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公开(公告)号：US4874686A
公开(公告)日：1989-10-17
申请号：US322511
申请日：1989-03-13
CPC分类号： G03F7/0752 , G03F7/038 , G03F7/0388
摘要： The present invention relates to a photosensitive lithographic plate necessitating no damping water, which plate has an excellent image reproducibility and stability in the lapse of time. The plate comprises, on a support, a photosensitive layer and a silicone rubber layer in this order, the silicone rubber layer being formed by addition reaction of an SiH group with a --CH.dbd.CH- group to cause crosslinking, and the photosensitive layer comprising:(1) a polymer comprising at least a structural formula (I): ##STR1## wherein R represents a hydrogen atom or a methyl group; R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each represents a member selected from the group consisting of a hydrogen atom, a halogen atom, a carboxyl group, a sulfo group, a nitro group, a cyano group, an amido group, an amino group, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylamino group, an arylamino group, an alkylsulfonyl group and an arylsulfo group; and Z represents an oxygen atom, a sulfur atom, --NH-, --NR.sub.6 (R.sub.6 represents an alkyl group), --OCH.sub.2 CH.sub.2 O- or --OCH.sub.2 CH(OH)-, and(2) a photopolymerization initiator.
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2.发明授权PS plate for use in making lithographic printing plate requiring no dampening water 失效PS版，用于制作不需要润版水的平版印刷版
公开(公告)号：US5126228A
公开(公告)日：1992-06-30
申请号：US558520
申请日：1990-07-27
申请人： Tatsuji Higashi , Yoshihiko Urabe , Kei Okuno , Nobuyuki Kita
发明人： Tatsuji Higashi , Yoshihiko Urabe , Kei Okuno , Nobuyuki Kita
CPC分类号： G03F7/0752
摘要： The present invention relates to a presensitized plate for use in making a lithographic plate requiring no dampening water and comprising, on a support, a light-sensitive resin layer and a silicone rubber layer, in this order, wherein the silicone rubber layer is crosslinked by addition reaction of an .fwdarw.SiH group with a --CH.dbd.CH-- group and wherein the light-sensitive resin layer comprises: (1) a monomer or oligomer having at least one photopolymerizable or photo-crosslinkable and olefinically unsaturated double bond, (2) an organic solvent-soluble polyurethane resin having a glass transition temperature of 20.degree. C. or below and being capable of forming a film, and (3) a photopolymerization initiator. According to the present invention, the PS plate has excellent image-forming properties and printing properties.
摘要翻译： 本发明涉及一种用于制造不需要润版水的平版印刷板的预感板，其特征在于，在支撑体上依次包含感光树脂层和硅橡胶层，其中硅橡胶层由 - > SiH基团与-CH = CH-基团的加成反应，其中感光树脂层包含：（1）具有至少一个可光聚合或光可交联和烯属不饱和双键的单体或低聚物，（2 ）玻璃化转变温度为20℃以下且能够形成膜的有机溶剂可溶性聚氨酯树脂，（3）光聚合引发剂。 根据本发明，PS板具有优异的成像性能和印刷性能。
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3.发明授权PS plate for making lithographic printing plate requiring no dampening water 失效用于制作不需要润版水的平版印刷版的PS版
公开(公告)号：US5069999A
公开(公告)日：1991-12-03
申请号：US603382
申请日：1990-10-26
CPC分类号： G03F7/0752 , G03F7/092 , Y10S430/151
摘要： A presensitized plate for use in making a lithographic printing plate requiring no dampening water comprises a substrate provided thereon with in order: (1) a photopolymerizable light-sensitive layer which comprises a monomer or an oligomer having at least one photopolymerizable olefinically unsaturated double bond, an organic solvent-soluble polyurethane resin or polyamide resin which is solid at room temperature and has film-forming ability and a photopolymerization initiator; (2) a crosslinked silicone rubber layer; and (3) a transparent cover coat layer, wherein the photopolymerization initiator comprises dialkylaminoarylcarbonyl compounds and at least one member selected from the group consisting of xanthones, thioxanthones, acrydones, benzophenones which do not carry a dialkylamino group, benzanthrones and anthraquinones and the transparent cover coat layer is formed from a biaxially oriented polypropylene film having a thickness ranging from 6 to 22 .mu.m and an oxygen permeability ranging from 900 to 10,000 cc/m.sup.2 /24 hr./at. at 20.degree. C. The presensitized plate does not cause so-called "fogging" even when it is kept to stand under irradiation with white light rays and whose sensitivity is not adversely affected by the degree of vacuum when the plate is exposed to light with a vacuum contact printer.
