摘要:
Liquid crystalline compounds having a comparatively high voltage holding ratio, high &Dgr;n and high &Dgr;&egr;, and excellent miscibility with known liquid crystalline compounds at low temperatures. The novel compounds have the formula (1) wherein R represents hydrogen atom or an alkyl group having 1 to 20 carbon atoms; n1 and n2 are independently 0, 1, or 2 provided that the sum of n1 and n2 is 1 or 2; ring A and ring B independently represent 1,4-phenylene, fluorine substituted 1,4-phenylene expressed by the formula (a) in the specification or 1,4-cyclohexylene provided that at least one of ring A and ring B is fluorine substituted 1,4-phenylene expressed by the formula (a); Za, Zb, and Zc independently represent single bond, —CH2CH2—, —COO—, —CF2O—, or —CH2CH2CH2CH2—; Q1, Q2, Q3, Q4, Q5, Q6, and Q7 independently represent hydrogen atom, a halogen atom, or methyl group provided that when at least one of Za, Zb, and Zc is —CH2CH2—, then Q2 is fluorine atom, and that when Za, Zb, and Zc are all single bonds, then Q1, Q2, Q3, Q4, Q5, Q6, and Q7 independently represent hydrogen atom or fluorine atom; Y represents hydrogen atom, a halogen atom, or a halogenated alkyl group having 1 to 5 carbon atoms; and each atom constituting this compound may be replaced by its isotope.
摘要:
A compound expressed by the general formula (1): wherein R1 denotes an alkyl group having from 1 to 20 carbon atoms in which one or more methylene groups in said group may be replaced by oxygen atoms or —CH═CH— and one or more hydrogen atoms in said group may be replaced by flourine or chlorine atoms, with the proviso that two or more methylene groups may not be continuously replaced by oxygen atoms, Y1 denotes an alkoxy group having 1 to 5 carbon atoms, in which at least one hydrogen atom is replaced by a fluorine atom and one or more hydrogen atoms may be further replaced by chlorine atoms, Z1, Z2 and Z3 each independently denote a covalent bond, —CH2CH2—, —CH═CH—, —COO— or —CF2)—, with the proviso that at least one of Z1, Z2 and Z3 is —COO— or —CF2O—, rings A1, A2, A3 and A4 each independently denote trans-1,4-cyclohexylene, 3-cyclohexen-1,4-ylene, 3-fluoro-3-cyclohexen-1,4-ylene, pyrimidine-2,5-diyl, 1,3-dioxan-2,5-diyl, trans-1-sila-1,4-cyclohexylene, trans-4-sila-1,4-cyclohexylene, or 1,4-phenylene in which one or more hydrogen atoms may be replaced by fluorine atoms or chlorine atoms, and m and n denote 0 or 1, with the proviso that when Z1, Z2 or Z3 is —CF2O—, then at least two groups selected from rings A1, A2, A3 and A4 directly bonded to —CF2O— are both 1,4-phenylene in which one or more hydrogen atoms may be replaced by fluorine atoms or chlorine atoms, and any of the rings A1, A2 and A3 bonded with the carbon atoms of —CF2O— is 1,4-phenylene in which at least one hydrogen atom is replaced by fluorine or chlorine atoms.
摘要:
A compound expressed by the general formula (1): whereinR.sup.1 denotes an alkyl group having 1 to 20 carbon atoms in which one or more methylene groups in said group may be replaced by oxygen atoms or --CH.dbd.CH-- and one or more hydrogen atoms in said group may be replaced by fluorine or chlorine atoms, with the proviso that two or more methylene groups may not be continuously replaced by oxygen atoms;Y.sup.1 denotes a halogen atom, CN, CF.sub.3, CHF.sub.2 or an alkoxy group having 1 to 5 carbon atoms, in which at least one hydrogen atom is replaced by a fluorine atom and one or more hydrogen atoms may be further replaced by chlorine atoms;Z.sup.1, Z.sup.2 and Z.sup.3 each independently denote a covalent bond, --CH.sub.2 CH.sub.2 --, --CH.dbd.CH-- or CF.sub.2 O--, with the proviso that at least one of Z.sup.1, Z.sup.2, and Z.sup.3 is --CF.sub.2 O--;rings A.sup.1, A.sup.2 and A.sup.3 each independently denote trans-1,4-cyclohexylene, 3-cyclohexene-1,4-ylene, 3-fluoro-3-cyclohexene-1,4-ylene, pyrimidine-2,5-diyl, 1,3-dioxane-2,5-diyl, trans-1-sila-1,4-cyclohexylene, trans-4-sila-1,4-cyclohexylene or 1,4-phenylene in which one or more hydrogen atoms may be replaced by fluorine atoms or chlorine atoms,with the proviso thatring A.sup.1, A.sup.2 or A.sup.3 bonded with the carbon atom of --CF.sub.2 O-- is a member selected from the group consisting of trans-1,4-cyclohexylene, 3-cyclohexene-1,4-ylene, and 3-fluoro-3-cyclohexene-1,4-ylene;ring A.sup.4 denotes 1,4-phenylene in which one or more hydrogen atoms may be replaced by fluorine atoms or chlorine atoms; andm and n each independently denote 0 or 1.
