-
公开(公告)号：US08519194B2
公开(公告)日：2013-08-27
申请号：US13145007
申请日：2009-11-24
CPC分类号： B01J29/7676 , B01J29/7476 , C07C2/76 , Y02P20/52 , C07C13/28
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone comprising a catalyst system which comprises a molecular sieve and at least one hydrogenation metal. The MCM-22 family molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and the hydrogenation metal is selected from the group consisting of palladium, ruthenium, nickel, zinc, tin, cobalt, and combinations of any two or more thereof. Hydroalkylation conditions of temperature and pressure are selected to produce a hydroalkylation conversion in a range of from about 15% to about 75% The benzene and hydrogen are then contacted in the at least one reaction zone under said selected hydroalkylation condition to produce an effluent containing cyclohexylbenzene.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个包含催化剂体系的反应区，该催化剂体系包含分子筛和至少一种氢化金属。 具有12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃的d间距最大值的X射线衍射图的MCM-22族分子筛，氢化金属选自钯， 钌，镍，锌，锡，钴及其任何两种或更多种的组合。 选择温度和压力的烷基化条件以产生约15％至约75％的加氢烷基转化率。然后在所述选择的加氢烷基化条件下，使苯和氢在至少一个反应区中接触，以产生含有环己基苯 。
-
公开(公告)号：US07179948B2
公开(公告)日：2007-02-20
申请号：US10739086
申请日：2003-12-19
申请人： Bernhard Scholz , Franz Nierlich , Dieter Reusch , Silvia Santiago Fernandez , Andreas Beckmann , Wilfried Bueschken , Alfred Kaizik
发明人： Bernhard Scholz , Franz Nierlich , Dieter Reusch , Silvia Santiago Fernandez , Andreas Beckmann , Wilfried Bueschken , Alfred Kaizik
摘要： The invention relates to a process for preparing tert-butanol by reaction of a homogeneous mixture comprising water, tert-butanol and an isobutene-containing hydrocarbon mixture over an acidic ion-exchange resin at from 30 to 120° C., wherein the homogeneous mixture contains, at a proportion by mass of isobutene of above 10%, from 30 to 80% of the maximum amount of water made possible by the solubility of water in the mixture of tert-butanol and the isobutene-containing hydrocarbon mixture.
摘要翻译： 本发明涉及一种通过酸性离子交换树脂在30〜120℃下由包含水，叔丁醇和含异丁烯的烃混合物的均匀混合物反应制备叔丁醇的方法，其中均匀混合物 以大于10％的异丁烯的比例含有由水在叔丁醇和含异丁烯的烃混合物的混合物中的溶解度而产生的最大量的水的30至80％。
-
3.发明授权
公开(公告)号：US4194990A
公开(公告)日：1980-03-25
申请号：US869730
申请日：1978-01-16
摘要： Catalyst and process for the production of chlorofluorinated hydrocarbons are disclosed by reacting a hydrocarbon with HCl, HF and an oxygen-containing gas under oxychlorofluorination conditions in the presence of a catalytic composition comprising magnesium and copper ions each in combination with fluoride ions and an alkali metal ion, or mixtures thereof, in combination with chloride ions.
摘要翻译： 催化剂和制备氯氟烃的方法通过在含氟氯离子和碱金属的催化剂组合物存在下，在含氟氯氟化条件下，将烃与HCl，HF和含氧气体反应， 离子或其混合物，与氯离子组合。
-
公开(公告)号：US08802901B2
公开(公告)日：2014-08-12
申请号：US13299878
申请日：2011-11-18
申请人： R. Jay Warner , Wei Qi , Tatiana Sonnenberg
发明人： R. Jay Warner , Wei Qi , Tatiana Sonnenberg
摘要： Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying acetic acid and an alcohol such as ethanol to produce an esterification product. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture. Ethyl acetate from the crude reaction mixture may be recovered as returned to assist in recovering the esterification product.
