公开(公告)号：US20130116348A1

公开(公告)日：2013-05-09

申请号：US13809104

申请日：2011-07-08

申请人： Yulin Shi ,  Xiuzhang Wu ,  Lei Gong ,  Quan Lin ,  Yijun Lv ,  Yifeng Bu ,  Hongxue Wang

发明人： Yulin Shi ,  Xiuzhang Wu ,  Lei Gong ,  Quan Lin ,  Yijun Lv ,  Yifeng Bu ,  Hongxue Wang

IPC分类号： C10G2/00

CPC分类号： C10G2/32 ,  C10G2/332 ,  C10G2/34 ,  C10G2/342 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10K1/005

摘要： The present invention relates to a Fischer-Tropsch synthesis process and system. The process comprises: a) introducing a feedstock gas containing CO and H2 into a first stage Fischer-Tropsch synthesis reactor to carry out a Fischer-Tropsch synthesis reaction; b) separating products of the first stage Fischer-Tropsch synthesis reaction, to separate water from the unconverted tail gas and to obtain hydrocarbon products and the unconverted tail gas; c) introducing the unconverted tail gas obtained in Step b) into a second stage Fischer-Tropsch synthesis reactor to carry out a Fischer-Tropsch synthesis reaction; d) separating products of the second stage Fischer-Tropsch synthesis reaction, to separate water from the unconverted tail gas, with a portion of the unconverted tail gas of the second stage Fischer-Tropsch synthesis reaction being returned to the second stage Fischer-Tropsch synthesis reactor for recycle reactions. The process and system are suitable for large-scale industrialized production.

摘要翻译： 本发明涉及费 - 托合成方法和系统。 该方法包括：a）将含有CO和H 2的原料气体引入第一级费 - 托合成反应器中以进行费 - 托合成反应; b）分离第一阶段费 - 托合成反应的产物，从未转化的尾气中分离水并获得烃产物和未转化的尾气; c）将步骤b）中获得的未转化的尾气引入第二级费 - 托合成反应器中以进行费 - 托合成反应; d）分离第二级费 - 托合成反应的产物，从未转化的尾气分离出水，第二级费 - 托合成反应的未转化尾气的一部分返回到第二级费 - 托合成 反应器用于再循环反应。 该工艺和系统适用于大规模工业化生产。

公开(公告)号：US20090283450A2

公开(公告)日：2009-11-19

申请号：US11572638

申请日：2008-09-03

申请人： Yuzhuo Zhang ,  Geping Shu ,  Jialu Jin ,  Minli Cui ,  Xiuzhang Wu ,  Xiangkun Ren ,  Yaowu Xu ,  Shipu Liang ,  Jianwei Huang ,  Ming Yuan ,  Juzhong Gao ,  Yufei Zhu

发明人： Yuzhuo Zhang ,  Geping Shu ,  Jialu Jin ,  Minli Cui ,  Xiuzhang Wu ,  Xiangkun Ren ,  Yaowu Xu ,  Shipu Liang ,  Jianwei Huang ,  Ming Yuan ,  Juzhong Gao ,  Yufei Zhu

IPC分类号： C10G1/06

CPC分类号： C10G1/002 ,  C10G1/065 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2300/42 ,  C10G2300/44

摘要： Process for direct coal liquefaction of coal, including: (1) preparing a coal slurry from raw coal; (2) preheating the coal slurry, then feeding it into reaction system to undergo liquefaction reaction; (3) separating reaction products in a separator to form a liquid phase and a gas phase, wherein the liquid phase is fractionated in an atmospheric tower into a light oil fraction and a bottom product; (4) feeding the atmospheric tower bottom product to a vacuum tower to separate into distillate and vacuum residue; (5) mixing the light oil fraction and the distillate to form a mixture, then feeding the mixture to a suspended bed hydrotreating reactor with forced circulation for hydrogenation; (6) fractionating hydrogenation products into oil products and a hydrogen donor recycling solvent. The process can operate long periods, with higher reactor efficiency and utilization factor, increased liquid oil yield and can supply high-quality feedstock for further processing.

摘要翻译： 煤炭直接煤液化工艺，包括：（1）从原煤制备煤浆; （2）预热煤浆，然后送入反应体系进行液化反应; （3）在分离器中分离反应产物以形成液相和气相，其中将液相在常压塔中分馏成轻油馏分和底部产物; （4）将大气塔底产物供给真空塔分离成馏出物和减压渣油; （5）将轻油馏分和馏出物混合以形成混合物，然后将混合物进料到具有强制循环氢化的悬浮床加氢处理反应器中; （6）将氢化产物分馏成油产物和氢供体回收溶剂。 该工艺可长时间运行，反应器效率更高，利用率更高，液体油产量提高，可供应优质原料进一步加工。