摘要翻译： 用于制造不需要润版水的平版印刷版的预感板包括其上依次提供的基材：（1）可光聚合的感光层，其包含具有至少一个可光聚合的烯属不饱和双键的单体或低聚物， 在室温下为固体且具有成膜能力的有机溶剂可溶性聚氨酯树脂或聚酰胺树脂，以及光聚合引发剂; （2）交联硅橡胶层; 和（3）透明覆盖层，其中光聚合引发剂包括二烷基氨基芳基羰基化合物和选自呫吨酮，噻吨酮，丙烯酸酯，不携带二烷基氨基的二苯甲酮，苯并蒽和蒽醌的至少一种，透明盖 涂层由厚度为6〜22μm，透氧度为900〜10,000cc / m 2 / 24hr / s的双轴取向聚丙烯膜形成。 即使在白光照射下保持静置时，预觉板也不会引起所谓的“起雾”，并且当板暴露于光时，其灵敏度不受真空度的不利影响。 真空接触式打印机。
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4.发明授权Light-sensitive diazo resin composition containing a higher fatty acid or higher fatty acid amide 失效含有高级脂肪酸或高级脂肪酸酰胺的感光性重氮树脂组合物
公开(公告)号：US5080999A
公开(公告)日：1992-01-14
申请号：US707190
申请日：1991-05-28
CPC分类号： G03F7/0166 , G03F7/027 , G03F7/033 , G03F7/0955
摘要： A light-sensitive composition which comprises, (a) an ethylenically unsaturated addition polymerizable compound, (b) an alkaline water-soluble or swellable, and film-forming polymer, (c) a photopolymerization initiator, (d) a negative working diazo resin, and (e) at least one compound selected from the group consisting of a higher fatty acid and a higher fatty acid amide which are solid at ordinary temperatures.The light-sensitive composition is hardly influenced by oxygen and is suitable for a presensitized plate from which a printing plate is to be prepared.
摘要翻译： 一种感光性组合物，其包含（a）烯属不饱和加成聚合性化合物，（b）碱性水溶性或可溶胀性和成膜性聚合物，（c）光聚合引发剂，（d）负性重氮树脂 ，和（e）至少一种选自常温下为固体的高级脂肪酸和高级脂肪酸酰胺的化合物。 感光性组合物几乎不受氧的影响，适用于要制备印版的预感板。
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5.发明授权Presensitized plates for use in making lithographic printing plates requiring no dampening water 失效用于制造不需要润版水的平版印刷版的预敏化板
公开(公告)号：US5059511A
公开(公告)日：1991-10-22
申请号：US485520
申请日：1990-02-27
申请人： Tatsuji Higashi , Yukio Abe , Nobuyuki Kita
发明人： Tatsuji Higashi , Yukio Abe , Nobuyuki Kita
CPC分类号： G03F7/0752
摘要： A presensitized plate, for use in making a lithographic printing plate requiring no dampening water, comprises a substrate, a light-sensitive resin layer applied thereon and a silicone rubber layer formed on the light-sensitive layer which is cross-linked through a reaction of SiH groups with --CH.dbd.CH-- groups, the light-sensitive resin layer comprising:(1) a monomer or an oligomer having at least one photopolymerizable (meth)acryloyl group and at least one allyl group;(2) a photopolymerization initiator; and optionally(3) a polymeric compound having film-forming ability; and(4) a monomer or an oligomer having at least one photopolymerizable (meth)acryloyl groups and free of allyl groups.According to the presensitized plate, the adhesion between the addition type silicone rubber layer and the light-sensitive resin layer is greatly improved and excellent image-forming properties of the presensitized plate are thus ensured.
