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公开(公告)号：US5288369A
公开(公告)日：1994-02-22
申请号：US796608
申请日：1991-11-22
申请人： Yoichi Ishibashi , Yoshitaka Miyauchi , Koji Hamaguchi , Hideaki Urushibata , Hiromichi Takahashi , Takanobu Shiroishi
发明人： Yoichi Ishibashi , Yoshitaka Miyauchi , Koji Hamaguchi , Hideaki Urushibata , Hiromichi Takahashi , Takanobu Shiroishi
IPC分类号： D21C5/02
CPC分类号： D21C5/027 , Y02W30/648
摘要： A deinking composition for use in the reclamation of waste paper consisting essentially of a mixture of higher fatty acids having 8 to 24 carbon atoms, or salts thereof, wherein the average carbon atom number of said fatty acids in said mixture ranges from 12.7 to 21.5, and wherein the content of higher fatty acids having 20 to 24 carbon atoms or salts thereof, ranges from 9.6 to 70.6% by weight, said mixture having an iodine value (IV) of not greater than 45.
摘要翻译： 用于回收基本上由具有8至24个碳原子的高级脂肪酸的混合物或其盐组成的废纸的脱墨组合物，其中所述混合物中所述脂肪酸的平均碳原子数为12.7至21.5， 并且其中具有20-24个碳原子的高级脂肪酸或其盐的含量为9.6至70.6重量％，所述混合物的碘值（IV）不大于45。
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公开(公告)号：US5282928A
公开(公告)日：1994-02-01
申请号：US889962
申请日：1992-05-29
申请人： Hiromichi Takahashi , Yoichi Ishibashi , Yoshitaka Miyauchi , Takanobu Shiroishi , Yoshinao Kono
发明人： Hiromichi Takahashi , Yoichi Ishibashi , Yoshitaka Miyauchi , Takanobu Shiroishi , Yoshinao Kono
CPC分类号： C11C3/06 , D21C5/027 , Y02W30/648
摘要： A deinking composition which shows a good deinking performance, a good defoaming property and excellent operation characteristics whereby a deinked pulp having a high whiteness and little contamination with the total remaining ink can be obtained in the reclamation of waste papers by flotation, washing or a combination procedure thereof and wherein the deinking composition comprises a reaction mixture (II), as a deinking agent, obtained by the addition reaction of alkylene oxide (D) with a mixture (I) comprising a fat and oil (A) which is constituted with a mixture of higher fatty acids (a) comprising fatty acids having 8 to 24 carbon atoms; having an average carbon atom number of from 12.7 to 22.5; containing from 9.6 to 70.6% by weight of higher fatty acids having 20 to 24 carbon atoms and having an iodine value (IV) of 70 or less and glycerol (b-1), and/or, a transesterification reaction mixture (B) obtained by reacting the fat and oil (A) with glycerol (b-2), and at least one mono- to tetradecahydric alcohol (C).
