Process for the Preparation of Random Radical Copolymers, and Active Substance Compositions Obtainable Therefrom
    9.
    发明申请
    Process for the Preparation of Random Radical Copolymers, and Active Substance Compositions Obtainable Therefrom 审中-公开
    制备随机自由基共聚物及其可获得的活性物质组合物的方法

    公开(公告)号:US20110237439A1

    公开(公告)日:2011-09-29

    申请号:US13132117

    申请日:2009-11-30

    摘要: A process for the preparation of random radical copolymers which comprises a) at least one olefinically unsaturated sulfonic acid of the formula (I), where n is 0 to 10; X is 0 or NR5; R1 is hydrogen or methyl; R2, R3 independently of one another are hydrogen or C1- to C6-alkyl and R5 is hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, it being possible for the aryl radicals to be monosubstituted or polysubstituted, salts thereof or mixtures of acid and salts and b) at least two structurally different olefinically unsaturated monomers of the formula (II), where Y is O or NR7; R5 is hydrogen or methyl; R6 is alkyl, hydroxyalkyl, (di)alkylaminoalkyl or (di)alkylaminoaryl and R7 is hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, it being possible for the aryl radicals to be monosubstituted or polysubstituted, and c) if appropriate, one or more olefinically unsaturated monomers which differ structurally from components (a) and (b), d) at least one initiator being dissolved either (i) in a solvent mixture comprising water and a water-soluble organic solvent with a boiling point of less than 140° C. or (ii) being dissolved in one or more pure alcohols by heating, and being polymerized in solution, where the polymer formed remains in solution. The copolymers which are obtainable by the process are suitable as formulation adjuvants in agrochemical active substance compositions.

    摘要翻译: 一种制备无规自由基共聚物的方法,其包括a)至少一种式(I)的烯属不饱和磺酸,其中n为0至10; X为0或NR5; R1是氢或甲基; R 2,R 3彼此独立地是氢或C 1 -C 6 - 烷基,R 5是氢,烷基,芳基,烷基芳基,芳基烷基,烷氧基烷基,芳氧基烷基,烷氧基芳基,羟基烷基,(二)烷基氨基烷基,(二)烷基氨基芳基,(二) 芳基氨基烷基,烷基芳基氨基烷基或烷基芳基氨基芳基,芳基可以是单取代或多取代的,其盐或酸和盐的混合物,以及b)至少两种结构不同的具有式(II)的烯属不饱和单体,其中Y是O或 NR7; R5是氢或甲基; R6是烷基,羟基烷基,(二)烷基氨基烷基或(二)烷基氨基芳基,R7是氢,烷​​基,芳基,烷基芳基,芳基烷基,烷氧基烷基,芳氧基烷基,烷氧基芳基,羟基烷基,(二)烷基氨基烷基,(二)烷基氨基芳基,(二) 烷基芳基氨基烷基或烷基芳基氨基芳基,芳基可以被单取代或多取代,以及c)如果合适的话,一种或多种在结构上与组分(a)和(b)不同的烯属不饱和单体,d)至少一个引发剂 (i)在包含水和沸点小于140℃的水溶性有机溶剂的溶剂混合物中溶解,或(ii)通过加热溶解在一种或多种纯醇中,并在溶液中聚合, 所形成的聚合物保留在溶液中。 可通过该方法获得的共聚物适合作为农药活性物质组合物中的制剂佐剂。

    Aqueous dispersion comprising pesticide particles and dissolved saccharide
    10.
    发明授权
    Aqueous dispersion comprising pesticide particles and dissolved saccharide 失效
    含有农药颗粒和溶解糖的水分散体

    公开(公告)号:US08541012B2

    公开(公告)日:2013-09-24

    申请号:US13140039

    申请日:2009-12-10

    IPC分类号: A01N25/00

    摘要: The present invention relates to an aqueous dispersion comprising solid pesticide particles with a particle size of below 10 μm and a saccharide which is dissolved in the aqueous phase. The invention furthermore relates to a process for the preparation of a dispersion according to the invention by bringing a pesticide and a saccharide, which is a monosaccharide, a disaccharide or a mixture of mono- and disaccharide, into contact and dispersing them. A further subject matter relates to the use of a saccharide for slowing down the particle growth of pesticide particles with a particle size of up to 10 μm in aqueous dispersion, to the use of the dispersion or the solid composition for controlling phytopathogenic fungi and/or undesired vegetation and/or undesired attack by insects or mites and/or for regulating the growth of plants. Finally, the present invention also relates to seed, dressed with the dispersion or the solid composition.

    摘要翻译: 本发明涉及一种水分散体,其包含粒径小于10um的固体农药颗粒和溶解在水相中的糖类。 本发明还涉及通过使作为单糖,二糖或单糖和二糖的混合物的农药和糖类与其接触分散来制备本发明分散体的方法。 另一主题涉及使用糖类来减缓水分散体中粒径达10微米的农药颗粒的颗粒生长,使用分散体或固体组合物来控制植物病原性真菌和/或 不期望的植被和/或昆虫或螨的不期望的攻击和/或用于调节植物的生长。 最后,本发明还涉及用分散体或固体组合物修饰的种子。