摘要:
The present invention relates to a transition metal half metallocene catalyst with a noble structure for preparing syndiotatic styrene polymer having high activity, superior stereoregularity, high melting point and broad molecular weight distribution and a process for preparing styrene polymer using the same. The present invention provides a half metallocene catalyst having a single nucleus structure, in which a transition metal in Groups 3 to 10 on the periodic table is connected to a cycloalkanedienyl group or its derivative forming 5-coordinate bond on a side thereof and to any one of triethanolamine, N-alkyldiethanolamine and N-dialkylethanolamine group, all of which have a plurality of binding sites and high steric hinderance, on the other side thereof. The noble metallocene catalyst according to the present invention is useful for preparing highly syndiotatic vinyl aromatic polymer with broad molecular weight distribution and high activity.
摘要:
Disclosed is a multinuclear transition metal half metallocene catalyst having a multinuclear half metallocene structure in which a transition metal of groups 3 to 10 on periodic table is connected to a cycloalkandienyl group or its derivative group on a side and also connected to phenol or phenolamine compound having a plurality of binding sites on another side. The metallocene catalyst is useful to produce syndiotatic styrene polymer having superior steroreguality, high melting point and broad molecular weight distribution with high activity together with a small amount of a cocatalyst. Further disclosed is a method for preparing styrene polymers using the same catalyst.
摘要:
The present invention relates to a transition metal half metallocene catalyst with a noble structure for preparing syndiotatic styrene polymer having high activity, superior stereoregularity, high melting point and broad molecular weight distribution and a process for preparing styrene polymer using the same. The present invention provides a half metallocene catalyst having a single nucleus structure, in which a transition metal in Groups 3 to 10 on the periodic table is connected to a cycloalkanedienyl group or its derivative forming 5-coordinate bond on a side thereof and to any one of triethanolamine, N-alkyldiethanolamine and N-dialkylethanolamine group, all of which have a plurality of binding sites and high steric hinderance, on the other side thereof. The noble metallocene catalyst according to the present invention is useful for preparing highly syndiotatic vinyl aromatic polymer with broad molecular weight distribution and high activity.
摘要:
Disclosed is a multinuclear transition metal half metallocene catalyst having a multinuclear half metallocene structure in which a transition metal of groups 3 to 10 on periodic table is connected to a cycloalkandienyl group or its derivative group on a side and also connected to phenol or phenolamine compound having a plurality of binding sites on another side. The metallocene catalyst is useful to produce syndiotatic styrene polymer having superior steroreguality, high melting point and broad molecular weight distribution with high activity together with a small amount of a cocatalyst. Further disclosed is a method for preparing styrene polymers using the same catalyst.
摘要:
The present invention relates to a method for preparing a styrenic olefin. The method of the present invention comprises the steps of: adding a catalyst and a solvent in a reactor and heating the reactor to create a reflux state; adding an alcohol starting material to the reactor dropwise at a constant rate; removing water generated by adding the alcohol starting material from the reactor, and purifying the obtained styrenic olefin. The method of the present invention is advantageous in minimizing byproducts and preparing styrenic olefins having a variety of substituents in high yield.
摘要:
The present invention relates to a method for preparing a styrenic olefin. The method of the present invention comprises the steps of: adding a catalyst and a solvent in a reactor and heating the reactor to create a reflux state; adding an alcohol starting material to the reactor dropwise at a constant rate; removing water generated by adding the alcohol starting material from the reactor, and purifying the obtained styrenic olefin. The method of the present invention is advantageous in minimizing byproducts and preparing styrenic olefins having a variety of substituents in high yield.
摘要:
A computer system, a control method thereof and a recording medium storing a computer program thereof are provided to recover a program efficiently and be resistant to viruses, worms, and user error. The control method of computer system receives a user's request for a recovery of a program which is installed in a first storage unit. A file system of a second storage unit is determined which stores therein a recovery program corresponding to the program for which the recovery is requested. The recovery program is read from the second storage unit with reference to the determined file system, and the program in the first storage unit is recovered by using the read recovery program.
摘要:
Disclosed are a computer system storing with a restoration program and a method of updating the restoration program, the computer system including: a first storage unit in which a predetermined program is installed, a second storage unit in which a restoration program corresponding to the program is stored, a communication unit which communicates with an external server, a user input unit, and a controller which stores an update file corresponding to the program received from the external server in the first storage unit, and updates the program installed in the first storage with the update file, the controller updating the restoration program of the second storage unit with the update file of the first storage unit if receiving a certain key input through the user input unit, and restoring the program on the basis of the updated restoration program.
摘要:
A computer system, a control method thereof and a recording medium storing a computer program thereof are provided to recover a program efficiently and be resistant to viruses, worms, and user error. The control method of computer system receives a user's request for a recovery of a program which is installed in a first storage unit. A file system of a second storage unit is determined which stores therein a recovery program corresponding to the program for which the recovery is requested. The recovery program is read from the second storage unit with reference to the determined file system, and the program in the first storage unit is recovered by using the read recovery program.