公开(公告)号：US20090259072A1

公开(公告)日：2009-10-15

申请号：US12441476

申请日：2007-06-29

申请人： Yoichi Umehara ,  Takeshi Minami ,  Susumu Yamamoto ,  Haruto Kobayashi ,  Yasuo Hosono

发明人： Yoichi Umehara ,  Takeshi Minami ,  Susumu Yamamoto ,  Haruto Kobayashi ,  Yasuo Hosono

IPC分类号： C07C51/42

CPC分类号： C07C51/47 ,  C07C53/08

摘要： An iodide compound is adsorbed and removed from an organic acid containing the iodide compound as an impurity by passing the organic acid through a packed bed of a cation-exchange resin having silver ion carried thereon at 50° C. or lower. The cation-exchange resin is a macroporous-type resin with an average particle size of 0.3 to 0.6 mm and an average pore size of 15 to 28 nm, and silver ion substitutes for 40 to 60% of the active site.

摘要翻译： 通过使有机酸通过其上承载有银离子的阳离子交换树脂的填充床在50℃以下，将含碘化合物的有机酸作为杂质吸附除去碘化物。 阳离子交换树脂是平均粒径为0.3〜0.6mm，平均孔径为15〜28nm的大孔型树脂，银离子代替活性部位的40〜60％。

公开(公告)号：US07985878B2

公开(公告)日：2011-07-26

申请号：US12441476

申请日：2007-06-29

申请人： Yoichi Umehara ,  Takeshi Minami ,  Susumu Yamamoto ,  Haruto Kobayashi ,  Yasuo Hosono

发明人： Yoichi Umehara ,  Takeshi Minami ,  Susumu Yamamoto ,  Haruto Kobayashi ,  Yasuo Hosono

IPC分类号： C07C51/42

CPC分类号： C07C51/47 ,  C07C53/08

摘要： An iodide compound is adsorbed and removed from an organic acid containing the iodide compound as an impurity by passing the organic acid through a packed bed of a cation-exchange resin having silver ion carried thereon at 50° C. or lower. The cation-exchange resin is a macroporous-type resin with an average particle size of 0.3 to 0.6 mm and an average pore size of 15 to 28 nm, and silver ion substitutes for 40 to 60% of the active site.

摘要翻译： 通过使有机酸通过其上承载有银离子的阳离子交换树脂的填充床在50℃以下，将含碘化合物的有机酸作为杂质吸附除去碘化物。 阳离子交换树脂是平均粒径为0.3〜0.6mm，平均孔径为15〜28nm的大孔型树脂，银离子代替活性部位的40〜60％。

公开(公告)号：US08802893B2

公开(公告)日：2014-08-12

申请号：US13257379

申请日：2011-02-08

申请人： Zhixiong You ,  Takeshi Minami ,  Chunji Yin ,  Yoichi Umehara ,  Tetsuro Matsumura ,  Chikako Hashimoto ,  Yasuo Hosono

发明人： Zhixiong You ,  Takeshi Minami ,  Chunji Yin ,  Yoichi Umehara ,  Tetsuro Matsumura ,  Chikako Hashimoto ,  Yasuo Hosono

IPC分类号： C07C51/10

CPC分类号： C08F226/06 ,  C07C51/12 ,  C08F212/36 ,  C07C53/08

摘要： According to a method for producing acetic acid by carbonylation of methanol characterized in that an acid having an acid dissociation constant (pKa) smaller than the constant of acetic acid is allowed to be present in the reaction system, acetic acid can be produced by the reaction of methanol and carbon monoxide in a reaction liquid in the presence of a solid catalyst containing rhodium and alkyl iodide, to achieve an enhanced reaction rate of carbonylation of methanol in producing acetic acid in the region at a high carbonylation degree (Ca>0.8 mol/mol) for more efficient production of acetic acid.

摘要翻译： 根据通过羰基化甲醇生产乙酸的方法，其特征在于在反应体系中存在酸解离常数（pKa）小于乙酸常数的酸，可以通过反应生成乙酸 的甲醇和一氧化碳在含有铑和烷基碘的固体催化剂存在下的反应液中，以在羰基化程度高（Ca> 0.8mol / L）的区域中提高甲醇生产乙酸的羰基化反应速率， mol）以更有效地生产乙酸。

公开(公告)号：US20120010371A1

公开(公告)日：2012-01-12

申请号：US13257379

申请日：2011-02-08

申请人： Zhixiong You ,  Takeshi Minami ,  Chunji Yin ,  Yoichi Umehara ,  Tetsuro Matsumura ,  Chikako Hashimoto ,  Yasuo Hosono

发明人： Zhixiong You ,  Takeshi Minami ,  Chunji Yin ,  Yoichi Umehara ,  Tetsuro Matsumura ,  Chikako Hashimoto ,  Yasuo Hosono

IPC分类号： C07C51/12 ,  C08F226/06

CPC分类号： C08F226/06 ,  C07C51/12 ,  C08F212/36 ,  C07C53/08

摘要： According to a method for producing acetic acid by carbonylation of methanol characterized in that an acid having an acid dissociation constant (pKa) smaller than the constant of acetic acid is allowed to be present in the reaction system, acetic acid can be produced by the reaction of methanol and carbon monoxide in a reaction liquid in the presence of a solid catalyst containing rhodium and alkyl iodide, to achieve an enhanced reaction rate of carbonylation of methanol in producing acetic acid in the region at a high carbonylation degree (Ca>0.8 mol/mol) for more efficient production of acetic acid.

