摘要:
The present invention relates to a method for preparing poly(organic oxidized silicon) particles having UV-absorbing groups, including reacting an organoalkoxysilane precursor having a UV-absorbing group selected from a group consisting of organotrialkoxysilane, diorganoalkoxysilane and a mixture thereof, in the presence of a base, with a silane compound selected from a group consisting of tetraalkoxysilane, alkyltrialkoxysilane, tetraalkoxysilane, aryltrialkoxysilane, dialkyldialkoxysilane, diaryldialkoxysilane, arylalkyldialkoxysilane and a mixture thereof, serving as a crosslinking regulator and UV stability enhancer, so as to prepare poly(organic oxidized silicon) particles selected from a group consisting of polysilsesquioxane, silsesquioxane-siloxane copolymer, silsesquioxane-silica copolymer, silsesquioxane-siloxane-silica copolymer and silsesquioxane-siloxane copolymer, having UV-absorbing groups. The poly(organic oxidized silicon) particles significantly solves the problem of poor UV stability, while maintaining UV absorption by the UV-absorbing group contained in the particles. Since the poly(organic oxidized silicon) particles having UV-absorbing groups do not exhibit white turbidity, they can be effectively used in cosmetics. In accordance with the present invention, the poly(organic oxidized silicon) particles having UV-absorbing groups can be prepared economically as compared to the existing methods.
摘要:
The present invention relates to a method for preparing poly(organic oxidized silicon) particles having UV-absorbing groups, including reacting an organoalkoxysilane precursor having a UV-absorbing group selected from a group consisting of organotrialkoxysilane, diorganoalkoxysilane and a mixture thereof, in the presence of a base, with a silane compound selected from a group consisting of tetraalkoxysilane, alkyltrialkoxysilane, tetraalkoxysilane, aryltrialkoxysilane, dialkyldialkoxysilane, diaryldialkoxysilane, arylalkyldialkoxysilane and a mixture thereof, serving as a crosslinking regulator and UV stability enhancer, so as to prepare poly(organic oxidized silicon) particles selected from a group consisting of polysilsesquioxane, silsesquioxane-siloxane copolymer, silsesquioxane-silica copolymer, silsesquioxane-siloxane-silica copolymer and silsesquioxane-siloxane copolymer, having UV-absorbing groups. The poly(organic oxidized silicon) particles significantly solves the problem of poor UV stability, while maintaining UV absorption by the UV-absorbing group contained in the particles. Since the poly(organic oxidized silicon) particles having UV-absorbing groups do not exhibit white turbidity, they can be effectively used in cosmetics. In accordance with the present invention, the poly(organic oxidized silicon) particles having UV-absorbing groups can be prepared economically as compared to the existing methods.
摘要:
A real time monitoring system of a spent fuel pool includes a detection unit configured to detect condition information using a sensor installed in the spent fuel pool; an input storage unit configured to receive and store configuration information of a spent fuel, history information related to burnup, and a normal value and a limit value of current condition information; an operation and determination unit configured to calculate the current condition information of the spent fuel by using the condition information detected by the detection unit and the configuration information and the history information stored in the input storage unit and configured to determine a risk level by comparing the current condition information with the limit value corresponding to the risk level; and a display unit configured to display the current condition information calculated by the operation and determination unit and configured to display the determined risk level.
摘要:
An apparatus for cooling a spent fuel pool having a heat exchanger includes a cooling water pool positioned above the spent fuel pool; a floating device configured to be elevated according to a water level of a cooling water in the spent fuel pool; and an emergency cooling water supply pipe configured to form a path through which the cooling water of the cooling water pool is moved to the spent fuel pool and configured to include a floating valve that opens or closes a flow passage of the cooling water in connection with the elevation of the floating device.
摘要:
A passive cooling system of a nuclear power plant includes a steam generator, a cooling water storage tank, a water cooling heat exchanger, an air cooling heat exchanger, a divergence valve, and a cooling tower. The steam generator generates steam by heat exchange with a primary coolant system, and the cooling water storage tank stores cooling water therein. The water cooling heat exchanger is disposed in the cooling water storage tank, and the air cooling heat exchanger is connected to the steam generator. The divergence valve is controllable to divert steam from the steam generator into both the water cooling heat exchanger and the air cooling heat exchanger. Each of the cooling water storage tank, the water cooling heat exchanger, and the air cooling heat exchanger are located in the cooling tower.
摘要:
An apparatus for cooling a spent fuel pool having a heat exchanger includes a cooling water pool positioned above the spent fuel pool; a floating device configured to be elevated according to a water level of a cooling water in the spent fuel pool; and an emergency cooling water supply pipe configured to form a path through which the cooling water of the cooling water pool is moved to the spent fuel pool and configured to include a floating valve that opens or closes a flow passage of the cooling water in connection with the elevation of the floating device.
摘要:
A number of new poly(organophosphazenes) have been synthesized which bear 2-butenoxy or 4-allyloxyphenylphenoxy side groups. Co-substituent groups included trifluoroethoxy, phenoxy, or benzyloxyphenoxy groups. Species with 4-allyloxyphenylphenoxy units underwent Si--H coupling to linear silanes or siloxanes to extend the side groups and form hybrid phosphazene/organosilicon polymers. A number of these polymers are rubbery elastomers which are readily cross-linked by heat or light. Seven of the mixed-substituent, cross-linked polymers were incorporated into interpenetrating polymer networks (IPN's) with polystyrene, poly(methyl methacrylate), polyacrylonitrile, poly(acrylic acid) and poly(dimethylsiloxane). The phase compatibility characteristics of the IPN's were assessed by DSC, TEM, FT-IR spectroscopy, and 1H and 31P NMR spectroscopy data.
摘要:
A passive cooling system of a nuclear power plant includes a cooling water storage tank configured to store a cooling water therein, a steam generation unit to which the cooling water is supplied from the cooling water storage tank connected thereto, the supplied cooling water being heated to generate a steam, a water cooling heat exchange unit connected to the steam generation unit and provided within the cooling water storage tank, and an air cooling heat exchange unit connected to the steam generation unit and provided outside the cooling water storage tank.
摘要:
A real time monitoring system of a spent fuel pool includes a detection unit configured to detect condition information using a sensor installed in the spent fuel pool; an input storage unit configured to receive and store configuration information of a spent fuel, history information related to burnup, and a normal value and a limit value of current condition information; an operation and determination unit configured to calculate the current condition information of the spent fuel by using the condition information detected by the detection unit and the configuration information and the history information stored in the input storage unit and configured to determine a risk level by comparing the current condition information with the limit value corresponding to the risk level; and a display unit configured to display the current condition information calculated by the operation and determination unit and configured to display the determined risk level.