公开(公告)号：US06482523B1

公开(公告)日：2002-11-19

申请号：US09280006

申请日：1999-03-29

申请人： Yukihiro Morikawa ,  Hiroyoshi Yano ,  Ichiro Higashikubo ,  Toshiaki Sasahara

发明人： Yukihiro Morikawa ,  Hiroyoshi Yano ,  Ichiro Higashikubo ,  Toshiaki Sasahara

IPC分类号： B32B2700

CPC分类号： B32B27/08 ,  B32B7/12 ,  B32B27/32 ,  B32B2323/043 ,  B32B2323/046 ,  B32B2325/00 ,  B32B2367/00 ,  B32B2369/00 ,  C08G18/0823 ,  C08G18/6659 ,  C09J175/04 ,  Y10T428/31507 ,  Y10T428/31551 ,  Y10T428/31565 ,  Y10T428/31573 ,  Y10T428/31587 ,  Y10T428/31605

摘要： An adhesive for lamination which comprises a resin whose dynamic wettability to a film substrate is at least 0.20 mN alone or in combination with a polyisocyanate curing agent, said adhesive for lamination having a good adhesiveness to a film substrate such as a plastic film, a metal foil, a metallized film or paper.

摘要翻译： 一种用于层压的粘合剂，其包含对膜基材的动态润湿性单独至少为0.20mN或与多异氰酸酯固化剂组合的树脂，所述层压粘合剂对薄膜基材如塑料膜，金属 箔，金属化膜或纸。

公开(公告)号：US06649084B2

公开(公告)日：2003-11-18

申请号：US09911713

申请日：2001-07-25

申请人： Yukihiro Morikawa ,  Ichiro Higashikubo ,  Kouji Yoshida ,  Toshiaki Sasahara

发明人： Yukihiro Morikawa ,  Ichiro Higashikubo ,  Kouji Yoshida ,  Toshiaki Sasahara

IPC分类号： C07C27112

CPC分类号： C08G18/792 ,  C08G18/283 ,  C08G18/664 ,  C08G18/718 ,  C08G18/809 ,  C09J175/04

摘要： A polyisocyanate curing agent comprising an isocyanate group-terminated prepolymer and a silane coupling agent represented by formula (2), OCN—(CH2)x—Si(OR′)3  (2) wherein R is an alkyl group having 1 to 5 carbon atoms and m and n is each an integer of 1 or more; and an adhesive for forming laminates based on the above polyisocyanate curing agent and an active hydrogen-group containing resin.

摘要翻译： 一种多异氰酸酯固化剂，其包含异氰酸酯基封端的预聚物和由式（2）表示的硅烷偶联剂，其中R为具有1至5个碳原子的烷基，m和n各自为1或更大的整数; 以及基于上述多异氰酸酯固化剂和含活性氢基树脂形成层压体的粘合剂。

公开(公告)号：US06596819B2

公开(公告)日：2003-07-22

申请号：US09915256

申请日：2001-07-27

申请人： Yukihiro Morikawa ,  Ichiro Higashikubo ,  Kouji Yoshida ,  Toshiaki Sasahara

发明人： Yukihiro Morikawa ,  Ichiro Higashikubo ,  Kouji Yoshida ,  Toshiaki Sasahara

IPC分类号： C08G1800

CPC分类号： C08G18/718 ,  B32B7/12 ,  C08G18/022 ,  C08G18/225 ,  C08G18/289 ,  C08G18/3206 ,  C08G18/4216 ,  C08G18/4277 ,  C08G18/4825 ,  C08G18/7621 ,  C09J175/08

摘要： A polyisocyanate curing agent for laminate adhesive, comprising: (A) an isocyanate group-terminated prepolymer having isocyanurate group and urethane group, obtained by reacting an organic polyisocyanate containing at least (a1) an aromatic diisocyanate with an active hydrogen group-containing compound containing at least (a2) a diol compound having a number-average molecular weight of 100 to 2,000, and, as an optional component, (B) an isocyanate group-terminated prepolymer having urethane group, and, also as an optional component, (C) a silane coupling agent represented by the following general formula (1): OCN—(CH2)m—Si(OR)3  (1)  (wherein R is a methyl group or an ethyl group, and m is an integer of 1 to 5); and a process for producing the polyisocyanate curing agent. The polyisocyanate curing agent is usable in a laminate adhesive which can be aged in a short time without shortening the pot life, which has good adhesivity, and which can withstand a severe retort treatment.

