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    Organic electroluminescent device and display unit
    2.
    发明授权
    Organic electroluminescent device and display unit 失效
    有机电致发光器件和显示单元

    公开(公告)号：US06916552B2

    公开(公告)日：2005-07-12

    申请号：US10068353

    申请日：2002-02-06

    申请人： Naoyuki Ueda ,  Ichinori Takada ,  Tetsuo Shibanuma ,  Mari Ichimura ,  Shinichiro Tamura

    发明人： Naoyuki Ueda ,  Ichinori Takada ,  Tetsuo Shibanuma ,  Mari Ichimura ,  Shinichiro Tamura

    IPC分类号： H01L51/50 ,  C09K11/06 ,  H01L51/00 ,  H01L51/30 ,  B32B19/00 ,  B32B9/00 ,  H01J1/62 ,  H01J63/04

    CPC分类号： H01L51/0058 ,  H01L51/0059 ,  H01L51/5012 ,  H01L51/5048 ,  Y10S428/917 ,  Y10T428/10

    摘要： An organic electroluminescent device capable of blue emission with a high color purity, and a display unit capable of full-color display with high color expressivity by using the organic electroluminescent device are provided. The organic electroluminescent device includes at least a hole transportation layer and a luminescent layer held between a lower electrode to become an anode and an upper electrode to become a cathode in a state of lamination in that order from the anode side. The luminescent layer is made of a spiro compound, and the hole transportation layer is made of triphenylamine tetramer. Furthermore, the display unit includes organic electroluminescent devices as blue-emitting elements arrayed for a plurality of pixels.

    摘要翻译： 本发明提供能够实现高色纯度的蓝色发光的有机电致发光元件，以及能够通过使用有机电致发光元件具有高色彩表现力的全色显示的显示单元。 有机电致发光器件至少包括空穴传输层和保持在成为阳极的下电极之间的发光层和以从阳极侧依次层叠的状态成为阴极的上电极。 发光层由螺环化合物制成，空穴输送层由三苯基胺四聚体构成。 此外，显示单元包括作为用于多个像素排列的蓝色发光元件的有机电致发光器件。

    (1,4-phenylene)bis(methylene) phosphonic acid esters and (1,4-phenylene)bis(methylene) triphenyl phosphonium salt compounds
    3.
    发明授权
    (1,4-phenylene)bis(methylene) phosphonic acid esters and (1,4-phenylene)bis(methylene) triphenyl phosphonium salt compounds 失效
    （1,4-亚苯基）双（亚甲基）膦酸酯和（1,4-亚苯基）双（亚甲基）三苯基鏻盐化合物

    公开(公告)号：US06979746B2

    公开(公告)日：2005-12-27

    申请号：US10227671

    申请日：2002-08-26

    申请人： Mari Ichimura ,  Shinichiro Tamura ,  Tadashi Ishibashi ,  Ichinori Takada

    发明人： Mari Ichimura ,  Shinichiro Tamura ,  Tadashi Ishibashi ,  Ichinori Takada

    IPC分类号： C07C255/58 ,  C09K11/06 ,  H01L51/30 ,  H01L51/50 ,  C07F9/40 ,  C07F9/56

    CPC分类号： C09K11/06 ,  C07C255/58 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0081 ,  H01L51/5012 ,  H01L2251/308

    摘要： A diphosphonic acid ester of formula [VII] or [VII′] and a diphosphonium salt of formula [VIII] or [VIII′] are provided: wherein R75, R76, R75′ and R76′ may be the same or different and independently represent an alkyl or alkenyl group having from 1 to 4 carbon atoms, a cyclohexyl group or a phenyl group, R77, R78, R79 and R80 may be the same or different provided that at least three thereof are cyano groups and the others independently represent a hydrogen atom, a cyano group, a nitro group or a halogen atom, R77′, R78′, R79′ and R80′ may be the same or different and independently represent a group selected from a hydrogen atom and a halogen atom provided that at least three thereof are fluorine atoms and X represents a halogen atom. These compounds are useful as synthetic intermediates for the preparation of luminescent bis(aminostyryl)benzene compounds.

    摘要翻译： 提供式[Ⅶ]或[Ⅶ']的二膦酸酯和式[Ⅷ]或[Ⅷ']的二鏻盐：其中R 75，R 76， >，R 75'和R 76'可以相同或不同，并且独立地表示具有1至4个碳原子的烷基或烯基，环己基或 苯基，R 77，R 78，R 79，R 80和R 80可以相同或不同，条件是 其中至少三个为氰基，其余独立地表示氢原子，氰基，硝基或卤素原子，R 77'，R 78'， R 79'和R 80'可以相同或不同，独立地表示选自氢原子和卤素原子的基团，条件是其至少三个是氟原子 X表示卤素原子。 这些化合物可用作制备发光双（氨基苯乙烯基）苯化合物的合成中间体。

    Bis(aminostyryl)benzene compounds and synthetic intermediates thereof, and process for preparing the compounds and intermediates
    5.
    发明授权
    Bis(aminostyryl)benzene compounds and synthetic intermediates thereof, and process for preparing the compounds and intermediates 有权
    双（氨基苯乙烯基）苯化合物及其合成中间体，以及制备化合物和中间体的方法

