公开(公告)号：US20210246095A1

公开(公告)日：2021-08-12

申请号：US17302276

申请日：2021-04-29

申请人： ASM IP Holding B.V.

发明人： Timo Hatanpää ,  Miika Mattinen ,  Mikko Ritala ,  Markku Leskelä

IPC分类号： C07C49/92 ,  C07C45/77 ,  C23C16/30 ,  C23C16/455

摘要： Methods are provided for synthesizing W(IV) beta-diketonate precursors. Additionally, methods are provided for forming W containing thin films, such as WS2, WNx, WO3, and W via vapor deposition processes, such as atomic layer deposition (ALD) type processes and chemical vapor deposition (CVD) type processes. Methods are also provided for forming 2D materials containing W.

公开(公告)号：US11014866B2

公开(公告)日：2021-05-25

申请号：US16434834

申请日：2019-06-07

申请人： ASM IP Holding B.V.

发明人： Timo Hatanpää ,  Miika Mattinen ,  Mikko Ritala ,  Markku Leskelä

IPC分类号： C07C49/92 ,  C07C45/77 ,  C23C16/30 ,  C23C16/455

摘要： Methods are provided for synthesizing W(IV) beta-diketonate precursors. Additionally, methods are provided for forming W containing thin films, such as WS2, WNx, WO3, and W via vapor deposition processes, such as atomic layer deposition (ALD) type processes and chemical vapor deposition (CVD) type processes. Methods are also provided for forming 2D materials containing W.

公开(公告)号：US20180099916A1

公开(公告)日：2018-04-12

申请号：US15729210

申请日：2017-10-10

申请人： ASM IP Holding B.V.

发明人： Timo Hatanpää ,  Miika Mattinen ,  Mikko Ritala ,  Markku Leskelä

IPC分类号： C07C49/92 ,  C23C16/455 ,  C23C16/30 ,  C07C45/77

CPC分类号： C07C49/92 ,  C07C45/77 ,  C23C16/305 ,  C23C16/45553

摘要： Methods are provided for synthesizing W(IV) beta-diketonate precursors. Additionally, methods are provided for forming W containing thin films, such as WS2, WNx, WO3, and W via vapor deposition processes, such as atomic layer deposition (ALD) type processes and chemical vapor deposition (CVD) type processes. Methods are also provided for forming 2D materials containing W.

公开(公告)号：US08703386B2

公开(公告)日：2014-04-22

申请号：US13405587

申请日：2012-02-27

申请人： John David Bass ,  Ho-Cheol Kim ,  Robert Dennis Miller ,  Qing Song ,  Linda Karin Sundberg ,  Gregory Michael Wallraff

发明人： John David Bass ,  Ho-Cheol Kim ,  Robert Dennis Miller ,  Qing Song ,  Linda Karin Sundberg ,  Gregory Michael Wallraff

IPC分类号： G03F7/00 ,  G03F7/004 ,  G03F7/029 ,  C07C49/92 ,  C07C7/00

CPC分类号： G03F7/0042

摘要： Compositions are disclosed having the formula (3): [C′]k[Ta(O2)x(L′)y]  (3), wherein x is an integer of 1 to 4, y is an integer of 1 to 4, Ta(O2)x(L′)y has a charge of 0 to −3, C′ is a counterion having a charge of +1 to +3, k is an integer of 0 to 3, L′ is an oxidatively stable organic ligand having a charge of 0 to −4, and L′ comprises an electron donating functional group selected from the group consisting of carboxylates, alkoxides, amines, amine oxides, phosphines, phosphine oxides, arsine oxides, and combinations thereof. The compositions have utility as high resolution photoresists.

摘要翻译： 公开了具有式（3）的组合物：[C'] k [Ta（O 2）x（L'）y]（3）其中x是1至4的整数，y是1至4的整数， Ta（O 2）x（L'）y具有0至-3的电荷，C'是具有+1至+3的电荷的抗衡离子，k是0至3的整数，L'是氧化稳定的有机物 配体的电荷为0至-4，L'包括选自羧酸盐，醇盐，胺，氧化胺，膦，氧化膦，胂氧化物及其组合的给电子官能团。 该组合物具有作为高分辨率光致抗蚀剂的作用。

公开(公告)号：US20110171382A1

公开(公告)日：2011-07-14

申请号：US11949871

申请日：2007-12-04

申请人： Robin A. Gardiner ,  Peter S. Kirlin ,  Thomas H. Baum ,  Douglas Gordon ,  Connie L. Gordon ,  Timothy E. Glassman ,  Sophia Pombrik ,  Brian A. Vaarstra

发明人： Robin A. Gardiner ,  Peter S. Kirlin ,  Thomas H. Baum ,  Douglas Gordon ,  Connie L. Gordon ,  Timothy E. Glassman ,  Sophia Pombrik ,  Brian A. Vaarstra