摘要翻译： 根据通过羰基化甲醇生产乙酸的方法，其特征在于在反应体系中存在酸解离常数（pKa）小于乙酸常数的酸，可以通过反应生成乙酸 的甲醇和一氧化碳在含有铑和烷基碘的固体催化剂存在下的反应液中，以在羰基化程度高（Ca> 0.8mol / L）的区域中提高甲醇生产乙酸的羰基化反应速率， mol）以更有效地生产乙酸。

公开(公告)号：US20130209768A1

公开(公告)日：2013-08-15

申请号：US13370508

申请日：2012-02-10

申请人： Zhixiong You ,  Takeshi Minami ,  Chikako Hashimoto ,  Yoichi Umehara

发明人： Zhixiong You ,  Takeshi Minami ,  Chikako Hashimoto ,  Yoichi Umehara

IPC分类号： C08F26/06

CPC分类号： C08F226/06 ,  C08F212/36

摘要： A vinylpyridine resin that is hardly pulverized and thermally decomposed such that the degradation of the catalytic activity is suppressed while having a pore volume and a specific surface area to maintain a sufficient catalytic activity, and also a method of manufacturing the vinylpyridine resin are provided. The resin represents: a volume ratio of the pores having a diameter of 3 through 5 nm to all the pores of not less than 4% and not more than 60%; a total pore volume of not less than 0.15 cc/g and not more than 0.35 cc/g; and a specific surface area of not less than 20 m2/g and not more than 100 m2/g. The resin can be manufactured by using a poor solvent and not less than 50 wt % and not more than 90 wt % of a good solvent as porous agent.

摘要翻译： 难以粉碎和热分解的乙烯基吡啶树脂，同时具有孔体积和比表面积以保持足够的催化活性而抑制催化活性的降解，还提供了制备乙烯基吡啶树脂的方法。 树脂表示：直径为3〜5nm的孔与全部孔的体积比为4％以上且60％以下; 总孔体积不小于0.15cc / g且不大于0.35cc / g; 比表面积不小于20m2 / g且不大于100m2 / g。 树脂可以通过使用不良溶剂和不少于50重量％且不大于90重量％的良溶剂作为多孔剂来制造。

公开(公告)号：US09926397B2

公开(公告)日：2018-03-27

申请号：US13370508

申请日：2012-02-10

申请人： Zhixiong You ,  Takeshi Minami ,  Chikako Hashimoto ,  Yoichi Umehara

发明人： Zhixiong You ,  Takeshi Minami ,  Chikako Hashimoto ,  Yoichi Umehara

IPC分类号： C08F226/06 ,  C08F212/36

CPC分类号： C08F226/06 ,  C08F212/36

摘要： A vinylpyridine resin that is hardly pulverized and thermally decomposed such that the degradation of the catalytic activity is suppressed while having a pore volume and a specific surface area to maintain a sufficient catalytic activity, and also a method of manufacturing the vinylpyridine resin are provided. The resin represents: a volume ratio of the pores having a diameter of 3 through 5 nm to all the pores of not less than 4% and not more than 60%; a total pore volume of not less than 0.15 cc/g and not more than 0.35 cc/g; and a specific surface area of not less than 20 m2/g and not more than 100 m2/g. The resin can be manufactured by using a poor solvent and not less than 50 wt % and not more than 90 wt % of a good solvent as porous agent.

公开(公告)号：US06616905B1

公开(公告)日：2003-09-09

申请号：US09647680

申请日：2000-10-03

申请人： Kazushige Kawamura ,  Yoichi Umehara ,  Dai Takeda ,  Osamu Togari ,  Naonori Sonehara ,  Hiroaki Nishijima ,  Sachio Asaoka

发明人： Kazushige Kawamura ,  Yoichi Umehara ,  Dai Takeda ,  Osamu Togari ,  Naonori Sonehara ,  Hiroaki Nishijima ,  Sachio Asaoka

IPC分类号： B01D5350

CPC分类号： B01J31/06 ,  B01D53/8609 ,  B01J21/18 ,  B01J37/0036 ,  B01J37/04 ,  Y10S502/514

摘要： Active carbon catalyst for recovering and removing sulfur oxides contained in flue gas by turning them into sulfuric acid by a catalytic desulfurization reaction. Powdery active carbon and fluororesin are kneaded by shearing force before being molded to a desired profile so that the inter-particulate gaps of powdery active carbon particles are made water-repellent. Flue gas preferably flows downwardly through a tower filled with such an active carbon catalyst, which is made to show a honeycomb structure having surfaces running only in a direction parallel to the flow. The activity of the catalyst maintains an enhanced level if dilute sulfuric acid or water is introduced into the active carbon from the top of the tower to cleanse the surface of the active carbon catalyst so that the catalyst layer is prevented from being clogged and contaminated by ashes and soot contained in flue gas.

摘要翻译： 活性炭催化剂，用于通过催化脱硫反应将其转化成硫酸来回收和除去烟道气中所含的硫氧化物。 通过剪切力将粉状活性炭和氟树脂在模塑成所需轮廓之前被捏合，使得粉末状活性炭颗粒的颗粒间隙成为防水的。 烟道气体优选地向下流过填充有这样的活性炭催化剂的塔，其被制成显示具有仅在与流动平行的方向上延伸的表面的蜂窝结构。 如果将稀硫酸或水从塔顶引入活性炭，则催化剂的活性维持在较高的水平，以清洁活性炭催化剂的表面，从而防止催化剂层被灰烬堵塞和污染 烟气中含有烟灰。