摘要翻译： 用于制造不需要润版水的平版印刷版的预觉板包括基材，涂布在其上的感光树脂层和形成在感光层上的硅橡胶层，该硅橡胶层通过 具有-CH = CH-基团的SiH基团，所述感光树脂层包含：（1）具有至少一个可光聚合的（甲基）丙烯酰基和至少一个烯丙基的单体或低聚物; （2）光聚合引发剂; 和（3）具有成膜能力的聚合物; 和（4）具有至少一个可光聚合的（甲基）丙烯酰基并且不含烯丙基的单体或低聚物。 根据预敏板，加性硅酮橡胶层和感光树脂层之间的粘附性大大提高，并且因此确保了预敏化板的优异的图像形成性能。
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公开(公告)号：US4877719A
公开(公告)日：1989-10-31
申请号：US918126
申请日：1986-10-14
申请人： Tatsuji Higashi , Nobuyuki Kita
发明人： Tatsuji Higashi , Nobuyuki Kita
CPC分类号： G03F7/38
摘要： Disclosed is a process for preparing an image-bearing plate for use in a lithographic printing plate, a photoresist or the like. The process comprises, after imagewise exposing a light-sensitive plate comprising a support having provided thereon a light-sensitive layer comprising a compound capable of producing an acid upon irradiation with actinic rays, a compound having at least one acid-decomposable group, and an alkali-soluble resin, treating the exposed plate with hot water of at least 25.degree. C. for a period of at least 10 seconds, prior to development. It is possible to achieve high sensitivity regardless of the interval between the exposure and the development.
摘要翻译： 公开了一种用于制备用于平版印刷版，光致抗蚀剂等的图像承载板的方法。 该方法包括：在包含其上提供有支持物的感光板上成像曝光后，在其上设置光敏层，所述感光层包含在光化射线照射时能够产生酸的化合物，具有至少一个酸可分解基团的化合物和 碱溶性树脂，在显影之前用至少25℃的热水处理暴露的板至少10秒的时间。 无论曝光和显影间隔如何，都可以实现高灵敏度。
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公开(公告)号：US4959296A
公开(公告)日：1990-09-25
申请号：US284400
申请日：1988-12-14
CPC分类号： G03F7/32
摘要： A developer for PS plates requiring no dampening water which comprise a substrate provided thereon with a primer layer, photopolymerizable light-sensitive layer and a silicone rubber layer in this order, comprises: (i) an organic solvent which can dissolve or swell non-exposed portions of the photopolymerizable light-sensitive layer and whose solubility in water at ordinary temperature is not more than 20% by weight; (ii) a surfactant; and (iii) water. The developer is excellent in developing properties and dot reproduction, shows high stability and does not cause scratches on the silicone rubber layer during development.
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公开(公告)号：US06270483B1
公开(公告)日：2001-08-07
申请号：US09296536
申请日：1999-04-22
IPC分类号： A61M500
CPC分类号： A61M5/16877 , A61M5/141 , Y10T137/2559 , Y10T137/7839
摘要： A compact liquid discharge regulator is provided at low cost by arranging a channel spirally formed in the surf ace of a passage forming member. The surface of the passage forming member is brought into close contact with the inner surface of a housing part, and the channel functions as a liquid passage. In this construction, the sectional form and length of the channel can be formed at high precision in accordance with the design. Therefore, a desired pipe loss is obtainable only by designing in advance the sectional form and length of the channel so as to correspond to the pipe loss. Particularly, with injection molding, mass production of a passage forming member of identical pipe loss can be effected merely by preparing a mold corresponding to the pipe loss, thus leading to a considerable reduction in the manufacturing cost of the discharge regulator.
摘要翻译： 通过在通道形成构件的冲浪中螺旋地形成通道来以低成本提供紧凑的液体排出调节器。 通道形成构件的表面与壳体部分的内表面紧密接触，并且通道用作液体通道。 在这种结构中，可以根据设计高精度地形成通道的截面形状和长度。 因此，只有通过预先设计通道的截面形式和长度以便对应于管道损失，才能获得期望的管道损失。 特别地，通过注射成形，可以仅通过制备与管道损失相对应的模具来实现大量生产具有相同管道损失的通道形成构件，从而导致放电调节器的制造成本的显着降低。
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9.发明授权Light-sensitive composition containing an unsaturated monomer and a photopolymerization initiator 失效含有不饱和单体和光聚合引发剂的感光性组合物
公开(公告)号：US4826753A
公开(公告)日：1989-05-02
申请号：US92885
申请日：1987-09-04
申请人： Tatsuji Higashi , Kouichi Kawamura , Yukio Abe
发明人： Tatsuji Higashi , Kouichi Kawamura , Yukio Abe
CPC分类号： G03F7/0295 , Y10S430/121
摘要： A light-sensitive composition containing a polymerizable compound having at least one ethylenically unsaturated group, and a photopolymerization initiator of general formula (I): ##STR1## wherein Y represents --COOR.sub.1, ##STR2## --R.sub.3 --COOR.sub.1, --R.sub.3 --CONHR.sub.1 or --NHCO--R.sub.4 (wherein R.sub.1 represents a hydrogen atom, an alkyl group, or an aryl group; R.sub.2 represents a hydrogen atom or a methyl group; R.sub.3 represents an alkylene group; R.sub.4 represents an alkyl group, an alkoxy group, an aryl group; and l and m respectively represents integers of 1 to 10.); Ar represents a phenylene, naphthylene or heterocyclic aromatic group; X represents a chlorine atom or a bromine atom; and n represents 1 or 2.The light-sensitive composition has a good stability over time since crystallization of the photopolymerization initiator on the surface of the light-sensitive layer is inhibited.