IPC分类号： C23C16/06 ,  C07C49/92 ,  C07F7/28 ,  C07F7/00 ,  C07F7/24 ,  C07F5/00 ,  C09D1/00

CPC分类号： C23C16/409 ,  C07C49/92 ,  C07F7/003 ,  C23C16/18 ,  C23C16/305 ,  C23C16/40 ,  C23C16/405 ,  C23C16/408

摘要： A metalorganic complex composition comprising a metalorganic complex selected from the group consisting of: metalorganic complexes comprising one or more metal central atoms coordinated to one or more monodentate or multidentate organic ligands, and complexed with one or more complexing monodentate or multidentate ligands containing one or more atoms independently selected from the group consisting of atoms of the elements C, N, H, S, O and F; wherein when the number of metal atoms is one and concurrently the number of complexing monodentate or multidentate ligands is one, then the complexing monodentate or multidentate ligand of the metalorganic complex is selected from the group consisting of beta-ketoiminates, beta-diiminates, C2-C10 alkenyl, C2-C15 cycloalkenyl and C6-C10 aryl.

摘要翻译： 一种金属有机络合物组合物，其包含选自以下的金属有机络合物：包含与一个或多个单齿或多齿有机配体配位的一个或多个金属中心原子的金属有机络合物，并与一个或多个络合的单齿或多齿配位体络合，所述配位体含有一个或多个 独立地选自元素C，N，H，S，O和F的原子的原子; 其中当金属原子数为1并且同时复合单齿或多齿配体的数目为1时，金属有机络合物的络合单齿或多齿配体选自β-酮亚胺，β-二亚胺，C2- C10链烯基，C2-C15环烯基和C6-C10芳基。

公开(公告)号：US06963005B2

公开(公告)日：2005-11-08

申请号：US10631432

申请日：2003-07-31

申请人： Daniel David Lecloux ,  Nora Sabina Radu ,  Ying Wang

发明人： Daniel David Lecloux ,  Nora Sabina Radu ,  Ying Wang

IPC分类号： H01L51/50 ,  C07C49/92 ,  C07F9/50 ,  C07F15/00 ,  C07F19/00 ,  C09K11/06 ,  H01L51/00 ,  H01L51/30 ,  H01L51/42 ,  C07F9/02 ,  B23B15/00 ,  H01J1/62

CPC分类号： H01L51/0085 ,  C07F9/5077 ,  C07F15/0033 ,  C07F15/0086 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/185 ,  H01L51/0084 ,  H01L51/0086 ,  H01L51/0087 ,  H01L51/0088 ,  H01L51/42 ,  H01L51/5016 ,  Y10S428/917

摘要： Compounds comprising phosphorus-containing metal complexes can be used in electroluminescent devices and have an emission maximum closer to the blue region of the visible light spectrum. The complexes can be used within an organic active layer in electronic devices, such as displays, detectors, voltaic cells, solid-state lighting, illumination devices or the like. The complexes may also be used as catalysts or as indicators in other applications. The new compounds can be used without the need of a host material. In non-limiting embodiments, Pt or Ir may be used for the metal atom within the complex, one ligand may include a phosphorus-containing bidentate ligand, and another ligand may include a monoanionic bidentate ligand. The phosphorus-containing bidentate ligand may include a benzyl group, a phenoxy group, a phenylamino group, or the like.

摘要翻译： 包含含磷金属络合物的化合物可用于电致发光器件中，并具有更接近可见光谱蓝色区域的发射最大值。 复合物可用于电子设备中的有机活性层中，例如显示器，检测器，伏特电池，固态照明，照明装置等。 复合物也可用作催化剂或在其它应用中用作指示剂。 可以使用新的化合物而不需要主体材料。 在非限制性实施方案中，Pt或Ir可用于络合物内的金属原子，一个配体可包括含磷双齿配体，另一配体可包括单阴离子二齿配体。 含磷二齿配体可以包括苄基，苯氧基，苯基氨基等。

公开(公告)号：US20050175860A1

公开(公告)日：2005-08-11

申请号：US11033403

申请日：2005-01-12

申请人： Kwang-Hyun Kim ,  Dong-Uk Kim ,  Tae-Jeong Kim ,  Ung-Chan Yoon ,  Sung-Hoon Kim ,  Ki-Dong Kim

发明人： Kwang-Hyun Kim ,  Dong-Uk Kim ,  Tae-Jeong Kim ,  Ung-Chan Yoon ,  Sung-Hoon Kim ,  Ki-Dong Kim

IPC分类号： H01L51/50 ,  C07C49/92 ,  C07D213/06 ,  C07D213/26 ,  C07D217/02 ,  C07F15/00 ,  C09K11/06 ,  H05B33/14

CPC分类号： C07F15/0033 ,  Y10S428/917

摘要： The present invention relates to emitting compounds for organic electroluminescent device, particularly to phenyl pyridine-iridium metal complex compounds represented by the following formula (1): wherein R1 to R8, A1 to A3, and Py are as defined in the specification. In addition, the present invention relates to an organic electroluminescent device comprising the above material which has high luminescence efficiency, enhanced operating life time, and high purity of red chromaticity.

