公开(公告)号：US07164026B2

公开(公告)日：2007-01-16

申请号：US10704576

申请日：2003-11-12

申请人： Yasuhiro Uozumi ,  Heiko Hoche ,  Kenzo Sumi

发明人： Yasuhiro Uozumi ,  Heiko Hoche ,  Kenzo Sumi

IPC分类号： C07F7/02 ,  C07D413/02

CPC分类号： C07D263/12 ,  C07D263/14 ,  Y02P20/582

摘要： A polymer-carrying optically active binaphthyl type oxazoline compound having axial asymmetry, represented by the following general formula (1) (wherein R1 and R2 may be the same or different from each other and each represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms or the like; R3 is a hydrogen atom or —R5—X—R6; R4 is a hydrogen atom or the like; R5 is a straight- or branched-chain aliphatic hydrocarbon chain which may have a directly or indirectly bonded substituent; X is CH2, CO2, O, CONR7 or NR7; R6 is a directly or indirectly bonded polymer; and R7 is a hydrogen atom or the like), and to a transition metal complex which uses the compound as the ligand.

摘要翻译： 由以下通式（1）表示的具有轴不对称性的聚合物携带光学活性的联萘型恶唑啉化合物（其中R 1和R 2可以相同或不同） 彼此分别表示氢原子，碳原子数为1〜6的烷基等; R 3是氢原子或-R 5 -SR R 4是氢原子等; R 5是直链或支链脂族烃链，其可以具有 直接或间接键合的取代基; X是CH 2，CO 2，O，CONR 7或NR 7; R 6是直接或间接结合的聚合物; R 7是氢原子等）和使用该化合物作为配体的过渡金属络合物。