摘要:
There is provided a liquid crystal composition in particular with a low threshold voltage and a wide range of nematic phase temperature (with high TNI point and low TC), while satisfying various properties required for liquid crystal compositions for active matrix type liquid crystal display elements. The composition contains, for example, compounds represented by general formulas (1-1) and (2-1): ##STR1## where each R.sub.1 independently represents an alkyl group having 1 to 10 carbon atoms; X.sub.1 represents H or F; and each X.sub.2 independently represents F, OCF.sub.3, CF.sub.3, or OCF.sub.2 H.
摘要:
A liquid crystal composition is disclosed which comprises: as a first component at least one of the compounds of the following formulas (1-1) and (1-2); as a second component at least one of the compounds of the following formula (2); as a third component at least one of the compounds of the following formulas (3-1) and (3-2); and as a fourth component at least one of the compounds of the following formulas (4-1) to (4-3)
摘要:
A novel liquid crystal composition comprising three components: at least one difluoro-oxymethane derivative, at least one trifluorophenyl derivative and a monofluorophenyl dervivative. The composition exhibits a high voltage holding ratio at high temperatures, sufficiently low threshold voltage and large optical anisotropy, while satisfying general characteristics required for the AM-LCD display mode.
摘要:
A liquid crystal composition is disclosed which comprises three components. The first component comprises at least one of the compounds of the following formulas (1-1) and (1-2). The second component comprises at least one of the compounds of the following formula (2). The third component comprises at least one of the compounds of the following formulas (3-1) to (3-4). ##STR1## Each symbol in formulas (1-1) to (3-4) is defined in the specification. The liquid crystal composition has low threshold voltage and high stability to hear and ultraviolet rays while satisfying general characteristics required for the STN display mode.
摘要:
A chiral, nematic liquid crystal composition suitable to STN-LCD, having superior steepness, rapid response and being able to prevent occurrence of high order and low order domain of LCD, which composition contains as a first component, at least one compound expressed by the formula (1) ##STR1## as a second component, at least one compound expressed by the formula (2) ##STR2## and as a third component, at least one compound of benzonitrile group, ##STR3## and further having a chiral dopant as a fourth component. In the above formulas, R.sup.1 and R.sup.2 each represent a linear alkyl group of 1 to 10 carbon atoms, A and B each represent trans-1,4-cyclohexylene or 1,4-phenylene, and R.sup.3 represents a linear alkyl group of 1 to 10 carbon atoms, or a group wherein an optional --CH.sub.2 -- or two or more not adjacent --CH.sub.2 --s present in the above group are replaced by --O-- or --CH=CH--; X.sup.1 and X.sup.2 each independently represent H or F; C represents --COO--, --C.sub.2 H.sub.4 --, trans-1,4-cyclohexylene or 1,4-phenylene; and n represents 0 or 1, and as a fourth component, a chiral dopant in a quantity in which a ratio (d/p) of the thickness (d.mu.m) of a liquid crystal layer in a liquid crystal cell to be filled with the liquid crystal composition to the helical pitch thereof (p.mu.m) is 0.03 to 2.0.
摘要:
A liquid crystal composition having a low threshold voltage and a suitably large optical anisotropy, while retaining a high specific resistance value, is provided,which composition is composed of compounds expressed by the formulas (1), (2) and (4): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.4 each represent an alkyl group of 1 to 10C; n represents 0 or 1; A.sup.1, A.sup.2, A.sup.3 and A.sup.4 represent trans-1,4-cyclohexylene or 1,4-phenylene; Z.sup.1, Z.sup.3 and Z.sup.4 represent --C.sub.2 H.sub.4 -- or a single bond; and X.sup.1, X.sup.4 and X.sup.5 represent H or F,use of which composition can realize an active matrix type liquid crystal display element of a low drive voltage, a low power consumption and a high speed response.
摘要翻译:提供具有低阈值电压和适当大的光学各向异性同时保持高电阻值的液晶组合物,该组成由式(1),(2)和(4)表示的化合物组成:本文 R1,R2和R4各自表示1〜10的烷基; n表示0或1; A1,A2,A3和A4表示反式-1,4-亚环己基或1,4-亚苯基; Z 1,Z 3和Z 4表示-C 2 H 4 - 或单键; X1,X4和X5表示H或F,使用哪种组合可以实现低驱动电压,低功耗和高速响应的有源矩阵型液晶显示元件。
摘要:
A liquid crystal composition used for a display element using TN (twisted nematic) mode or STN (super-twisted nematic) mode, having reduced threshold voltage and temperature dependency is provided,which composition is constituted by the following formulas (1) and (2): ##STR1## wherein R.sup.1 and R.sup.2 are an alkyl group of 1 to 10C; A.sup.1 and A.sup.2 each independently are 1,4-cyclohexylene or 1,4-penylene;n is 0 or 1; and X is H or F, andwhen the liquid crystal composition of the present invention is used, it is possible to realize a liquid crystal display element superior in low voltage drive, low power consumption and contrast.