摘要翻译： 一种层叠粘合剂用聚异氰酸酯固化剂，其特征在于，含有：（A）具有异氰脲酸酯基和异氰酸酯基的异氰酸酯基封端的预聚物，其通过使至少含有（a1）芳香族二异氰酸酯的有机多异氰酸酯与含有活性氢基的化合物反应得到， 至少（a2）数均分子量为100〜2,000的二醇化合物，作为任意成分，（B）具有氨基甲酸酯基的异氰酸酯基封端的预聚物，作为任意成分，（C ）由以下通式（1）表示的硅烷偶联剂：（其中R是甲基或乙基，m是1至5的整数）; 以及多异氰酸酯固化剂的制造方法。 多异氰酸酯固化剂可用于能够在短时间内老化而不缩短适用期的粘合剂，并且能够承受严重的蒸煮处理的层压粘合剂中。

公开(公告)号：US06309507B1

公开(公告)日：2001-10-30

申请号：US09260126

申请日：1999-03-01

申请人： Yukihiro Morikawa ,  Toshiaki Sasahara ,  Shin Konishi

发明人： Yukihiro Morikawa ,  Toshiaki Sasahara ,  Shin Konishi

IPC分类号： C09J10100

CPC分类号： C09J175/04 ,  C08G18/10 ,  C08G18/664 ,  C08G18/798 ,  C08G18/8064 ,  C08G18/32

摘要： A polyisocyanate curing agent for a laminate adhesive, which comprises a hydrophilic polar group-containing polyisocyanate; a laminate adhesive excellent in heat-resistance, durability and adhesiveness to polyolefin film which adhesive comprises the above hydrophilic polar group-containing polyisocyanate and an active hydrogen-containing compound; and use of an adhesive comprising the above polyisocyanate curing agent and an active hydrogen-containing compound in film lamination.

摘要翻译： 一种用于层压粘合剂的多异氰酸酯固化剂，其包含含亲水极性基团的多异氰酸酯; 粘合剂包括上述亲水极性基团的多异氰酸酯和含活性氢的化合物的耐热性，耐久性和与聚烯烃膜的粘合性优异的层压粘合剂; 以及在膜层压中使用包含上述多异氰酸酯固化剂和含活性氢化合物的粘合剂。

公开(公告)号：US06743374B2

公开(公告)日：2004-06-01

申请号：US10208034

申请日：2002-07-31

申请人： Motomu Kita ,  Mitsushige Ikemoto ,  Toshiaki Sasahara

发明人： Motomu Kita ,  Mitsushige Ikemoto ,  Toshiaki Sasahara

IPC分类号： C08G1822

CPC分类号： C08G18/222 ,  C08G18/283 ,  C08G18/706 ,  C08G18/7837

摘要： A self-emulsifiable polyisocyanate with high functionality, having the average number of functional groups in 4.3 or more and a viscosity of 8,000 mPa·s (at 25° C.) or less, which is obtained by subjecting a modified polyisocyanate containing allophanate bonds and a poly(oxyalkylene)glycol monoalkyl ether (e) having oxyethylene bonds in a total amount of 30 mole % or more in its molecule to a urethanization reaction, said modified polyisocyanate being obtained by reacting a polyol (a) having the average number of functional groups in an amount of 2 or more with an organic polyisocyanate (b) in the presence of an allophanate-forming catalyst (c) comprising a zirconium carboxylate; and a process for producing the same.

摘要翻译： 具有高官能度的自乳化多异氰酸酯，其官能团的平均数为4.3以上，粘度为8,000mPa.s（25℃）以下，其通过使含有脲基甲酸酯键的改性多异氰酸酯和 所述改性多异氰酸酯通过使具有平均数量的官能团的多元醇（a）反应获得，所述聚（异氰酸酯）是分子内具有30摩尔％以上氧化乙烯键的聚（氧化烯）二醇单烷基醚（e） 在含有羧酸锆的脲基甲酸酯形成催化剂（c）的存在下，使用有机多异氰酸酯（b）的量为2以上的基团; 及其制造方法。

公开(公告)号：US06306947B1

公开(公告)日：2001-10-23

申请号：US09320718

申请日：1999-05-27

申请人： Takeshi Morishima ,  Shunsuke Murakami ,  Toshiaki Sasahara ,  Shin Konishi ,  Kazuya Sugimoto

发明人： Takeshi Morishima ,  Shunsuke Murakami ,  Toshiaki Sasahara ,  Shin Konishi ,  Kazuya Sugimoto

IPC分类号： C08F26108

CPC分类号： C09D11/10 ,  C08F283/006 ,  C08G18/0819 ,  C08G18/3876 ,  C08G18/4277 ,  C08G18/6659 ,  C09D175/04 ,  Y10S525/92

摘要： An aqueous emulsion which comprises as a resin component a self-emulsifiable copolymer in which at least one ethylenically unsaturated monomer and at least one urethane prepolymer having at least one mercapto group and at least one hydrophilic, polar group are bonded by radical polymerization or in which at least one ethylenically unsaturated monomer, at least one organic polyisocyanate, at least one compound having at least one mercapto group and at least one active hydrogen-containing group and at least one compound having at least one hydrophilic, polar group and at least one active hydrogen-containing group are bonded by urethanization reaction and radical polymerization. The aqueous emulsion is better in storage stability than conventional ones.

摘要翻译： 一种水性乳液，其包含作为树脂组分的自乳化共聚物，其中至少一种烯键式不饱和单体和至少一种具有至少一个巯基和至少一个亲水性极性基团的氨基甲酸酯预聚物通过自由基聚合键合，或其中 至少一种烯键式不饱和单体，至少一种有机多异氰酸酯，至少一种具有至少一个巯基和至少一个含活性氢基团的化合物和至少一种具有至少一个亲水性极性基团和至少一种活性基团的化合物 含氢基团通过氨基甲酸酯化反应和自由基聚合键合。 水乳液的储存稳定性优于常规乳液。