摘要翻译： 本发明涉及用于有机电致发光器件的发光化合物，特别涉及由下式（1）表示的苯基吡啶 - 铱金属络合物：其中R 1至R 8 - A 1，A 3，和Py如说明书中所定义。 此外，本发明涉及包含上述材料的有机电致发光器件，其具有高发光效率，增加的使用寿命和高纯度的红色度。

公开(公告)号：US20050119466A1

公开(公告)日：2005-06-02

申请号：US10500963

申请日：2002-12-18

申请人： Makoto Saito ,  Takashi Ueda ,  Takashi Tani

发明人： Makoto Saito ,  Takashi Ueda ,  Takashi Tani

IPC分类号： C07C45/45 ,  C07C45/77 ,  C07C49/12 ,  C07C49/92 ,  C07F5/00

CPC分类号： C07C49/92 ,  C07C45/455 ,  C07C45/77 ,  C07C49/12

摘要： Disclosed is a process for preparing 2,2,6,6-tetramethyl-3,5-heptanedione, comprising reacting a pivalic acid alkyl ester with pinacolone in the presence of an alkali metal alkoxide catalyst using a pivalic acid alkyl ester as a solvent but using no other solvent or reacting them in an amide type or urea type solvent in the presence of an alkali metal alkoxide catalyst. Also disclosed is a process for preparing a 2,2,6,6-tetramethyl-3,5-heptanesione metal complex using the 2,2,6,6-tetramethyl-3,5-heptanedione obtained by the above process. The process for preparing 2,2,6,6-tetramethyl-3,5-heptanedione is an industrially advantageous process in which an alkali metal alkoxide that is easy to handle can be used-as a catalyst for preparing 2,2,6,6-tetramethyl-3,5-heptanedione from a pivalic acid alkyl ester and pinacolone.

摘要翻译： 公开了一种制备2,2,6,6-四甲基-3,5-庚二酮的方法，包括在碱金属醇盐催化剂存在下，使用新戊酸烷基酯作为溶剂使新戊酸烷基酯与频那酮酮反应，但 不使用其它溶剂或在酰胺型或尿素型溶剂中，在碱金属醇盐催化剂的存在下反应。 还公开了使用通过上述方法获得的2,2,6,6-四甲基-3,5-庚二酮制备2,2,6,6-四甲基-3,5-庚内酯金属络合物的方法。 制备2,2,6,6-四甲基-3,5-庚二酮的方法是工业上有利的方法，其中可以使用易于处理的碱金属醇盐 - 作为制备2,2,6,6-四甲基-3,5-庚二酮的催化剂， 由新戊酸烷基酯和频哪醇酮制备6-四甲基-3,5-庚二酮。

公开(公告)号：US20050100511A1

公开(公告)日：2005-05-12

申请号：US11011668

申请日：2004-12-14

申请人： Vladimir Grushin ,  Norman Herron ,  Viacheslav Petrov ,  Nora Radu ,  Ying Wang

发明人： Vladimir Grushin ,  Norman Herron ,  Viacheslav Petrov ,  Nora Radu ,  Ying Wang

IPC分类号： H01L51/50 ,  C07C49/92 ,  C07D213/26 ,  C07D213/89 ,  C07D217/08 ,  C07F5/00 ,  C07F9/53 ,  C07F19/00 ,  C09K11/06 ,  A61K49/00

CPC分类号： C09K11/06 ,  C07F9/5345 ,  C09K2211/10 ,  C09K2211/1003 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1018 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/182 ,  Y10S428/917

摘要： The present invention is generally directed to luminescent lanthanide compounds with phosphine oxide, phosphine oxide-sulfide, pyridine N-oxide, and phosphine oxide-pyridine N-oxide ligands. It also relates to electronic devices in which the active layer includes a lanthanide complex.

公开(公告)号：US6111124A

公开(公告)日：2000-08-29

申请号：US224614

申请日：1998-12-31

申请人： Thomas H. Baum ,  Raymond H. Dubois

发明人： Thomas H. Baum ,  Raymond H. Dubois

IPC分类号： C07C49/92 ,  C07F9/94 ,  C23C16/18 ,  C23C16/40 ,  H01L21/316

CPC分类号： C23C16/409 ,  C07F9/94 ,  Y10S427/101

摘要： Anhydrous mononuclear Lewis base adducted tris(.beta.-diketonato) bismuth complexes, useful as precursors for chemical vapor deposition of bismuth, for producing Bi-containing films of significantly improved stoichiometry, morphology and functional character, as compared to films obtained from dinuclear tris(.beta.-diketonato) bismuth complexes of the prior art.

摘要翻译： 无水单核路易斯碱加合的三（β-二酮）铋络合物，可用作铋的化学气相沉积的前体，用于生产具有显着改善的化学计量，形态和功能特征的含Bi膜，与从二核三（β 二酮）铋络合物。