摘要翻译： 脱墨剂组合物具有良好的脱墨性能，良好的消泡性能和优异的操作特性，可以通过浮选，洗涤或组合来回收废纸，从而获得具有高白度和总剩余油墨污染少的脱墨纸浆 其脱墨组合物包含作为脱墨剂的反应混合物（II），其通过环氧烷（D）与包含脂肪和油（A）的混合物（I）的加成反应获得，所述混合物（I）由 含有碳原子数为8〜24的脂肪酸的高级脂肪酸（a）的混合物; 平均碳原子数为12.7〜22.5; 含有9.6〜70.6重量％的具有20〜24个碳原子且碘值（IV）为70以下的高级脂肪酸和甘油（b-1），和/或得到的酯交换反应混合物（B） 通过使脂肪和油（A）与甘油（b-2）和至少一种一至十四元醇（C）反应。
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公开(公告)号：US5302243A
公开(公告)日：1994-04-12
申请号：US880087
申请日：1992-05-05
申请人： Yoichi Ishibashi , Yoshinao Kono , Yoshitaka Miyauchi , Takanobu Shiroishi , Hiromichi Takahashi
发明人： Yoichi Ishibashi , Yoshinao Kono , Yoshitaka Miyauchi , Takanobu Shiroishi , Hiromichi Takahashi
IPC分类号： D21C5/02
CPC分类号： D21C5/027 , Y02W30/648
摘要： The present invention aims at developing a deinking method applicable to the deinking of, for example, waste OA (office automation) paper and telephone directories, whereby a deinked pulp having a high whiteness and little contamination with large ink spots and unliberated ink can be obtained. The object of the present invention can be achieved by deinking, for example, waste OA paper or telephone directories by using a deinking composition containing as an effective component a reaction mixture (III) obtained by conducting the addition reaction of ethylene oxide and propylene oxide with a mixture (I) comprising a fat and oil (a) and a mono- to hexahydric alcohol (b) and/or with a transesterification mixture (II) obtained by conducting the transesterification reaction of a fat and oil (a) with a mono- to hexahydric alcohol (b), in such a manner that the molar ratio of ethylene oxide to propylene oxide which are used as starting materials ranges from 0.8 to 1.2 and that the molar number of ethylene oxide which is used for the addition reaction ranges from 50 to 100 mol per mole of the fat and oil (a).
摘要翻译： 本发明旨在开发适用于例如废弃OA（办公室自动化）纸和电话簿的脱墨的脱墨方法，由此可以获得具有高白度和少量污染的脱墨纸浆，并且可以获得大的墨点和未起泡的油墨 。 本发明的目的可以通过使用含有作为有效成分的脱墨组合物来脱墨，例如废纸OA或电话簿，通过进行环氧乙烷和环氧丙烷的加成反应获得的反应混合物（III） 包含脂肪和油（a）和一至六元醇（b）的混合物（I）和/或通过脂肪和油（a）与单体（a）进行酯交换反应而获得的酯交换混合物（II） - 以六元醇（b）的形式，使用作为原料的环氧乙烷与环氧丙烷的摩尔比为0.8〜1.2，加成反应所用的环氧乙烷的摩尔数为 每摩尔脂肪和油（a）为50-100摩尔。
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4.发明授权Deinking composition comprising a fatty acid mixture and a nonionic surfactant 失效包含脂肪酸混合物和非离子表面活性剂的脱墨组合物
公开(公告)号：US5801135A
公开(公告)日：1998-09-01
申请号：US542419
申请日：1995-10-12
CPC分类号： D21C5/027 , Y02W30/648
摘要： A liquid deinking composition comprising (a) a fatty acid mixture containing 40 to 90 weight % of saturated fatty acids having 12 to 14 carbon atoms and less than 60 weight % of saturated fatty acids having 16 to 18 carbon atoms, (b) a nonionic surfactant with HLB of 2 to 12 in a proportion of (a)/(b)=5/95 to 40/60 (weight ratio), and (c) 0 to 20 weight % (based on the composition) of water. No crystals of fatty acids are precipitated at ambient temperatures, and the separation, solidification or precipitation of crystals due to a temperature change is not caused. Further, the handling property is improved because of the liquid form.
摘要翻译： 一种液体脱墨组合物，其包含（a）含有40至90重量％的具有12至14个碳原子且小于60重量％的具有16至18个碳原子的饱和脂肪酸的饱和脂肪酸的脂肪酸混合物，（b）非离子表面活性剂 （a）/（b）= 5/95〜40/60（重量比）和（c）0〜20重量％（基于组成）的HLB为2〜12的表面活性剂。 没有脂肪酸晶体在环境温度下沉淀，并且不会引起由于温度变化引起的晶体的分离，固化或沉淀。 此外，由于液体形式，处理性能得到改善。
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公开(公告)号：US06179957B2
公开(公告)日：2001-01-30
申请号：US09101017
申请日：1998-06-29
IPC分类号： D21B108
CPC分类号： D21C5/025 , Y02W30/648
摘要： In a deinking process at least comprising the step of stripping ink from wastepaper as the starting material and the step of removing the stripped ink from a flotation system, the contact angle of the aqueous solution portion of a slurry containing the stripped ink with the interfaces of ink particles in the flotation step is controlled to be at least 70°.
