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1.发明授权公开(公告)号：US07157504B2
公开(公告)日：2007-01-02
申请号：US10261441
申请日：2002-09-30
CPC分类号： C09D11/30 , B41M5/0017 , B41M7/0018 , C09D11/54
摘要： Systems and methods for providing smudge resistant and durable ink-jet images having good optical density are provided. Specifically, a system for printing durable ink-jet ink images can comprise a set of two ink-jet pens, preferably thermal ink-jet pens. The first ink-jet pen contains an ink-jet ink, wherein the ink-jet ink comprises a first liquid vehicle, from 0.5% to 6% by weight of a pigment colorant, and from 0.2% to 15% by weight of an anionic or neutral latex-containing colloidal suspension. The second ink-jet pen contains a fixer composition, wherein the fixer composition comprises effective amounts of second liquid vehicle, and from 0.2% to 15% by weight of a cationic polymer such as poly(vinyl pyridine) salts, polyalkylaminoethyl acrylates, polyalkylaminoethyl methacrylates, poly(vinyl imidazole); or preferably, polyethyleneimines, polybiguanides, and/or polyguanides. When applied to the substrate, upon overprinting or underprinting the fixer composition with respect to the ink-jet ink, a durable and smudge resistant image is formed. A method of the present invention can utilize the system and provide for underprinting or overprinting the fixer composition as desired.
摘要翻译： 提供了用于提供具有良好光密度的耐污染和持久的喷墨图像的系统和方法。 具体来说，用于印刷耐用喷墨墨水图像的系统可以包括一组两个喷墨笔，优选热喷墨笔。 第一喷墨笔包含喷墨油墨，其中喷墨油墨包括第一液体载体，0.5重量％至6重量％的颜料着色剂和0.2重量％至15重量％的阴离子 或含中性胶乳的胶体悬浮液。 第二喷墨笔包含定影剂组合物，其中定影剂组合物包含有效量的第二液体载体，和0.2重量％至15重量％的阳离子聚合物，例如聚（乙烯基吡啶）盐，聚烷基氨基乙基丙烯酸酯，聚烷基氨基乙基甲基丙烯酸酯 ，聚（乙烯基咪唑）; 或优选地，聚乙烯亚胺，聚双胍和/或聚胍。 当施加到基材上时，对于定影剂组合物相对于喷墨油墨进行套印或印刷，形成耐久且耐污染的图像。 本发明的方法可以利用该系统并根据需要提供定影剂组合物的印刷或套印。
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公开(公告)号：US08148461B2
公开(公告)日：2012-04-03
申请号：US11983158
申请日：2007-11-06
CPC分类号： C09D11/30 , C08K5/005 , C08K9/10 , Y10T428/2989
摘要： A composition and method of associating stabilizer functionalities with latex particulates is provided. The composition can comprise a latex particulate configured for inclusion in an ink-jet ink to provide improved humidfastness of an image printed by the ink-jet ink, wherein the latex particulate has a molecular weight from 10,000 Mw to 10,000,000 Mw, and has a particle size from 10 nm to 2 μm; and an image stabilizer configured for improving lightfastness of the image, wherein the image stabilizer is bound to the latex particulate. The method can comprise the steps of coupling a polymerizable monomer with a stabilizing agent reactive with the polymerizable monomer, thereby forming a precursor stabilizer-containing monomer; polymerizing the precursor stabilizer-containing monomer to form a latex particulate; and decoupling the stabilizing agent from the latex particulate.
摘要翻译： 提供了一种将稳定剂官能团与胶乳颗粒缔合的组合物和方法。 该组合物可以包括被配置为包括在喷墨油墨中以提供由喷墨油墨印刷的图像的改善的耐湿性的胶乳颗粒，其中胶乳颗粒的分子量为10,000Mw至10,000,000Mw，并且具有颗粒 尺寸从10nm到2μm; 以及图像稳定器，其被配置为提高图像的耐光性，其中图像稳定剂结合到胶乳颗粒。 该方法可以包括将可聚合单体与可聚合单体反应的稳定剂偶联的步骤，从而形成含前体稳定剂的单体; 聚合含前体稳定剂的单体以形成胶乳颗粒; 并使稳定剂与胶乳颗粒分离。
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公开(公告)号：US07411011B2
公开(公告)日：2008-08-12
申请号：US10404260
申请日：2003-03-31
CPC分类号： C09D11/54 , B41M7/0027 , C09D11/30 , Y10T428/24802
摘要： Compositions, systems, and methods for protecting an ink-jet produced image printed on a substrate are provided. The composition can comprise a liquid vehicle and latex particulates dispersed in the liquid vehicle, wherein the latex particulates have a surface dielectric constant from 2.0 to 3.0 at room temperature, and a bulk density from 0.1 g/cm3 less to 0.1 g/cm3 greater than the vehicle density. An alternative composition can comprise a liquid vehicle and latex particulates dispersed in the liquid vehicle, wherein the latex particulates have a reactive surfactant covalently attached thereto.
