公开(公告)号：US06403841B1

公开(公告)日：2002-06-11

申请号：US09856303

申请日：2001-07-24

申请人： Yasuhiro Iwasawa ,  Youzhu Yuan ,  Takafumi Shido ,  Nobuhiro Tamura

发明人： Yasuhiro Iwasawa ,  Youzhu Yuan ,  Takafumi Shido ,  Nobuhiro Tamura

IPC分类号： C07C4330

CPC分类号： B01J23/36 ,  C07C41/09 ,  C07C41/50 ,  C07C43/043 ,  C07C43/303

摘要： An object of the present invention is to provide a catalyst for a lower alcohol oxidation reaction which makes possible to manufacture a partial oxide of a lower alcohol such as dimethoxymethane or the like selectively and efficiently by direct oxidation of a lower alcohol such as methanol or the like, and to provide a method for manufacturing a partial oxide of a lower alcohol such as dimethoxymethane or the like selectively and efficiently from a lower alcohol such as methanol or the like by using this catalyst for a lower alcohol oxidation reaction. A partial oxide of a lower alcohol such as dimethoxymethane or the like is manufactured by subjecting a lower alcohol to vapor phase contact oxidation with a molecular oxygen-containing gas in the presence of an oxidation reaction catalyst for a lower alcohol composed of a rhenium-antimony compound oxide such as SbRe2O6 or the like. When the vapor phase contact oxidation is conducted, in particular, at a temperature of 300 to 400° C., dimethoxymethane can be manufactured highly selectively.

摘要翻译： 本发明的目的是提供一种用于低级醇氧化反应的催化剂，其可以通过直接氧化低级醇如甲醇或其它醇来选择性和有效地制备低级醇如二甲氧基甲烷等的部分氧化物 并且提供通过使用该低级醇氧化反应用催化剂从低级醇如甲醇等中选择性且有效地制备低级醇如二甲氧基甲烷等的部分氧化物的方法。 在由铼 - 锑组成的低级醇的氧化反应催化剂的存在下，通过使含低分子量的气体进行气相接触氧化来制造低级醇如二甲氧基甲烷等的部分氧化物 复合氧化物如SbRe 2 O 6等。 进行气相接触氧化时，特别是在300〜400℃的温度下，能够高选择性地制造二甲氧基甲烷。

公开(公告)号：US06475948B1

公开(公告)日：2002-11-05

申请号：US09831407

申请日：2001-09-07

申请人： Yasuhiro Iwasawa ,  Takafumi Shido ,  Haichao Liu

发明人： Yasuhiro Iwasawa ,  Takafumi Shido ,  Haichao Liu

IPC分类号： B01J2300

CPC分类号： C07C253/26 ,  B01J23/002 ,  B01J23/18 ,  B01J23/36 ,  B01J2523/00 ,  C07C253/24 ,  Y02P20/52 ,  C07C255/08 ,  B01J2523/53 ,  B01J2523/74 ,  C07C255/07

摘要： An object of the present invention is to provide an ammoxidation reaction catalyst composed of an Sb—Re compound oxide with which ammoxidation into an unsaturated nitrile such as methacrylonitrile or the like can be performed in the presence of a molecular oxygen-containing gas and ammonia, and a method for manufacturing an unsaturated nitrile such as methacrylonitrile or the like from an aliphatic hydrocarbon such as isobutylene, isobutane or the like using this ammoxidation reaction catalyst. An unsaturated nitrile such as methacrylonitrile or the like is manufactured by subjecting an aliphatic hydrocarbon such as isobutylene, isobutane or the like to vapor phase contact ammoxidation with ammonia and a molecular oxygen-containing gas in the presence of an ammoxidation reaction catalyst composed of an Sb—Re compound oxide such as SbRe2O6 or the like.

摘要翻译： 本发明的目的是提供一种由Sb-Re复合氧化物组成的氨氧化反应催化剂，其可以在含分子氧的气体和氨的存在下进行氨基氧化成不饱和腈如甲基丙烯腈等， 以及使用该氨氧化反应催化剂从异丁烯，异丁烷等脂肪族烃制造不饱和腈如甲基丙烯腈等的方法。 通过使异丁烯，异丁烷等脂族烃与氨和含分子氧的气体在由Sb组成的氨氧化反应催化剂存在下进行气相接触氨氧化，制造甲基丙烯腈等不饱和腈 -Re复合氧化物如SbRe 2 O 6等。

公开(公告)号：US5864051A

公开(公告)日：1999-01-26

申请号：US966738

申请日：1997-11-10

申请人： Yasuhiro Iwasawa ,  Kiyotaka Asakura ,  Tomoya Inoue

发明人： Yasuhiro Iwasawa ,  Kiyotaka Asakura ,  Tomoya Inoue

IPC分类号： B01J23/644 ,  C07C45/33 ,  C07C45/34

CPC分类号： C07C45/33 ,  B01J23/6445

摘要： A catalyst for the selective oxidation of alkanes and alkenes has been developed. The catalyst consists of a noble metal component such as platinum and a SbOx component. A unique feature of the catalyst is that the noble metal component is present as particles of which from about 1 to about 30 mole % of each particle is in the form of a noble metal/Sb alloy. Optionally a modifier and/or a refractory inorganic oxide may also be added to the catalyst. A process for preparing the catalyst is also presented.

摘要翻译： 已经开发了用于选择性氧化烷烃和烯烃的催化剂。 催化剂由贵金属组分如铂和SbO x组分组成。 催化剂的独特特征在于，贵金属组分以颗粒形式存在，其中每个颗粒的约1至约30摩尔％为贵金属/ Sb合金的形式。 任选地，还可以向催化剂中加入改性剂和/或耐火无机氧化物。 还提出了制备催化剂的方法。