摘要翻译： 在脱墨方法中，至少包括从废纸中除去油墨作为起始原料的步骤和从浮选系统中除去汽提的油墨的步骤，含有汽提油墨的浆料的水溶液部分的接触角与 浮选步骤中的油墨颗粒被控制在至少70°。
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公开(公告)号：US06312559B1
公开(公告)日：2001-11-06
申请号：US08940811
申请日：1997-09-30
IPC分类号： D21C502
CPC分类号： D21C5/027 , Y02W30/648
摘要： There is provided a deinking process carried out using white water according to which an excellent whiteness and an excellent areal ratio of residual ink fines can be secured while maintaining a proper pulp yield. In the deinking process comprising a flotation step wherein use is made of treatment water containing white water, at least part of the flotation step is effected in the presence of at least one compound selected from the group consisting of cationic compounds, amine compounds, acid salts of amine compounds, and ampholytic compounds.
摘要翻译： 提供了使用白水进行脱墨处理，根据该脱墨方法，可以在保持适当的纸浆产率的同时确保残留油墨细粉的优异的白度和优异的面积比。 在包括浮选步骤的脱墨方法中，其中使用含有白水的处理水，至少部分浮选步骤在至少一种选自阳离子化合物，胺化合物，酸盐的化合物存在下进行 的胺化合物和两性化合物。
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公开(公告)号：US06599392B1
公开(公告)日：2003-07-29
申请号：US09463905
申请日：2000-02-02
申请人： Takaaki Tadokoro , Yasushi Ikeda , Takayuki Ikenaga , Atsuhito Mori , Yoichi Ishibashi , Yasuo Ishii , Toshiyuki Nishimori , Hiromichi Takahashi
发明人： Takaaki Tadokoro , Yasushi Ikeda , Takayuki Ikenaga , Atsuhito Mori , Yoichi Ishibashi , Yasuo Ishii , Toshiyuki Nishimori , Hiromichi Takahashi
IPC分类号： D21H2122
摘要： According to the present invention, a bulky sheet can be obtained without reducing the effect of a sizing agent. Thus, an ester compound having the melting point of not more than 100° C. selected from (A) an ester compound of a polyhydric alcohol and a fatty acid and (B) an ester compound of a polyhydric alcohol and a fatty acid further including from more than 0 mole to less than 12 moles on the average of C2-4 oxyalkylene groups per 1 mole of the said ester compound is used as a paper bulking promoter.
摘要翻译： 根据本发明，可以在不降低施胶剂的效果的情况下获得大片状片材。 因此，具有选自（A）多元醇和脂肪酸的酯化合物的熔点不高于100℃的酯化合物和（B）多元醇和脂肪酸的酯化合物进一步包括 每1摩尔所述酯化合物的C2-4氧化烯平均值大于0摩尔至小于12摩尔，用作纸张膨胀促进剂。
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8.发明授权Wastepaper deinking method using amine or acid salt of amine in the flotation stage 失效在浮选阶段使用胺或胺的酸盐进行废纸脱墨方法公开(公告)号：US06251220B1
公开(公告)日：2001-06-26
申请号：US08894715
申请日：1997-08-26
IPC分类号： D21C502
CPC分类号： D21C5/027 , D21C5/025 , Y02W30/648
摘要： A deinking method comprising the steps of liberating ink from waste paper as a raw material and removing the liberated ink from a flotation system, wherein a nonionic surfactant, e.g., a reaction product obtained by adding an alkylene oxide to a mixture of an oil & fat and an alcohol, an alkylene oxide adduct of a fatty acid, or an alkylene oxide adduct of a higher alcohol, is used for the liberation of ink, and the flotation step is effected in the presence of a cationic compound, an amine, an acid salt of an amine or an amphoteric compound at a pH of from 4 to 9, provides a high quality deinked pulp having a high whiteness and a little residual ink spots.
