公开(公告)号：US12012371B2

公开(公告)日：2024-06-18

申请号：US17640092

申请日：2020-08-14

申请人： thyssenkrupp Industrial Solutions AG ,  thyssenkrupp AG

发明人： Nils Tenhumberg ,  Stefan Gehrmann ,  Michael Kleiber

IPC分类号： C07C27/08 ,  B01D3/14 ,  B01D3/36 ,  B01D3/40 ,  B01D53/14 ,  B01D53/22 ,  B01D61/36 ,  C07C1/04 ,  C07C7/00 ,  C07C7/06 ,  C07C7/08 ,  C07C7/11 ,  C07C7/144 ,  C07C29/04 ,  C10G53/08

CPC分类号： C07C27/08 ,  B01D3/145 ,  B01D3/36 ,  B01D3/40 ,  B01D53/1418 ,  B01D53/1425 ,  B01D53/1487 ,  B01D53/229 ,  B01D61/362 ,  C07C1/043 ,  C07C1/0485 ,  C07C7/005 ,  C07C7/06 ,  C07C7/08 ,  C07C7/11 ,  C07C7/144 ,  C07C29/04 ,  C10G53/08 ,  B01D2252/205 ,  B01D2311/2626 ,  B01D2311/2669 ,  C07C2521/18 ,  C07C2523/72 ,  C07C2523/75 ,  C07C2523/889 ,  C10G2400/20

摘要： A process can produce alcohols having at least two carbon atoms by catalytic conversion of synthesis gas into a mixture containing alkanes, alkenes, and alcohols. Alkenes are converted into corresponding alcohols in a subsequent step by hydration of the alkanes. Before the hydration and after the catalytic conversion, gas and liquid phases may be separated. Specific catalysts can be employed that have a markedly higher selectivity for alkenes than for alkanes. These catalysts comprise grains of non-graphitic carbon having cobalt nanoparticles dispersed therein. The cobalt nanoparticles have an average diameter dp from 1 to 20 nm, and an average distance D between nanoparticles is from 2 to 150 nm. The combined total mass fraction of metal ω in the grains ranges from 30% to 70% by weight of the total mass of the grains of non-graphitic carbon, wherein 4.5 dp/ω>D≥0.25 dp/ω.