属工作流体的组合物和至少一种其中R，R 4，R 5和n如权利要求1中所定义的式I（I）的化合物。 式I的化合物适合用作抗磨剂和用作润滑剂，液压油和金属加工液的极压添加剂。 还描述了新的式I化合物。
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10.发明授权Hydraulic fluid compositions, novel glucamine derivatives and complex compounds containing same 失效液压油组合物，新型葡糖胺衍生物和含有它们的络合物
公开(公告)号：US4830770A
公开(公告)日：1989-05-16
申请号：US137269
申请日：1987-12-23
IPC分类号： C07C215/12 , C07C67/00 , C07C213/00 , C07C217/28 , C07C217/30 , C07C219/04 , C07C219/08 , C07C313/00 , C07C323/25 , C07C323/26 , C07C323/32 , C07F1/00 , C07F1/08 , C07F3/00 , C07F5/00 , C07F15/04 , C08K5/17 , C08K5/36 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C10M133/08 , C10M135/24 , C10M135/30 , C10M137/04 , C10M139/00 , C10M159/18 , C10N10/00 , C10N10/02 , C10N10/04 , C10N10/06 , C10N10/08 , C10N10/12 , C10N10/14 , C10N10/16 , C10N30/00 , C10N30/06 , C10N30/08 , C10N30/10 , C10N40/00 , C10N40/04 , C10N40/08 , C10N40/25 , C10N60/00
CPC分类号： C10M133/08 , C07F1/005 , C07F15/045 , C07F3/003 , C10M135/24 , C10M159/18 , C10M2215/042 , C10M2219/084 , C10M2227/09 , C10N2240/08
摘要： The invention relates to compositions comprising a lubricant or a hydraulic fluid and at least one compound of the general formula ##STR1## wherein n is 2, 3 or 4, X is --S--, --O--, --O--CO-- or --CH.sub.2 --, R.sup.1 is C.sub.1 -C.sub.22 alkyl, C.sub.5 -C.sub.6 cycloalkyl or phenyl, and R.sup.2 is hydrogen, C.sub.1 -C.sub.8 alkyl, C.sub.2 -C.sub.4 alkyl which is substituted by an --OH group, or a group of the formula --CH.sub.2 --CH(OH)--CH.sub.2 --X--R.sup.1, wherein X and R.sup.1 have the given meanings, and to novel compounds of the formula indicated above. The glucamine derivatives of formula I are especially suitable for use as antiwear agents and as extreme pressure additives for mineral and synthetic lubricant oils and hydraulic fluids, and also as amphipolar ligands for imparting lipophilic properties to intrinsically hydrophilic metal salts, metal oxides, metal hydroxides and to protic acids. The complex compounds so obtained of the formulaM.sub.n.sup.m. X.sub.m.sup.n. pY.qZ,wherein M is a cation of valency m or a proton, X is an anion of valency n, Z is a compound of formula I, Y is water or a neutral organic molecule, p is a value from 0 to 2, q is a value from 1 to 8, m is an integer from 1 to 6 and n is an integer from 1 to 4, are also disclosed.
摘要翻译： 本发明涉及包含润滑剂或液压流体和至少一种通式（I）的化合物的组合物，其中n为2,3或4，X为-S-，-O-，-O-CO - 或-CH 2 - ，R 1是C 1 -C 22烷基，C 5 -C 6环烷基或苯基，R 2是氢，C 1 -C 8烷基，被-OH基取代的C 2 -C 4烷基或式-CH 2 -CH OH）-CH 2 -X-R 1，其中X和R 1具有给定的含义，以及新的上述式化合物。 式I的葡糖胺衍生物特别适合用作抗磨剂和用作矿物和合成润滑油和液压油的极压添加剂，以及用作赋予亲水性亲水性质的本征亲水金属盐，金属氧化物，金属氢氧化物和 到质子酸。 如此获得的式Mnm的络合物。 Xmn。 pY.qZ，其中M是价态m或质子的阳离子，X是价数n的阴离子，Z是式I的化合物，Y是水或中性有机分子，p是0至2的值， q是1至8的值，m是1至6的整数，n是1至4的整数。
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