摘要:
A high-speed agitation type mixer of a continuous extruding method including a plurality of agitating members provided around a rotational shaft inside a fixed casing is used to mix and react a water absorbing resin containing a carboxyl group with an aqueous liquid containing, for example, a crosslinking agent that can react with the carboxyl group. The agitating members of the mixer of a continuous extruding method are provided so as to form in the ejection side a second area whose thrusting force is weaker than the thrusting force in a first area in which the water absorbing resin supplied into the casing is dispersed. A device for manufacturing a water absorbing agent is thus offered which boasts good absorbency under pressure and always maintain its excellent performance with end products.
摘要:
A method for the production of a water-absorbent agent comprises mixing an absorbent resin containing a carboxyl group with an additive soluble in the aqueous solution of at least one member selected from the group consisting of inorganic acids, organic acids, and polyamino acids and a cross-linking agent capable of reacting with the carboxyl group. A water-absorbent agent obtained by adding from 0.005 to 8 parts by weight of an epoxy compound to 100 parts by weight of a water-absorbent resin, exhibiting an absorption capacity without load of at least 45 (g/g), an absorption capacity under load of 20 g/cm2 of not less than 30 (ml/g) and having a residue amount of an epoxy compound of not more than 2 ppm. A water-absorbent composition comprises a polyamino acid (salt) and a water-absorbent resin containing a carboxyl group.
摘要:
A method for the production of a water-absorbent agent comprises mixing an absorbent resin containing a carboxyl group with an additive soluble in the aqueous solution of at least one member selected from the group consisting of inorganic acids, organic acids, and polyamino acids and a cross-linking agent capable of reacting with the carboxyl group. A water-absorbent agent obtained by adding from 0.005 to 8 parts by weight of an epoxy compound to 100 parts by weight of a water-absorbent resin, exhibiting an absorption capacity without load of at least 45 (g/g), an absorption capacity under load of 20 g/cm2 of not less than 30 (ml/g) and having a residue amount of an epoxy compound of not more than 2 ppm. A water-absorbent composition comprises a polyamino acid (salt) and a water-absorbent resin containing a carboxyl group.
摘要:
A method for the production of a water-absorbent agent comprises mixing an absorbent resin containing a carboxyl group with an additive soluble in the aqueous solution of at least one member selected from the group consisting of inorganic acids, organic acids, and polyamino acids and a cross-linking agent capable of reacting with the carboxyl group. A water-absorbent agent obtained by adding from 0.005 to 8 parts by weight of an epoxy compound to 100 parts by weight of a water-absorbent resin, exhibiting an absorption capacity without load of at least 45 (g/g), an absorption capacity under load of 20 g/cm.sup.2 of not less than 30 (ml/g) and having a residue amount of an epoxy compound of not more than 2 ppm. A water-absorbent composition comprises a polyamino acid (salt) and a water-absorbent resin containing a carboxyl group.
摘要:
A method for the production of a water-absorbent agent comprises mixing an absorbent resin containing a carboxyl group with an additive soluble in the aqueous solution of at least one member selected from the group consisting of inorganic acids, organic acids, and polyamino acids and a cross-linking agent capable of reacting with the carboxyl group. A water-absorbent agent obtained by adding from 0.005 to 8 parts by weight of an epoxy compound to 100 parts by weight of a water-absorbent resin, exhibiting an absorption capacity without load of at least 45 (g/g), an absorption capacity under load of 20 g/cm2 of not less than 30 (ml/g) and having a residue amount of an epoxy compound of not more than 2 ppm. A water-absorbent composition comprises a polyamino acid (salt) and a water-absorbent resin containing a carboxyl group.