摘要翻译： 含有具有至少一个烯键式不饱和基团的聚合性化合物和通式（I）的光聚合引发剂的感光性组合物：其中Y表示-COOR1，-IG3-R3-COOR1，-R3 -CONHR1或-NHCO-R4（其中R1表示氢原子，烷基或芳基; R2表示氢原子或甲基; R3表示亚烷基; R4表示烷基，烷氧基， 芳基; l和m分别表示1〜10的整数。 Ar表示亚苯基，亚萘基或杂环芳基; X表示氯原子或溴原子; 并且n表示1或2.由于光敏层的表面上的光聚合引发剂的结晶被抑制，因此光敏性组合物随着时间的推移具有良好的稳定性。
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10.发明授权
公开(公告)号：US5629136A
公开(公告)日：1997-05-13
申请号：US568372
申请日：1995-12-06
申请人： Tatsuji Higashi , Koji Sonokawa , Tsumoru Hirano
发明人： Tatsuji Higashi , Koji Sonokawa , Tsumoru Hirano
CPC分类号： G03F7/0752
摘要： A presensitized plate for use in making a lithographic printing plate requiring no fountain solution excellent in scratch resistance and press life is disclosed, which comprises support and, formed thereon in order from support, a photosensitive layer and a silicone rubber layer, wherein the silicone rubber layer is a crosslinked and cured product obtained by addition reaction of (a) polysiloxane having alkenyl groups with (b) hydrogen polysiloxane having .tbd.Si--H groups so that the number of .tbd.Si--H groups in (b) is from 11 to 30 based on the number of alkenyl groups in (a), wherein polysiloxane (a) has at least two alkenyl groups directly bonded to silicon atoms per molecule, average repeating number x of --[Si(R.sup.1)(R.sup.2)--O].sub.x -- group of 100 .ltoreq.x.ltoreq.600 (wherein R.sup.1 and R.sup.2 each represents a alkyl group, aryl group, aralkyl group, alkenyl group, polydimethylsiloxane group or halogenated hydrocarbon group, provided that 70% or more of R.sup.1 and R.sup.2 are methyl groups), and alkyl groups or alkenyl groups directly bonded to the terminal silicon atoms, and wherein the hydrogen polysiloxane (b) is formula (I):R.sup.3 --Si(R.sup.4).sub.2 --O--[SiH(R.sup.4)--O].sub.y --[Si(R.sup.4).sub.2 --O].sub.z --Si(R.sup.4).sub.2 --R.sup.3 (I)wherein R.sup.3 represents a hydrogen atom or a methyl group; R.sup.4 represents an alkyl group, an aryl group, or an aralkyl group, provided that 70% or more of R.sup.4 is a methyl group; y is from 4 to 100, and z is from 0 to 100.
摘要翻译： 公开了一种用于制造不需要耐刮擦性和冲压寿命优异的润版液的平版印刷版的预敏化板，其包括载体，并且从载体上依次形成感光层和硅橡胶层，其中硅橡胶 层是通过（a）具有烯基的聚硅氧烷与（b）具有3个Si-H基团的氢聚硅氧烷的加成反应得到的交联固化物，使得（b）中的3BOND Si-H基团的数量为11〜30 基于（a）中的烯基数，其中聚硅氧烷（a）具有至少两个每分子直接与硅原子键合的烯基， - [Si（R 1）（R 2）-O] x - 基团，其中R 1和R 2各自表示烷基，芳基，芳烷基，烯基，聚二甲基硅氧烷基或卤代烃基，其中R 1和R 2的70％或更多为甲基 基团）和烷基或醇 （b）为式（I）：R3-Si（R4）2-O- [SiH（R4）-O] y- [Si（R4）2） -O] z-Si（R 4）2 -R 3（I）其中R 3表示氢原子或甲基; R4表示烷基，芳基或芳烷基，条件是R4的70％以上为甲基。 y为4〜100，z为0〜100。
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