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公开(公告)号：US20140135520A1
公开(公告)日：2014-05-15
申请号：US14124068
申请日：2012-06-07
申请人： Isamu Shiina , Kenya Nakata , Keisuke Ono
发明人： Isamu Shiina , Kenya Nakata , Keisuke Ono
IPC分类号： C07C67/08
CPC分类号： C07C67/08 , B01J31/0241 , B01J2231/49 , C07B57/00 , C07B2200/07 , C07C2101/08 , C07C2103/26 , C07C2601/08 , C07C2603/26 , C07D207/337 , C07D209/26 , C07D209/46 , C07D209/88 , C07D317/68 , C07C69/612 , C07C69/734 , C07C69/65 , C07C69/616 , C07C69/738 , C07C69/736
摘要： A method that manufacturers an optically active carboxylic acid ester at high yield and high enantioselectivity is provided. An optically active carboxylic acid ester is manufactured at high yield and high enantioselectivity by reacting a racemic carboxylic acid and a specific alcohol or phenol derivatives in a polar solvent having a dipole moment of 3.0 or higher in the presence of an acid anhydride and an asymmetric catalyst, esterifying one enantiomer of the racemic carboxylic acid at high selectivity, and increasing the amount of esterified carboxylic acid by racemizing the optically active carboxylic acid which is the other enantiomer not used in esterification.
摘要翻译： 提供了以高产率和高对映选择性制造光学活性羧酸酯的方法。 通过在酸酐和不对称催化剂的存在下，使外消旋羧酸和特定的醇或苯酚衍生物在偶极矩为3.0或更高的极性溶剂中反应，以高产率和高对映选择性制备光学活性羧酸酯 以高选择性酯化外消旋羧酸的一种对映异构体，并通过外消旋化作为酯化反应中未使用的另一对映异构体的光学活性羧酸来增加酯化羧酸的量。
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公开(公告)号：US20160340303A1
公开(公告)日：2016-11-24
申请号：US14885863
申请日：2015-10-16
IPC分类号： C07C327/32 , C07C327/26 , B01J31/02 , C07C335/32
CPC分类号： C07C327/32 , B01J31/0222 , B01J31/0237 , B01J31/0241 , B01J31/0271 , B01J2231/32 , B01J2231/4294 , C07C327/26 , C07C335/32
摘要： A method for synthesizing of thioesters by using a compound as a catalyst is disclosed. The compound is represented by formula I below: In formula I, R5 represents H, a substituted or unsubstituted alkyl, a substituted or unsubstituted aryl, or a substituted or unsubstituted heteroaryl; X and Y each independently represents one of H, C1-10 alkyl, C5-10 aryl, C1-10 alkyl alcohol, thiohydroxy, carbonyl, sulfonyl, sulfamoyl, carbamoyl, C1-10 alkoxycarbonyl, C1-10 alkoxycarbamoyl, C1-10 alkylamino, C1-10 alkylsulfonyl, C1-10 haloalkylsulfonyl, ureido, amido, and C1-10 alkoxylcarbamoyl; and n is 0, 1, 2, 3, 4 or 5.
摘要翻译： 在式I中，R 5表示H，取代或未取代的烷基，取代或未取代的芳基或取代或未取代的杂芳基; X和Y各自独立地表示H，C 1-10烷基，C 5-10芳基，C 1-10烷基醇，硫代羟基，羰基，磺酰基，氨磺酰基，氨基甲酰基，C 1-10烷氧基羰基，C 1-10烷氧基氨基甲酰基，C 1-10烷基氨基 ，C 1-10烷基磺酰基，C 1-10卤代烷基磺酰基，脲基，酰氨基和C 1-10烷氧基氨基甲酰基; 且n为0,1,2,3,4或5。
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公开(公告)号：US20160304792A1
公开(公告)日：2016-10-20
申请号：US15198397
申请日：2016-06-30
发明人： Michael P. LANCI , Stuart L. SOLED , Javier GUZMAN , Sabato MISEO , Thomas E. GREEN , Joseph E. BAUMGARTNER , Lei ZHANG , Christine E. KLIEWER , Lukasz KOZIOL , Kanmi MAO , Tracie L. OWENS , Gary P. SCHLEICHER , Xiaochun XU
CPC分类号： C10G45/52 , B01J21/04 , B01J21/08 , B01J21/12 , B01J23/42 , B01J23/44 , B01J23/464 , B01J23/468 , B01J31/0241 , B01J31/28 , B01J35/002 , B01J37/0203 , C10G45/34 , C10G45/46 , C10G65/08 , C10G2300/202 , C10G2300/307
摘要： Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation.