    公开(公告)号：US06337167B1

    公开(公告)日：2002-01-08

    申请号：US09455724

    申请日：1999-12-06

    申请人： Mari Ichimura ,  Shinichiro Tamura ,  Tadashi Ishibashi ,  Ichinori Takada

    发明人： Mari Ichimura ,  Shinichiro Tamura ,  Tadashi Ishibashi ,  Ichinori Takada

    IPC分类号： C07C21154

    CPC分类号： C09K11/06 ,  C07C255/58 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0081 ,  H01L51/5012 ,  H01L2251/308

    摘要： To provide compounds, which are suitable for use as an organic luminescent material capable of developing intense luminescence which is yellow to red, and a process for preparing in general and high efficiency. A bis(aminostyryl)benzene compound of the following general formula [I] is provided wherein R2 and R3 independently represent an unsubstituted aryl group, and R1 and R4 independently represent an aryl group, and R5 to R8, independently represent a cyano group or the like. A process for the preparation thereof is described wherein a 4-(N,N-diarylamino)benzaldehyde and a diphosphonic acid ester or diphosphonium are subjected to condensation reaction. Intermediates of the bis(aminostyryl)benzene compound are also described.

    摘要翻译： 提供适合用作能够发展黄色至红色的强烈发光的有机发光材料的化合物，以及一般且高效制备的方法。 提供以下通式[I]的双（氨基苯乙烯基）苯化合物，其中R2和R3独立地表示未取代的芳基，R1和R4独立地表示芳基，R5至R8独立地表示氰基等 。 描述了其制备方法，其中使4-（N，N-二芳基氨基）苯甲醛和二膦酸酯或二鏻进行缩合反应。 还描述了双（氨基苯乙烯基）苯化合物的中间体。

    Organic light-emitting material and method for producing an organic material
    9.
    发明申请
    Organic light-emitting material and method for producing an organic material 审中-公开
    有机发光材料及其制造方法

    公开(公告)号：US20070149815A1

    公开(公告)日：2007-06-28

    申请号：US10595710

    申请日：2004-11-05

    申请人： Ichinori Takada ,  Naoyuki Ueda

    发明人： Ichinori Takada ,  Naoyuki Ueda

    IPC分类号： C07C211/60 ,  C07C211/61 ,  C09K11/06 ,  H01L51/54

    CPC分类号： H01L51/006 ,  C07C211/61 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1014 ,  H01L51/0054 ,  H01L51/0058 ,  H01L51/5012 ,  H05B33/14

    摘要： An organic light-emitting material characterized in that it is used in a light emitting layer in a green light emitting element and represented by the following general formula (1): wherein: n1 is an integer of 0 to 3; R1 is an alkyl group having 10 carbon atoms or less; Ar1 is a monovalent group which is derived from monocyclic or fused-ring aromatic hydrocarbon having 20 carbon atoms or less, and which optionally has a substituent having 10 carbon atoms or less; and Ar2 is a divalent group which is derived from a ring assembly having 30 carbon atoms or less and being comprised of monocyclic or fused-ring aromatic hydrocarbon having 1 to 3 rings, and which optionally has a substituent having 4 carbon atoms or less. There can be provided an organic light-emitting material which has satisfactorily excellent light emission efficiency and high color purity as well as higher reliability and which is advantageously used to constitute a green light emitting layer, and a method for producing the same.

    摘要翻译： 一种有机发光材料，其特征在于其用于绿色发光元件的发光层并由以下通式（1）表示：其中：n 1是整数0 到3; R 1是具有10个或更少碳原子的烷基; Ar 1是衍生自具有20个或更少碳原子的单环或稠环芳烃的单价基团，并且其任选具有10个或更少碳原子的取代基; 和Ar 2是衍生自具有30个或更少碳原子的环组合的二价基团，并且由具有1至3个环的单环或稠环芳烃组成，并且其任选具有取代基 具有4个或更少的碳原子。 可以提供发光效率好，色纯度高，可靠性高，有利地用于构成绿色发光层的有机发光材料及其制造方法。

    Organic Electroluminescent Element and Display Apparatus
    10.
    发明申请
    Organic Electroluminescent Element and Display Apparatus 审中-公开
    有机电致发光元件和显示装置

    公开(公告)号：US20080278065A1

    公开(公告)日：2008-11-13

    申请号：US10595563

    申请日：2004-11-05

    申请人： Naoyuki Ueda ,  Ichinori Takada

    发明人： Naoyuki Ueda ,  Ichinori Takada

    IPC分类号： H01L51/52

    CPC分类号： H05B33/14 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1014 ,  H01L51/0054 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/5012

    摘要： An organic electroluminescent element is characterized by having a light emitting layer (503) containing a fluoranthene derivative and emitting green light. The fluoranthene derivative is introduced as a guest into the light emitting layer, and, by using an organic material having a fluorescence spectrum overlapping the absorption spectrum of the fluoranthene derivative, e.g., an arylanthracene derivative as a host, the organic electroluminescent element advantageously emits green light with satisfactorily excellent light emission efficiency and high color purity and has higher reliability.

    摘要翻译： 有机电致发光元件的特征在于具有包含荧蒽衍生物并发出绿光的发光层（503）。 荧蒽衍生物作为客体引入发光层，并且通过使用具有与荧蒽衍生物（例如芳基蒽衍生物作为主体）的吸收光谱重叠的荧光光谱的有机材料，有机电致发光元件有利地发射绿色 具有令人满意的优异的发光效率和高的色纯度，并且具有更高的可靠性。