摘要翻译： 一种脱墨方法，包括以下步骤：从作为原料的废纸中释放墨水，并从浮选系统中除去所释放的油墨，其中非离子表面活性剂，例如通过将烯化氧加入到油和油的混合物中获得的反应产物 并且使用醇，脂肪酸的烯化氧加合物或高级醇的烯化氧加成物，用于释放油墨，并且浮选步骤在阳离子化合物，胺，酸的存在下进行 胺或两性化合物的盐在pH为4至9时提供高质量脱墨纸浆，其具有高白度和少量残留油墨斑点。
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公开(公告)号：US5672244A
公开(公告)日：1997-09-30
申请号：US437383
申请日：1995-05-09
IPC分类号： D21C5/02
CPC分类号： D21C5/027 , Y02W30/648
摘要： In the deinking of feed waste papers comprising magazines and newspapers at a weight ratio of magazine to newspaper of from 5/95 to 60/40, a reclaimed pulp with excellent qualities can be obtained by adjusting the treating temperature in the flotation step to 40.degree. to 80.degree. C. and adding a deinking agent, which contains an alkylene oxide adduct of an oil or fat, wherein said alkylene oxide adduct comprises ethylene oxide and propylene oxide added at a molar ratio of ethylene oxide to propylene oxide of from 1/1 to 5/1, and has a cloud point of 45.degree. to 90.degree. C., at least in one of the steps of the deinking process.
摘要翻译： 在杂志和报纸的重量比为5/95至60/40的杂志和报纸的脱墨中，通过将浮选步骤中的处理温度调节至40°，可以获得具有优异品质的回收纸浆 加入含有油脂的环氧烷加合物的脱墨剂，其中所述环氧烷加合物包含以环氧乙烷与环氧丙烷的摩尔比加成的环氧乙烷和环氧丙烷的1/1 至5/1，并且具有45℃至90℃的浊点，至少在脱墨过程的步骤之一中。
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10.发明授权Method for controlling deinking flotation using interfacial potential of ink particles and pulp 失效使用墨水颗粒和纸浆的界面电位控制脱墨浮选的方法
公开(公告)号：US6103056A
公开(公告)日：2000-08-15
申请号：US117437
申请日：1998-07-30
CPC分类号： D21C5/025 , Y02W30/648
摘要： The present invention provides a deinking process from which bulkier pulp sheets that are excellent in paper strength, printability, ect. can be obtained. A deinking process comprising the steps of sipping ink from the flotation system. The flotation step is controlled so that the interfacial potential (.xi. potential) of ink particals is in the range of -5 mV to -60 mV and the interfacial potential (.xi. potential) of pulp is in the range of -5 mV to -.mV wherein a difference exist of at least 10 mV in the .xi. potential of the ink particles and pulp.
摘要翻译： PCT No.PCT / JP97 / 01794 Sec。 371日期：1998年7月30日 102（e）1998年7月30日PCT PCT 1997年5月27日PCT公布。 第WO97 / 46753号公报 日期1997年12月11日本发明提供了一种脱墨工艺，其中纸张强度，印刷性等优异的蓬松纸浆片材。 可以获得。 一种脱墨方法，包括从浮选系统中浸渍墨水的步骤。 控制浮选步骤，使得油墨部件的界面电位（xi电位）在-5mV至-60mV的范围内，并且纸浆的界面电位（xi电位）在-5mV至 - mV，其中在墨水颗粒和纸浆的xi电位中存在至少10mV的差异。
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