摘要翻译： 提供了用于修饰具有二氧化硅载体（或其它非氧化铝载体）的另外的氧化铝的氢化催化剂的方法，并且使用这样的催化剂实现了出人意料的优异的原料氢化。 改进的氢化催化剂可以具有相对低的裂化活性，同时提供增加的氢化活性。
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公开(公告)号：US09315442B2
公开(公告)日：2016-04-19
申请号：US14124068
申请日：2012-06-07
申请人： Isamu Shiina , Kenya Nakata , Keisuke Ono
发明人： Isamu Shiina , Kenya Nakata , Keisuke Ono
IPC分类号： C07C69/76 , C07C67/08 , C07D317/68 , C07B57/00 , C07D207/337 , C07D209/26 , C07D209/46 , C07D209/88 , B01J31/02
CPC分类号： C07C67/08 , B01J31/0241 , B01J2231/49 , C07B57/00 , C07B2200/07 , C07C2101/08 , C07C2103/26 , C07C2601/08 , C07C2603/26 , C07D207/337 , C07D209/26 , C07D209/46 , C07D209/88 , C07D317/68 , C07C69/612 , C07C69/734 , C07C69/65 , C07C69/616 , C07C69/738 , C07C69/736
摘要： A method that manufacturers an optically active carboxylic acid ester at high yield and high enantioselectivity is provided. An optically active carboxylic acid ester is manufactured at high yield and high enantioselectivity by reacting a racemic carboxylic acid and a specific alcohol or phenol derivatives in a polar solvent having a dipole moment of 3.0 or higher in the presence of an acid anhydride and an asymmetric catalyst, esterifying one enantiomer of the racemic carboxylic acid at high selectivity, and increasing the amount of esterified carboxylic acid by racemizing the optically active carboxylic acid which is the other enantiomer not used in esterification.
摘要翻译： 提供了以高产率和高对映选择性制造光学活性羧酸酯的方法。 通过在酸酐和不对称催化剂的存在下，使外消旋羧酸和特定的醇或苯酚衍生物在偶极矩为3.0或更高的极性溶剂中反应，以高产率和高对映选择性制备光学活性羧酸酯 以高选择性酯化外消旋羧酸的一种对映异构体，并通过外消旋化作为酯化反应中未使用的另一对映异构体的光学活性羧酸来增加酯化羧酸的量。
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公开(公告)号：US20150298109A1
公开(公告)日：2015-10-22
申请号：US14438543
申请日：2013-10-28
IPC分类号： B01J31/02 , C07C335/20 , C07D207/16 , C07F9/655 , C07F9/6553 , C07F9/58 , C07F9/535 , C07F9/50
CPC分类号： B01J31/0271 , B01J31/0218 , B01J31/0232 , B01J31/0241 , B01J31/0249 , B01J31/0267 , B01J2231/346 , C07C335/20 , C07D207/16 , C07F9/5054 , C07F9/5355 , C07F9/58 , C07F9/65515 , C07F9/655345
摘要： The present invention provides a bifunctional catalyst of the formula (1): wherein: each R1 is independently selected from an optionally substituted alkyl group, an optionally substituted cycloalkyl group, an optionally substituted aryl group, an optionally substituted heteroaryl group, an optionally substituted aralkyl group and an optionally substituted alkaryl group; Z represents a divalent organic linking moiety optionally containing one or more stereocentres; and EWG represents an electron-withdrawing group. (R1)3P═N—Z—NH-EWG (1)
摘要翻译： 本发明提供式（1）的双官能催化剂：其中：每个R 1独立地选自任选取代的烷基，任选取代的环烷基，任选取代的芳基，任选取代的杂芳基，任选取代的芳烷基 基团和任选取代的烷芳基; Z表示任选含有一个或多个立体中心的二价有机连接部分; EWG代表吸电子基团。 （R1）3P = N-Z-NH-EWG（1）
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6.发明授权Process for preparation of oligomeric or polymeric compounds using selective Michael addition 有权使用选择性迈克尔加成制备低聚物或聚合物的方法公开(公告)号：US08524958B2
公开(公告)日：2013-09-03
申请号：US12665748
申请日：2008-06-13
申请人： Richard M. Jones , Steven H. Nahm
发明人： Richard M. Jones , Steven H. Nahm
CPC分类号： B01J23/04 , B01J31/0237 , B01J31/0239 , B01J31/0241 , B01J31/0245 , B01J31/0267 , B01J31/04 , C07C67/347 , C08G61/12 , C08G2261/334 , C08L65/00 , C07C69/716
摘要： A method of preparing an oligomeric or polymeric compound in a liquid solution is disclosed which consists of reacting a Michael donor compound with a Michael acceptor compound in the presence of a first catalyst and a Group IA and/or Group IIA metal ion catalyst.