摘要翻译： 提供了用于保护印刷在基板上的喷墨产生图像的组合物，系统和方法。 组合物可以包含分散在液体载体中的液体载体和胶乳颗粒，其中胶乳颗粒在室温下的表面介电常数为2.0至3.0，堆积密度为0.1g / cm 3 小于0.1g / cm 3，大于车辆密度。 替代组合物可以包含分散在液体载体中的液体载体和胶乳颗粒，其中胶乳颗粒具有共价连接到其上的反应性表面活性剂。
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4.发明授权Low bulk density, low surface dielectric constant latex polymers for ink-jet ink applications 有权低体积密度，用于喷墨油墨应用的低表面介电常数胶乳聚合物公开(公告)号：US07402617B2
公开(公告)日：2008-07-22
申请号：US10360473
申请日：2003-02-06
CPC分类号： C09D11/30
摘要： The present invention is drawn toward latex particulates in ink-jet inks having a surface dielectric constant from 2.0 to 3.0.
摘要翻译： 本发明涉及表面介电常数为2.0〜3.0的喷墨油墨中的胶乳微粒。
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公开(公告)号：US07358301B2
公开(公告)日：2008-04-15
申请号：US10322032
申请日：2002-12-17
IPC分类号： C08L75/04
CPC分类号： C09D11/30 , C08K5/005 , C08K9/10 , Y10T428/2989
摘要： A composition and method of associating stabilizer functionalities with latex particulates is provided. The composition can comprise a latex particulate configured for inclusion in an ink-jet ink to provide improved humidfastness of an image printed by the ink-jet ink, wherein the latex particulate has a molecular weight from 10,000 Mw to 10,000,000 Mw, and has a particle size from 10 nm to 2 μm; and an image stabilizer configured for improving durability of the image, wherein the image stabilizer is bound to or otherwise associated with the latex particulate. The method can comprise the steps of coupling a polymerizable monomer with a stabilizing agent reactive with the polymerizable monomer, thereby forming a stabilizer precursor-containing monomer; polymerizing the stabilizer-containing monomer to form a latex particulate; and decoupling the stabilizing agent from the latex particulate.
摘要翻译： 提供了一种将稳定剂官能团与胶乳颗粒缔合的组合物和方法。 该组合物可以包括配置成包括在喷墨油墨中以提供由喷墨油墨印刷的图像的改善的耐湿性的胶乳颗粒，其中胶乳颗粒的分子量为10,000Mw至10,000,000Mw，并且具有颗粒 大小从10nm到2um; 以及图像稳定器，其被配置为改善图像的耐久性，其中图像稳定器结合或以其他方式与胶乳颗粒相关联。 该方法可以包括将可聚合单体与可聚合单体反应的稳定剂偶联，由此形成含稳定剂前体的单体; 聚合含稳定剂的单体以形成胶乳颗粒; 并使稳定剂与胶乳颗粒分离。
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公开(公告)号：US08273933B2
公开(公告)日：2012-09-25
申请号：US13051812
申请日：2011-03-18
CPC分类号： C08F2/22 , C08F8/00 , C08F8/02 , C08F220/02
摘要： A method for forming a functionalized latex polymer includes polymerizing a heterogeneous dispersion of water insoluble monomers in water, thereby forming a latex polymer. An at least partially water soluble halogenated non-ionic group is reacted with the latex polymer, whereby a halogen is displaced from the non-ionic group, thereby forming an at least partially water soluble non-ionic group that attaches to the latex polymer.