公开(公告)号：US07763167B2

公开(公告)日：2010-07-27

申请号：US11572638

申请日：2005-07-27

申请人： Yuzhuo Zhang ,  Geping Shu ,  Jialu Jin ,  Minli Cui ,  Xiuzhang Wu ,  Xiangkun Ren ,  Yaowu Xu ,  Shipu Liang ,  Jianwei Huang ,  Ming Yuan ,  Juzhong Gao ,  Yufei Zhu

发明人： Yuzhuo Zhang ,  Geping Shu ,  Jialu Jin ,  Minli Cui ,  Xiuzhang Wu ,  Xiangkun Ren ,  Yaowu Xu ,  Shipu Liang ,  Jianwei Huang ,  Ming Yuan ,  Juzhong Gao ,  Yufei Zhu

IPC分类号： C10G1/06 ,  C10G1/00

CPC分类号： C10G1/002 ,  C10G1/065 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2300/42 ,  C10G2300/44

摘要： Process for direct coal liquefaction of coal, including: (1) preparing a coal slurry from raw coal; (2) preheating the coal slurry, then feeding it into reaction system to undergo liquefaction reaction; (3) separating reaction products in a separator to form a liquid phase and a gas phase, wherein the liquid phase is fractionated in an atmospheric tower into a light oil fraction and a bottom product; (4) feeding the atmospheric tower bottom product to a vacuum tower to separate into distillate and vacuum residue; (5) mixing the light oil fraction and the distillate to form a mixture, then feeding the mixture to a suspended bed hydrotreating reactor with forced circulation for hydrogenation; (6) fractionating hydrogenation products into oil products and a hydrogen donor recycling solvent. The process can operate long periods, with higher reactor efficiency and utilization factor, increased liquid oil yield and can supply high-quality feedstock for further processing.

摘要翻译： 煤炭直接煤液化工艺，包括：（1）从原煤制备煤浆; （2）预热煤浆，然后送入反应体系进行液化反应; （3）在分离器中分离反应产物以形成液相和气相，其中将液相在常压塔中分馏成轻油馏分和底部产物; （4）将大气塔底产物供给真空塔分离成馏出物和减压渣油; （5）将轻油馏分和馏出物混合以形成混合物，然后将混合物进料到具有强制循环氢化的悬浮床加氢处理反应器中; （6）将氢化产物分馏成油产物和氢供体回收溶剂。 该工艺可长时间运行，反应器效率更高，利用率更高，液体油产量提高，可供应优质原料进一步加工。

公开(公告)号：US20090152171A1

公开(公告)日：2009-06-18

申请号：US11572638

申请日：2005-07-27

申请人： Yuzhuo Zhang ,  Geping Shu ,  Jialu Jin ,  Minli Cui ,  Xiuzhang Wu ,  Xiangkun Ren ,  Yaowu Xu ,  Shipu Liang ,  Jianwei Huang ,  Ming Yuan ,  Juzhong Gao ,  Yufei Zhu

发明人： Yuzhuo Zhang ,  Geping Shu ,  Jialu Jin ,  Minli Cui ,  Xiuzhang Wu ,  Xiangkun Ren ,  Yaowu Xu ,  Shipu Liang ,  Jianwei Huang ,  Ming Yuan ,  Juzhong Gao ,  Yufei Zhu

IPC分类号： C10G1/06

CPC分类号： C10G1/002 ,  C10G1/065 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2300/42 ,  C10G2300/44

摘要： Process for direct coal liquefaction of coal, including: (1) preparing a coal slurry from raw coal; (2) preheating the coal slurry, then feeding it into reaction system to undergo liquefaction reaction; (3) separating reaction products in a separator to form a liquid phase and a gas phase, wherein the liquid phase is fractionated in an atmospheric tower into a light oil fraction and a bottom product; (4) feeding the atmospheric tower bottom product to a vacuum tower to separate into distillate and vacuum residue; (5) mixing the light oil fraction and the distillate to form a mixture, then feeding the mixture to a suspended bed hydrotreating reactor with forced circulation for hydrogenation; (6) fractionating hydrogenation products into oil products and a hydrogen donor recycling solvent. The process can operate long periods, with higher reactor efficiency and utilization factor, increased liquid oil yield and can supply high-quality feedstock for further processing.

摘要翻译： 煤炭直接煤液化工艺，包括：（1）从原煤制备煤浆; （2）预热煤浆，然后送入反应体系进行液化反应; （3）在分离器中分离反应产物以形成液相和气相，其中将液相在常压塔中分馏成轻油馏分和底部产物; （4）将大气塔底产物供给真空塔分离成馏出物和减压渣油; （5）将轻油馏分和馏出物混合以形成混合物，然后将混合物进料到具有强制循环氢化的悬浮床加氢处理反应器中; （6）将氢化产物分馏成油产物和氢供体回收溶剂。 该工艺可长时间运行，反应器效率更高，利用率更高，液体油产量提高，可供应优质原料进一步加工。