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    Catalyst for asymmetric induction
    3.
    发明授权
    Catalyst for asymmetric induction 失效
    非对称诱导催化剂

    公开(公告)号：US5288682A

    公开(公告)日：1994-02-22

    申请号：US851285

    申请日：1992-03-12

    申请人： Atsunori Mori ,  Shohei Inoue

    发明人： Atsunori Mori ,  Shohei Inoue

    IPC分类号： B01J31/02 ,  C07C253/08 ,  C07C255/36 ,  B01J31/00

    CPC分类号： C07C253/00 ,  B01J31/0212 ,  B01J31/0241 ,  B01J31/0247 ,  B01J2231/343 ,  C07B2200/07

    摘要： Optically active cyanohydrins are prepared by addition of hydrogen cyanide to aldehydes in the presence of catalysts which comprise the dipeptide derivative represented by the formula ##STR1## wherein R.sup.1 represents an isopropyl group, an isobutyl group, a sec-butyl group, a tert-butyl group, a methyl group, a benzyl group or a phenyl group, R.sup.2 represents a benzyl group, an indol-3-ylmethyl group, an isopropyl group, an isobutyl group or a phenyl group, R.sup.3 represents a lower alkoxy group, a hydroxy group or a mono- or di-lower alkylamino group, R.sup.4 represents a hydrogen atom, or R.sup.2 and R.sup.4 are bonded together at their terminals to form a CH.sub.2 CH.sub.2 CH.sub.2 group, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are the same or different, and each represents a hydrogen atom, a halogen atom, a lower alkyl group or a lower alkoxy group or R.sup.5 and R.sup.6, R.sup.6 and R.sup.7, or R.sup.7 and R.sup.8 are bonded together at their terminals to form CH.dbd.CH--CH.dbd.CH or OCH.sub.2 O, and * denotes an absolute configuration of S or R, and a titanium (IV) alkoxide.

    摘要翻译： 通过在催化剂存在下，将氰化氢加入到醛中来制备光活性氰醇，该催化剂包含由式（* CHEMICAL STRUCTURE *）（I）表示的二肽衍生物，其中R 1表示异丙基，异丁基，仲丁基 基团，叔丁基，甲基，苄基或苯基，R 2表示苄基，吲哚-3-基甲基，异丙基，异丁基或苯基，R 3表示低级 烷氧基，羟基或单 - 或二 - 低级烷基氨基，R 4表示氢原子，或者R 2和R 4在其末端键合在一起形成CH 2 CH 2 CH 2基，R 5，R 6，R 7和R 8相同， 各自表示氢原子，卤素原子，低级烷基或低级烷氧基或R5和R6，R6和R7，或R7和R8在其末端键合在一起形成CH = CH-CH = CH 或OCH 2 O，*表示S或R的绝对构型，钛（IV） 醇盐

    Preparation process for cyclic conjugated polymer and polymerization catalyst for cyclic conjugated polymer
    5.
    发明授权
    Preparation process for cyclic conjugated polymer and polymerization catalyst for cyclic conjugated polymer 有权
    环状共轭聚合物的制备方法和环状共轭聚合物的聚合催化剂

    公开(公告)号：US08957181B2

    公开(公告)日：2015-02-17

    申请号：US14122468

    申请日：2012-05-21

    申请人： Syuji Okamoto ,  Hikaru Meguro ,  Atsunori Mori

    发明人： Syuji Okamoto ,  Hikaru Meguro ,  Atsunori Mori

    IPC分类号： C08G75/00 ,  C08G61/12 ,  C08G61/10

    CPC分类号： C08G61/126 ,  C08G61/10 ,  C08G2261/3223 ,  C08G2261/417

    摘要： A preparation process for a cyclic conjugated polymer, includes the steps of deprotonating a monohalogenated cyclic conjugated compound of a 5- to 7-membered ring using a deprotonation catalyst comprising secondary amine represented by R1NHR2 (R1 and R2 are the same or different and are each a branched or cyclic alkyl group of 1 to 15 carbon atoms or a phenyl group) and a Grignard reagent represented by R3MgX (X is a halogen atom selected from chlorine, bromine and iodine, and R3 is a straight-chain or branched alkyl group of 1 to 6 carbon atoms) and polymerizing the deprotonated monohalogenated cyclic conjugated compound.

