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1.
公开(公告)号:US08609754B2
公开(公告)日:2013-12-17
申请号:US13510820
申请日:2010-11-18
申请人: Yoshitaka Naito , Shigeki Hamamoto , Hirotoshi Saito , Hiroshi Tanigawa , Joichi Watanabe , Koichi Tezuka , Masahito Nakamoto
发明人: Yoshitaka Naito , Shigeki Hamamoto , Hirotoshi Saito , Hiroshi Tanigawa , Joichi Watanabe , Koichi Tezuka , Masahito Nakamoto
IPC分类号: C08L51/04
CPC分类号: C08L25/12 , C08K5/523 , C08L33/18 , C08L55/02 , C08L2201/02 , C08L2666/24
摘要: Provided is a flame-retardant thermoplastic resin composition in which any halogenated flame retardant is not used but a phosphoric flame retardant is used, which has flame retardancy meeting U.S. UL Standard 94 V-2, which exhibits excellent dripping performance during burning, and which is excellent in balance between properties. The flame-retardant thermoplastic resin composition contains 100 parts by mass of a copolymer mixture containing a graft copolymer (A) obtained by graft-polymerizing a rubbery polymer, a vinyl cyanide compound, and a copolymerizable vinyl compound and a vinyl copolymer (B) which is obtained by copolymerizing the vinyl cyanide compound and the copolymerizable vinyl compound and which has a mass-average molecular weight of 90,000 to 160,000 and 5 to 20 parts by mass of a phosphoric flame retardant (C) blended with the copolymer mixture. The content CB1 of vinyl cyanide units in the acetone-insoluble fraction of the copolymer mixture is 22.0% to 32.0% by mass, the content CB2 of vinyl cyanide units in the acetone-soluble fraction thereof is 22.0% to 34.0% by mass, and |CB1−CB2| is 0% to 3.0% by mass.
摘要翻译: 本发明提供一种阻燃热塑性树脂组合物,其中不使用任何卤化阻燃剂,但使用磷阻燃剂,其阻燃性符合美国UL标准94V-2,其在燃烧时表现出优异的滴水性能, 性能之间的平衡优异。 阻燃性热塑性树脂组合物含有100质量份含有通过使橡胶状聚合物,乙烯基氰化合物和可共聚乙烯基化合物接枝聚合得到的接枝共聚物(A)和乙烯基共聚物(B)的共聚物混合物, 通过共聚合乙烯基氰化合物和可共聚的乙烯基化合物,其质均分子量为90,000至160,000,和5至20质量份与共聚物混合物共混的磷阻燃剂(C)。 共聚物混合物的丙酮不溶级分中的乙烯基氰单元的含量CB1为22.0〜32.0质量%,丙酮可溶成分中的乙烯基氰单元的含量CB2为22.0〜34.0质量%, | CB1-CB2 | 为0〜3.0质量%。
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2.
公开(公告)号:US20120245261A1
公开(公告)日:2012-09-27
申请号:US13510820
申请日:2010-11-18
申请人: Yoshitaka Naito , Shigeki Hamamoto , Hirotoshi Saito , Hiroshi Tanigawa , Joichi Watanabe , Koichi Tezuka , Masahito Nakamoto
发明人: Yoshitaka Naito , Shigeki Hamamoto , Hirotoshi Saito , Hiroshi Tanigawa , Joichi Watanabe , Koichi Tezuka , Masahito Nakamoto
CPC分类号: C08L25/12 , C08K5/523 , C08L33/18 , C08L55/02 , C08L2201/02 , C08L2666/24
摘要: Provided is a flame-retardant thermoplastic resin composition in which any halogenated flame retardant is not used but a phosphoric flame retardant is used, which has flame retardancy meeting U.S. UL Standard 94 V-2, which exhibits excellent dripping performance during burning, and which is excellent in balance between properties. The flame-retardant thermoplastic resin composition contains 100 parts by mass of a copolymer mixture containing a graft copolymer (A) obtained by graft-polymerizing a rubbery polymer, a vinyl cyanide compound, and a copolymerizable vinyl compound and a vinyl copolymer (B) which is obtained by copolymerizing the vinyl cyanide compound and the copolymerizable vinyl compound and which has a mass-average molecular weight of 90,000 to 160,000 and 5 to 20 parts by mass of a phosphoric flame retardant (C) blended with the copolymer mixture. The content CB1 of vinyl cyanide units in the acetone-insoluble fraction of the copolymer mixture is 22.0% to 32.0% by mass, the content CB2 of vinyl cyanide units in the acetone-soluble fraction thereof is 22.0% to 34.0% by mass, and |CB1−CB2| is 0% to 3.0% by mass.
摘要翻译: 本发明提供一种阻燃热塑性树脂组合物,其中不使用任何卤化阻燃剂,但使用磷阻燃剂,其阻燃性符合美国UL标准94V-2,其在燃烧时表现出优异的滴水性能, 性能之间的平衡优异。 阻燃性热塑性树脂组合物含有100质量份含有通过使橡胶状聚合物,乙烯基氰化合物和可共聚乙烯基化合物接枝聚合得到的接枝共聚物(A)和乙烯基共聚物(B)的共聚物混合物, 通过共聚合乙烯基氰化合物和可共聚的乙烯基化合物,其质均分子量为90,000至160,000,和5至20质量份与共聚物混合物共混的磷阻燃剂(C)。 共聚物混合物的丙酮不溶级分中的乙烯基氰单元的含量CB1为22.0〜32.0质量%,丙酮可溶成分中的乙烯基氰单元的含量CB2为22.0〜34.0质量%, | CB1-CB2 | 为0〜3.0质量%。
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公开(公告)号:US3947046A
公开(公告)日:1976-03-30
申请号:US365128
申请日:1973-05-30
申请人: Masayuki Maruyama , Joichi Watanabe
发明人: Masayuki Maruyama , Joichi Watanabe
摘要: An oil seal ring is obtained which can maintain its oil scraping performance at a satisfactory level despite the frictional wear it undergoes. It is formed with a tapered sliding surface having a hardness maximized at its oil scraping edge and decreasing with the distance therefrom. It can be manufactured by casehardening a ring blank through one end surface thereof which is oppositely tapered and subsequently finishing the end surface to shape.
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