摘要翻译： 公开了一种在液体溶液中制备低聚物或聚合物的方法，该方法由迈克尔供体化合物与迈克尔受体化合物在第一催化剂和IAA族和/或IIA族金属离子催化剂存在下反应而成。
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公开(公告)号：US6127301A
公开(公告)日：2000-10-03
申请号：US884124
申请日：1997-06-27
申请人： Kiyoshi Iwanaga , Mitsuhisa Tamura
发明人： Kiyoshi Iwanaga , Mitsuhisa Tamura
IPC分类号： B01J31/22 , B01J31/02 , B01J31/04 , B01J31/12 , C07B61/00 , C07C2/30 , C07C2/32 , C07C11/107 , C08F4/609 , C08F4/622 , C08F4/69 , C08F4/78 , C08F10/00 , C08F10/02 , C10G50/00 , B01J31/00 , B01J21/08 , C07C2/02 , C08F4/44
CPC分类号： B01J31/04 , B01J31/0241 , B01J31/122 , C07C2/30 , C08F10/00 , B01J2231/20 , B01J2531/62 , C07C2531/02 , C07C2531/14
摘要： The present invention provides a novel catalyst system which can be preferably used in the trimerization, oligomerization reaction or polymerization reaction of an olefin, and a method for the trimerization, oligomerization or polymerization reaction of an olefin, which comprises using the catalyst system. A catalyst system obtained by contacting the following components (A) to (C):(A) a chromium compound,(B) an imine compound, and(C) a metal alkyl compound, and a method for the trimerization, oligomerization or polymerization reaction of an olefin, which comprises using the catalyst system are disclosed.
摘要翻译： 本发明提供了可以优选用于烯烃的三聚，低聚反应或聚合反应的新型催化剂体系，以及包含使用该催化剂体系的烯烃三聚，低聚或聚合反应的方法。 通过使以下成分（A）〜（C）与（A）铬化合物，（B）亚胺化合物，（C）金属烷基化合物）和（C）金属烷基化合物接触而得到的催化剂体系，以及三聚，低聚或聚合的方法 公开了包含使用催化剂体系的烯烃的反应。
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公开(公告)号：US3948965A
公开(公告)日：1976-04-06
申请号：US488603
申请日：1974-07-12
申请人： James N. Cawse
发明人： James N. Cawse
IPC分类号： C07C69/04 , B01J31/20 , B01J31/24 , C07B61/00 , C07C27/00 , C07C27/06 , C07C29/15 , C07C29/151 , C07C29/158 , C07C31/04 , C07C31/18 , C07C41/00 , C07C41/01 , C07C43/10 , C07C67/00
CPC分类号： B01J31/0241 , B01J31/0267 , B01J31/0271 , B01J31/181 , B01J31/20 , B01J31/4046 , C07C29/1512 , C07C29/1514 , C07C29/158 , B01J2231/648 , B01J2531/0211 , B01J2531/822 , Y02P20/52 , Y02P20/584
摘要： This invention relates to the manufacture of such valuable chemicals as polyhydric alcohols, their ether and ester derivatives, oligomers of such alcohols and monohydric alcohols and their ether and ester derivatives by reacting oxides of carbon and hydrogen in the presence of a bis(triorgano phosphine)iminium cation and a rhodium carbonyl complex provided to the reaction as a rhodium carbonyl cluster anion which possesses an infrared spectrum which exhibits three intense wavelength bands between about plus and minus 10 cm.sup.-.sup.1 of about 1868 cm.sup.-.sup.1, about 1838 cm.sup.-.sup.1, and about 1785 cm.sup.-.sup.1 at a pressure of at least about 500 pounds per square inch absolute.
