Production of hydrogen
    2.
    发明授权
    Production of hydrogen 失效
    生产氢气

    公开(公告)号:US4202744A

    公开(公告)日:1980-05-13

    申请号:US38925

    申请日:1979-05-14

    IPC分类号: C25B1/02

    CPC分类号: C25B1/02

    摘要: Hydrogen is produced in a cyclic metals oxidation/carbon reduction process. In particular, elemental iron or cobalt is oxidized in an aqueous solution of an alkali metal hydroxide with the simultaneous generation of hydrogen. The iron or cobalt oxidation products of the reaction are thereafter reduced to elemental iron or cobalt by contact with a carbonaceous reducing agent at elevated temperatures and the reduced material recycled for reoxidation. In an alternate operation, hydrogen is produced in a cyclic electrolytic/carbon reduction process wherein elemental iron or cobalt is electrolytically converted to corresponding oxidation products with the simultaneous generation of hydrogen. The electrolytic cell used in this process comprises a cathode, a magnetic anode that is adapted to attract and retain iron and/or cobalt particles and an aqueous electrolyte. In the electrolytic cell, hydrogen is produced at the cathode and metal particles contained on the magnetic electrode are oxidized to a non-ferromagnetic specie, such as ferrous hydroxide. The non-ferromagnetic species are recovered from the electrolytic cell and thereafter reconverted to particulate elemental iron and/or cobalt by treating the material with a carbonaceous reductant at an elevated temperature.

    摘要翻译: 在循环金属氧化/碳还原过程中产生氢。 特别地,元素铁或钴在碱金属氢氧化物的水溶液中被氧化,同时产生氢。 然后通过在高温下与碳质还原剂接触将反应的铁或钴氧化产物还原成元素铁或钴,并将还原的材料再循环用于再氧化。 在替代操作中,在循环电解/碳还原过程中产生氢气,其中将元素铁或钴电解转化为相应的氧化产物同时产生氢气。 在该方法中使用的电解池包括阴极,适于吸引和保留铁和/或钴颗粒的磁性阳极和水性电解质。 在电解池中,在阴极处产生氢,并且包含在磁极上的金属颗粒被氧化成非铁磁性物质,例如氢氧化亚铁。 非电磁物质从电解池回收,然后通过在高温下用碳质还原剂处理该材料而再转化为颗粒状元素铁和/或钴。

    Process for the removal of acid gases from hydrocarbon gases containing
the same
    3.
    发明授权
    Process for the removal of acid gases from hydrocarbon gases containing the same 失效
    从含有该气体的烃气体中除去酸性气体的方法

    公开(公告)号:US4460385A

    公开(公告)日:1984-07-17

    申请号:US444856

    申请日:1982-11-26

    IPC分类号: B01D53/14 C07C7/11

    摘要: Disclosed is a process for selectively removing one or more acid gases from hydrocarbon feed streams containing the same using hydroxyalkyl pyrrolidones as a physical solvent for each of the acid gases or aqueous mixtures containing the physical solvent. The process may be operated using the generalized flow sheet of a typical industrial acid gas treating plant as shown in FIG. 1.

    摘要翻译: 公开了一种使用羟烷基吡咯烷酮作为每种含有物理溶剂的酸性气体或含水混合物的物理溶剂来选择性地从其含有该酸的烃进料流中除去一种或多种酸性气体的方法。 该方法可以使用如图1所示的典型工业酸性气体处理设备的通用流程图来操作。 1。