摘要:
A method for the production of an absorbent resin retaining at a high level an absorption capacity without load, one of the basic physical properties of absorbent resin, and excelling in an absorption capacity under load is provided. The production is attained by mixing an absorbent resin as a base polymer possessing a carboxyl group with a first cross-linking agent possessing a solubility parameter (SP value) of not less than 12.5 (cal/cm.sup.3).sup.1/2 and exhibiting reactivity with the carboxyl group and a second cross-linking agent possessing a solubility parameter (SP value) of less than 12.5 (cal/cm.sup.3).sup.1/2 and exhibiting reactivity with the carboxyl group and then subjecting the resultant mixture to a heat treatment at a temperature not less than 160.degree. C.
摘要翻译:提供一种吸收性树脂的制造方法,其在高负荷下保持无负载的吸收能力,吸收性树脂的基本物理性能之一,以及负载下的吸收容量优异。 通过将具有羧基的基础聚合物的吸收性树脂与具有不小于12.5(cal / cm 3)1/2的溶解度参数(SP值)的第一交联剂混合并显示出与 羧基和具有小于12.5(cal / cm 3)1/2的溶解度参数(SP值)的第二交联剂,并表现出与羧基的反应性,然后在不是的温度下对所得混合物进行热处理 小于160℃
摘要:
An object of the present invention is to provide a particulate water-absorbent resin composition which is so excellent that: the absorption ability in an initial short time is secured in some degree, and further, the absorption capacity lastingly increases over a long period, and also the liquid permeability and the liquid diffusibility can be secured. As a means of achieving this object, a particulate water-absorbent resin composition according to the present invention is a particulate water-absorbent resin composition comprising a carboxyl-group-containing water-absorbent resin in an amount of not smaller than 80 mass %, with the composition being characterized by being: not less than 20 g/g in specific-particle-diameter absorption capacity under load (0.29 psi (2.00 kPa), 1 hour); and not less than 3 g/g in specific-particle-diameter absorption index increment in 20 hours.
摘要:
There is provided: a production process for a water-absorbing agent having stable properties in a short time; and a water-absorbing agent. The production process comprises the step of blending an acid-group-containing water-absorbent resin powder with a noncrosslinkable water-soluble inorganic base and/or an irreducible alkaline-metal-salt pH buffer and further with a dehydratable crosslinking agent reactable with the acid group, thereby subjecting the resin powder to crosslinking treatment, or comprises the step of blending an acid-group-containing water-absorbent resin powder with the above base and/or pH buffer and further with a crosslinking agent reactable with the acid group, thereby subjecting the resin powder to crosslinking treatment, wherein the resin powder has a weight-average particle diameter of 300 to 600 μm wherein the ratio of fine powders having particle diameters of not larger than 150 μm in the resin powder is not more than 10 weight %.
摘要:
An object of the present invention is to provide a particulate water-absorbent resin composition which is so excellent that: the absorption ability in an initial short time is secured in some degree, and further, the absorption capacity lastingly increases over a long period, and also the liquid permeability and the liquid diffusibility can be secured. As a means of achieving this object, a particulate water-absorbent resin composition according to the present invention is a particulate water-absorbent resin composition comprising a carboxyl-group-containing water-absorbent resin in an amount of not smaller than 80 mass %, with the composition being characterized by being: not less than 20 g/g in specific-particle-diameter absorption capacity under load (0.29 psi (2.00 kPa), 1 hour); and not less than 3 g/g in specific-particle-diameter absorption index increment in 20 hours.
摘要:
As a characteristic that had not been known conventionally at all, “permeability potential under pressure (PPUP)” of a particulate water absorbing agent is regulated, and further, “range of particle size distribution” and “coloring” are concomitantly regulated. The present invention is directed to a particulate water absorbing agent having the following (a) to (c): (a) permeability potential under pressure (PPUP) being 50 to 100%; (b) yellowness index (YI) being 0 to 10, and rate of change of yellowness index (ΔYI) being 100 to 150% following a coloring acceleration test for 14 days at 70±1° C. and the relative humidity of 95±1%; and (c) particles of smaller than 150 μm specified by standard sieve classification accounting for 0 to 5% by weight, weight average particle diameter (D50) being 200 to 550 μm, and logarithmic standard deviation (σζ) of particle size distribution being 0.20 to 0.40.