摘要翻译： 形成官能化胶乳聚合物的方法包括将水不溶性单体的非均相分散体聚合在水中，从而形成胶乳聚合物。 将至少部分水溶性的卤代非离子基团与胶乳聚合物反应，由此卤素从非离子基团位移，从而形成附着于胶乳聚合物的至少部分水溶性非离子基团。
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公开(公告)号：US20070298165A1
公开(公告)日：2007-12-27
申请号：US11895868
申请日：2007-08-27
CPC分类号： C09D11/54 , B41M7/0027 , C09D11/30 , Y10T428/24802
摘要： Compositions, systems, and methods for protecting an ink-jet produced image printed on a substrate are provided. The composition can comprise a liquid vehicle and latex particulates dispersed in the liquid vehicle, wherein the latex particulates have a surface dielectric constant from 2.0 to 3.0 at room temperature, and a bulk density from 0.90 g/cm3 to 1.10 g/cm3. An alternative composition can comprise a liquid vehicle and latex particulates dispersed in the liquid vehicle, wherein the latex particulates have a reactive surfactant covalently attached thereto.
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公开(公告)号：US07119133B2
公开(公告)日：2006-10-10
申请号：US10360472
申请日：2003-02-06
摘要： The present invention is drawn to a latex-encapsulated particulate, comprising a particulate from 30 nm to 150 nm in size, and a latex at least partially encapsulating the particulate. The latex can have a surface dielectric constant from 2.0 to 3.0 at room temperature, and the latex-encapsulated particulate can have a bulk density from 0.90 g/cm3 to 2.0 g/cm3.
摘要翻译： 本发明涉及胶乳包封的颗粒，其包含尺寸为30nm至150nm的颗粒，以及至少部分包封颗粒的胶乳。 胶乳在室温下的表面介电常数可以为2.0〜3.0，胶乳包封的颗粒的体积密度可以为0.90g / cm 3〜2.0g / cm 3， / SUP>。
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公开(公告)号：US06841591B2
公开(公告)日：2005-01-11
申请号：US10059840
申请日：2002-01-28
CPC分类号： C09D11/30
摘要： A method for stabilizing a dye in an ink comprising the dye and a vehicle is provided. The ink is intended for printing on a print medium, which may comprise a variety of surfaces. The method comprises: (a) providing at least one dye moiety (molecule or monomer); (b) encapsulating the dye moiety in a transparent polymeric matrix to form an encapsulated dye particle that provides a barrier to protect the dye moiety; and (c) incorporating the encapsulated dye particle in the ink. The dye moiety is substantially water-insoluble. Consequently, the method of the present invention enables the use of hydrophobic colorants in a hydrophilic vehicle. A hydrophobic film thus forms on the print medium upon drying.
摘要翻译： 提供了一种用于稳定包含染料和载体的油墨中的染料的方法。 墨水用于在可以包括各种表面的打印介质上进行打印。 该方法包括：（a）提供至少一个染料部分（分子或单体）; （b）将染料部分包封在透明聚合物基质中以形成包封的染料颗粒，其提供保护染料部分的屏障; 和（c）将包封的染料颗粒结合在油墨中。 染料部分基本上不溶于水。 因此，本发明的方法能够在亲水性载体中使用疏水性着色剂。 因此，干燥后在印刷介质上形成疏水膜。
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公开(公告)号：US20110172358A1
公开(公告)日：2011-07-14
申请号：US13051812
申请日：2011-03-18
CPC分类号： C08F2/22 , C08F8/00 , C08F8/02 , C08F220/02
摘要： A method for forming a functionalized latex polymer includes polymerizing a heterogeneous dispersion of water insoluble monomers in water, thereby forming a latex polymer. An at least partially water soluble halogenated non-ionic group is reacted with the latex polymer, whereby a halogen is displaced from the non-ionic group, thereby forming an at least partially water soluble non-ionic group that attaches to the latex polymer.
摘要翻译： 形成官能化胶乳聚合物的方法包括将水不溶性单体的非均相分散体聚合在水中，从而形成胶乳聚合物。 将至少部分水溶性的卤代非离子基团与胶乳聚合物反应，由此卤素从非离子基团位移，从而形成附着于胶乳聚合物的至少部分水溶性非离子基团。
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