摘要翻译： 本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。 该方法包括酯化乙酸和醇如乙醇以产生酯化产物。 在催化剂存在下，用氢还原酯化产物，得到包含可与粗反应混合物分离的醇，特别是乙醇的粗反应混合物。 可以从粗反应混合物中回收乙酸乙酯以帮助回收酯化产物。
-
5.发明申请METHOD FOR PRODUCING BIO-FUEL THAT INTEGRATES HEAT FROM CARBON-CARBON BOND-FORMING REACTIONS TO DRIVE BIOMASS GASIFICATION REACTIONS 有权生物燃料的生物燃料的方法，其将从碳卡结合反应加热到驱动生物质气化反应公开(公告)号：US20110086927A1
公开(公告)日：2011-04-14
申请号：US12962747
申请日：2010-12-08
IPC分类号： C07C27/08
CPC分类号： C10G2/332 , C01B3/326 , C01B2203/0233 , C01B2203/0283 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/0811 , C01B2203/0838 , C01B2203/0866 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1217 , C10G2/32 , C10G2/333 , C10G2300/1011 , Y02E50/13 , Y02E50/32 , Y02P20/52 , Y02P30/20
摘要： A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.
摘要翻译： 描述了在吸热气化反应中将生物质（优选从制备生物柴油回收的甘油）转化为合成气（即H 2 / CO气体混合物）的低温催化方法。 合成气用于放热碳 - 碳键形成反应，如费 - 托，甲醇或二甲醚合成。 来自放热碳 - 碳键形成反应的热量与吸热气化反应相结合，从而为从可再生生物质资源生产燃料和化学物质提供了节能途径。
-
6.发明申请公开(公告)号：US20100160693A1
公开(公告)日：2010-06-24
申请号：US12642954
申请日：2009-12-21
IPC分类号： C07C27/08
摘要： A process is provided for making a reaction product comprising 1-butanol by contacting a reactant comprising ethanol containing a significant amount of water with a decomposed hydrotalcite catalyst. The catalyst may be 1) hydrotalcites which have been thermally decomposed, either partially or fully, to form catalytically active species; 2) combinations of hydrotalcites (optionally containing transition metals) and metal carbonates; and 3) hydrotalcites (optionally containing transition metals) surface-impregnated with a transition metal nitrate, where catalysts 2) and 3) have also been thermally decomposed, either partially or fully, to form catalytically active species. The catalyst, at a selected reaction time, has greater activity when the ethanol contains water as compared to when the ethanol is anhydrous.
摘要翻译： 提供了通过使包含大量水的乙醇的反应物与分解的水滑石催化剂接触来制备包含1-丁醇的反应产物的方法。 催化剂可以是1）部分或完全热分解以形成催化活性物质的水滑石; 2）水滑石（任选地含有过渡金属）和金属碳酸盐的组合; 和3）表面浸渍有过渡金属硝酸盐的水滑石（任选地含有过渡金属），其中催化剂2）和3）也被部分或全部热分解以形成催化活性物质。 与乙醇为无水相比，当乙醇含有水时，催化剂在选定的反应时间具有更大的活性。
-
公开(公告)号：US20110190551A1
公开(公告)日：2011-08-04
申请号：US12915625
申请日：2010-10-29
申请人： Radmila Jevtic , Victor J. Johnston , Lincoln Sarager , R. Jay Warner , Heiko Weiner , Trinity Horton
发明人： Radmila Jevtic , Victor J. Johnston , Lincoln Sarager , R. Jay Warner , Heiko Weiner , Trinity Horton
CPC分类号： B01J21/16 , B01J23/626 , B01J23/89 , B01J37/0009 , C07C29/141 , C07C67/055 , C07C31/08 , C07C69/15
摘要： In one embodiment, the invention is to a process for forming an ethanol mixture by hydrogenating an acetaldehyde feed stream in the presence of a catalyst. The acetaldehyde feed stream comprises acetaldehyde and at least one of acetic acid and ethanol. Preferably the acetaldehyde feed stream is a by-product stream from a vinyl acetate synthesis process.