    摘要翻译： 环状共轭聚合物的制备方法包括以下步骤：使用包含由R1NHR2表示的仲胺的脱质子化催化剂（R 1和R 2相同或不同，各自相同或不同），将5-卤代环状结合的5-卤代环结合化合物去质子化 1〜15个碳原子的支链或环状烷基或苯基）和由R3MgX表示的格利雅试剂（X为选自氯，溴和碘的卤素原子，R 3为直链或支链烷基 1至6个碳原子）并使去质子化的单卤化环状共轭化合物聚合。

    Catalyst for asymmetric induction
    7.
    发明授权
    Catalyst for asymmetric induction 失效
    非对称诱导催化剂

    公开(公告)号：US5308820A

    公开(公告)日：1994-05-03

    申请号：US5117

    申请日：1993-01-15

    申请人： Atsunori Mori ,  Shohei Inoue

    发明人： Atsunori Mori ,  Shohei Inoue

    IPC分类号： B01J31/02 ,  C07B53/00 ,  C07B61/00 ,  C07C251/24 ,  C07C253/08 ,  C07C253/30 ,  C07C253/34 ,  C07C255/16 ,  C07D295/185

    CPC分类号： C07D295/185 ,  B01J31/0212 ,  B01J31/0241 ,  B01J31/0247 ,  C07B53/00 ,  C07C251/24 ,  C07C253/00 ,  C07C253/34 ,  B01J2231/343 ,  C07B2200/07 ,  C07C2101/14

    摘要： A catalyst for asymmetric induction is provided which comprises an amino acid amide derivative represented by the formula [I]: ##STR1## wherein R.sup.1 represents an isopropyl group, etc., R.sup.2 and R.sup.3 are the same or different and each represents a lower alkyl group, etc., R.sup.4 represents a chlorine atom, etc., R.sup.5, R.sup.6 and R.sup.7 are the same or different and each represents a hydrogen atom, etc., and * denotes an abosolute configuration of S or R, and a titanium (IV) alkoxide.Optically active cyanohydrins are obtained in high yield and at high purity by addition of hydrogen cyanide to aldehyde compounds in the presence of the above mentioned catalyst.

    摘要翻译： 提供了一种用于不对称诱导的催化剂，其包含由式[I]表示的氨基酰胺衍生物：其中R 1表示异丙基等，其中R 2和R 3相同或不同，各自表示 低级烷基等，R4表示氯原子等，R5，R6和R7相同或不同，表示氢原子等，*表示S或R的疏水构型，钛 （IV）醇盐。 在上述催化剂存在下，通过向醛化合物中加入氰化氢，以高产率和高纯度获得光学活性氰醇。

    Preparation Process for Cyclic Conjugated Polymer and Polymerization Catalyst for Cyclic Conjugated Polymer
    8.
    发明申请
    Preparation Process for Cyclic Conjugated Polymer and Polymerization Catalyst for Cyclic Conjugated Polymer 有权
    循环共轭聚合物的制备方法和循环共轭聚合物的聚合催化剂

    公开(公告)号：US20140107303A1

    公开(公告)日：2014-04-17

    申请号：US14122468

    申请日：2012-05-21

    申请人： Syuji Okamoto ,  Hikaru Meguro ,  Atsunori Mori

    发明人： Syuji Okamoto ,  Hikaru Meguro ,  Atsunori Mori

    IPC分类号： C08G61/12

    CPC分类号： C08G61/126 ,  C08G61/10 ,  C08G2261/3223 ,  C08G2261/417

    摘要： A preparation process for a cyclic conjugated polymer, includes the steps of deprotonating a monohalogenated cyclic conjugated compound of a 5- to 7-membered ring using a deprotonation catalyst comprising secondary amine represented by R1NHR2 (R1 and R2 are the same or different and are each a branched or cyclic alkyl group of 1 to 15 carbon atoms or a phenyl group) and a Grignard reagent represented by R3MgX (X is a halogen atom selected from chlorine, bromine and iodine, and R3 is a straight-chain or branched alkyl group of 1 to 6 carbon atoms) and polymerizing the deprotonated monohalogenated cyclic conjugated compound.

    摘要翻译： 环状共轭聚合物的制备方法包括以下步骤：使用包含由R1NHR2表示的仲胺的脱质子化催化剂（R 1和R 2相同或不同，各自相同或不同），将5-卤代环状结合的5-卤代环结合化合物去质子化 1〜15个碳原子的支链或环状烷基或苯基）和由R3MgX表示的格利雅试剂（X为选自氯，溴和碘的卤素原子，R 3为直链或支链烷基 1至6个碳原子）并使去质子化的单卤化环状共轭化合物聚合。