摘要翻译： 本发明涉及在双（三有机膦）存在下，通过使碳和氢的氧化物反应来制造这种有价值的化学物质，如多元醇，它们的醚和酯衍生物，这些醇和一元醇的低聚物及其醚和酯衍生物， 亚胺鎓阳离子和铑羰基络合物，其作为具有红外光谱的铑羰基簇阴离子提供给反应，该红外光谱在约1868cm -1的约+ 10cm -1之间呈现出三个强的波长带，约1838cm -1 cm -1至约1785cm -1，压力为至少约500磅/平方英寸绝对压力。
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公开(公告)号：US20180008967A1
公开(公告)日：2018-01-11
申请号：US15428123
申请日：2017-02-08
发明人： Taekyung YU , WooSik KIM , Aasim SHAHZAD , Minyoung YI
IPC分类号： B01J27/10 , B01J27/08 , C02F1/74 , C02F1/32 , B01J31/06 , B01J37/03 , B01J37/02 , B01J23/50 , B01J35/00 , B01J31/26 , B01J35/08 , B01J37/04
CPC分类号： B01J27/10 , B01J23/50 , B01J27/08 , B01J31/0241 , B01J31/06 , B01J31/064 , B01J31/26 , B01J35/0006 , B01J35/0013 , B01J35/004 , B01J35/08 , B01J37/0221 , B01J37/031 , B01J37/04 , C02F1/325 , C02F1/725 , C02F1/74 , C02F2305/08 , C02F2305/10
摘要： The present invention relates to a hybrid nanostructured photocatalyst, comprising a first nanoparticle comprising silver halide (AgX); a second nanoparticle, which is formed on an outer surface of the first nanoparticle and comprises Ag; and a polymer formed on any one outer surface of the first nanoparticle and the second nanoparticle, and a preparation method thereof. Specifically, the present invention provides a hybrid nanostructured photocatalyst having a high photocatalytic activity in a visible light region and a preparation method thereof.
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10.发明申请公开(公告)号：US20160304795A1
公开(公告)日：2016-10-20
申请号：US15198346
申请日：2016-06-30
发明人： Michael P. LANCI , Stuart L. SOLED , Javier GUZMAN , Sabato MISEO , Thomas E. GREEN , Joseph E. BAUMGARTNER , Lei ZHANG , Christine E. KLIEWER , Lukasz KOZIOL , Kanmi MAO , Tracie L. OWENS , Gary P. SCHLEICHER
IPC分类号： C10G69/02 , B01J23/44 , C10M101/02 , B01J23/42
CPC分类号： C10M101/02 , B01J21/12 , B01J23/42 , B01J23/44 , B01J23/464 , B01J23/468 , B01J31/0241 , B01J31/28 , B01J35/002 , B01J35/006 , B01J35/1019 , B01J35/1047 , B01J35/1061 , B01J37/0009 , B01J37/0201 , B01J37/0203 , B01J37/0207 , B01J37/088 , C10G45/34 , C10G45/46 , C10G45/52 , C10G65/12 , C10G2300/202 , C10M2203/1006
摘要： Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation.
摘要翻译： 提供了用于修饰具有二氧化硅载体（或其它非氧化铝载体）的另外的氧化铝的氢化催化剂的方法，并且使用这样的催化剂实现了出人意料的优异的原料氢化。 改进的氢化催化剂可以具有相对低的裂化活性，同时提供增加的氢化活性。
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