摘要翻译： 在一个实施方案中，本发明涉及通过在催化剂存在下氢化乙醛进料流形成乙醇混合物的方法。 乙醛进料流包括乙醛和乙酸和乙醇中的至少一种。 优选地，乙醛进料流是来自乙酸乙烯酯合成方法的副产物流。
-
公开(公告)号：US20110098368A1
公开(公告)日：2011-04-28
申请号：US12907137
申请日：2010-10-19
申请人： Madhu Anand
发明人： Madhu Anand
IPC分类号： C07C27/08 , C01B17/20 , B01J27/051
CPC分类号： C01B17/20 , B01J21/066 , B01J27/051 , B01J35/026 , B01J37/0045 , B01J37/038 , B01J37/20 , C01G31/00 , C01G39/06 , C01G41/00 , C07C1/0445 , C07C2527/051 , C07C9/04
摘要： Methods and apparatus relate to catalysts and preparation of the catalysts, which are defined by sulfides of a transition metal, such as one of molybdenum, tungsten, and vanadium. Precipitation forms the catalysts and occurs in a slurry media in which the pH is adjusted. Exemplary uses of the catalysts include packing for a methanation reactor that converts carbon monoxide and hydrogen into methane.
摘要翻译： 方法和装置涉及催化剂和制备催化剂，其由过渡金属的硫化物如钼，钨和钒中的一种所定义。 沉淀形成催化剂并发生在其中调节pH的浆料介质中。 催化剂的示例性用途包括将一氧化碳和氢气转化为甲烷的甲烷化反应器的填料。
-
公开(公告)号：US06953867B2
公开(公告)日：2005-10-11
申请号：US10399655
申请日：2001-10-19
IPC分类号： C01G23/00 , B01J21/08 , B01J27/16 , B01J35/10 , C07B61/00 , C07C29/04 , C07C31/08 , C07C31/10 , C07C41/00 , C07C27/08
摘要： A catalyst support consisting mainly of synthetic silica, with 0.5-10 parts by weight of one or more oxides or phosphates of the elements of group IIA, IIIB, IVB, VB, VIB, VIIB, VIII, IB, IIB, IIIA, IVA and the lanthanides, wherein the support preparation method comprises mixing particulate synthetic silica with particulate oxides or phosphates of the elements of Groups IIA, IIIB, IVB, VB, VIB, VIIB, VIII, IB, IIB, IIIA, IVA and the lanthanides, or with precursors thereof, a forming step and calcinations. The catalyst support is used together with phosphoric acid in the production of alcohols from olefins by hydration.
摘要翻译： 主要由合成二氧化硅组成的催化剂载体，其具有0.5-10重量份的IIA，IIIB，IVB，VB，VIB，VIIB，VIII，IB，IIB，IIIA，IVA族元素的一种或多种氧化物或磷酸盐，以及 镧系元素，其中载体制备方法包括将颗粒状合成二氧化硅与IIA，IIIB，IVB，VB，VIB，VIIB，VIII，IB，IIB，IIIA，IVA族和镧系元素的元素的微粒氧化物或磷酸盐混合，或与 其前体，成型步骤和煅烧。 催化剂载体与磷酸一起用于通过水合由烯烃生产醇。
-
公开(公告)号：US5808107A
公开(公告)日：1998-09-15
申请号：US962365
申请日：1997-10-31
IPC分类号： C07D307/33 , C07C27/04 , C07C29/147 , C07C31/22 , C07C67/31 , C07C69/675 , C07D315/00 , C07D307/32 , C07C27/06 , C07C27/08
CPC分类号： C07D315/00
摘要： Preparation of 4-hydroxy substituted butyrolactones is described. A process for the preparation of 3-hydroxybutyrolactone, 1,2,4-trihydroxybutane and 3,4-dihydroxy acid methyl ester from malic acid is particularly described. The preparation of 4-hydroxymethyl-4-hydroxybutyric acid -1-methyl ester and 4-hydroxymethyl butyrolactone is particularly described. The compounds are intermediates to various pharmaceutical and agricultural products.
摘要翻译： 描述了4-羟基取代的丁内酯的制备。 特别描述了从苹果酸制备3-羟基丁内酯，1,2,4-三羟基丁烷和3,4-二羟基酸甲酯的方法。 特别描述了4-羟甲基-4-羟基丁酸-1-甲酯和4-羟甲基丁内酯的制备。 这些化合物是各种药物和农产品的中间体。
-
-
-
-
-
-
-
-
-
搜索结果
27 条记录 (耗时 0.021 秒)