SYNTHETIC METHOD AND APPLICATION OF 2-HYDROXYPHENYL-5-PYRAZINYL KETONE

    公开(公告)号:US20220033362A1

    公开(公告)日:2022-02-03

    申请号:US17388067

    申请日:2021-09-16

    发明人: Mei LUO

    IPC分类号: C07D239/26 B01J31/02

    摘要: Disclosed is a method of synthesizing a 2-hydroxyphenyl-5-pyrazinel ketone represented by the following chemical formula (I), comprising: weighing 0.048 g of a palladium complex, 0.8413 g of chromone-3-formaldehyde and 2.5719 g of ammonium formate into a 100 mL round bottom flask, then adding 50 mL of anhydrous methanol to dissolve, heating to reflux for 36 h, then stopping the reaction, performing column chromatography with petroleum ether and dichloromethane in a volume ratio of 1:1, and then naturally volatilizing the first component to obtain a light yellow crystal, namely the 2-hydroxyphenyl-5-pyrazinel ketone, referred to as compound (I); the chemical formula of the compound (I) is as follows: an application of compound (I) as a catalyst in the reaction of benzophenone imine and trimethylsilyl nitrile showing a good catalytic performance, with a conversion rate of 69.1%.

    Numerical control machine for stretch bending and monitoring method for clamping force of round clamp thereof

    公开(公告)号:US11517953B2

    公开(公告)日:2022-12-06

    申请号:US16719929

    申请日:2019-12-18

    IPC分类号: B21D11/02 G05B19/18

    摘要: A NC machine for stretch bending and monitoring method for clamping force of round clamp thereof is invented, which includes a round head clamp, a hydraulic system and a clamping force monitoring device. The round head clamp includes a housing, an internal module arranged in the housing and a positioning member for positioning the internal module in the housing. The hydraulic system includes a hydraulic rod and a hydraulic ram for pushing the hydraulic rod. The clamping force monitoring device includes a sensor and a data processing module. The present invention is suitable for the workpiece of different shapes and sizes. In this invention, the clamping force can be adjusted in real time when it needs to be changed, and this not only can avoid the problems of excessive energy consumption, excessive clamping marks and damage of the workpiece, but also save energy and protect the workpiece.

    Flexible-rope-driven hybrid spray painting robot mechanism and operating method thereof

    公开(公告)号:US11325243B2

    公开(公告)日:2022-05-10

    申请号:US17594388

    申请日:2020-05-27

    IPC分类号: B25J9/00 B25J11/00

    摘要: A flexible-rope-driven hybrid spray painting robot mechanism includes a static platform framework, a flexible-rope-guided pulley train, flexible transmission ropes, a moving platform, and drive mechanisms. A moving platform casing is driven by eight flexible ropes in parallel, to realize three degrees of freedom of translation thereof. A spray gun is connected in series to the moving platform casing via a universal joint cross, and is driven by four flexible ropes in parallel, to realize two degrees of freedom of rotation thereof. Beneficial technical effect of the present invention: The flexible ropes are used in parallel to control three degrees of freedom of translation and two degrees of freedom of rotation of the end spray gun, achieving advantages of a small movement inertia and flexible movement. Electric drive devices are placed together in a bottom layer of the static platform framework and are isolated from a spraying space.

    Dual-function starch-based composite nanoparticles as well as preparation method and application thereof

    公开(公告)号:US11203647B2

    公开(公告)日:2021-12-21

    申请号:US16740576

    申请日:2020-01-13

    摘要: The present application discloses dual-function starch-based composite nanoparticles as well as a preparation method and application thereof. The preparation method comprises: hydrolyzing starch to form linear dextrin, grading the linear dextrin by using an alcohol-alcohol gradient precipitation method to obtain linear dextrin having homogeneous molecular weight distribution; oxidizing the linear dextrin by adopting an oxidation system to obtain oxidized dextrin; carrying out complex reaction on the oxidized dextrin and curcumin to form an oxidized dextrin-curcumin complex; and forming an oxidized dextrin-curcumin/chitosan hydrochloride composite nanoparticles from the oxidized dextrin-curcumin complex and chitosan hydrochloride. The aqueous phase solution of the dual-function starch-based composite nanoparticles containing gel polysaccharide is uniformly mixed with primary emulsion, calcium ion induction is carried out on the obtained double emulsion to obtain double-emulsion gel.

    ROPE TRACTION TYPE GRINDING, CLEANING, AND COATING INTEGRATED OPERATION ROBOT

    公开(公告)号:US20210387351A1

    公开(公告)日:2021-12-16

    申请号:US17143841

    申请日:2021-01-07

    摘要: The present disclosure relates to a rope traction type grinding, cleaning, and coating integrated operation robot. The operation robot includes a hanging basket, a first traction mechanism connected to the hanging basket, a grinding mechanism arranged in front of the hanging basket, and a cleaning and spraying mechanism and a spring reaction force regulation mechanism arranged in the hanging basket. The first traction mechanism includes first ropes for connecting the hanging basket and first rope winding mechanisms. The cleaning and spraying mechanism includes a first vertical plate and a second vertical plate that are arranged in parallel in a vertical direction. A cleaning nozzle and a spraying nozzle are mounted on the first vertical plate. From the above technical solution, it can be seen that the operation robot adopts a rope traction manner, and has the advantages of large work space, low mechanism inertia, and accurate and reliable location.