公开(公告)号：US06849579B2

公开(公告)日：2005-02-01

申请号：US10603956

申请日：2003-06-25

申请人： James A. Armbruster ,  Dale R. Sanson

发明人： James A. Armbruster ,  Dale R. Sanson

IPC分类号： A01N43/42 ,  A01N43/824 ,  A01N43/56 ,  A01N43/653 ,  A01N43/84

CPC分类号： A01N43/42 ,  A01N61/00 ,  A01N47/36 ,  A01N39/04 ,  A01N43/653 ,  A01N43/56 ,  A01N43/84 ,  A01N43/90 ,  A01N33/22 ,  A01N2300/00

摘要： A selective synergistic postemergent herbicide composition is provided for the control of undesired broadleaf vegetation and grassyweeds comprising the combination of quinclorac and a selective herbicidal protox inhibitor. About 0.05 part to about 0.1 part by weight of the protox inhibitor is provided for each part by weight of quinclorac. Better synergistic results are obtained from the combination of quinclorac, a selective herbicidal protox inhibitor, and a selective herbicidal auxinic agent. About 0.05 part to about 0.1 part by weight of the protox inhibitor is provided for each part by weight of quinclorac, and about 1 part to about 4 parts by weight of the auxinic herbicidal agent for each part by weight of quinclorac. The synergistic composition hereof has been found to provide more rapid and better control of grassy weeds such as crabgrass than presently registered herbicides.

摘要翻译： 提供了一种选择性协同的出芽后除草剂组合物，用于控制不希望的阔叶植物和草草，其包含五氯酸和选择性除草前毒素抑制剂的组合。 为喹喔啉的每重量份提供约0.05〜0.1重量份的促毒素抑制剂。 五氯酚，选择性除草前毒素抑制剂和选择性除草生长素剂的组合获得更好的协同效果。 提供约0.05重量份至约0.1重量份的前毒素抑制剂，每重量份喹草酸，和约1重量份至约4重量份的生长素除草剂。 已经发现其协同组合可以比目前登记的除草剂更为快速和更好地控制诸如马唐的草地杂草。

公开(公告)号：US5416067A

公开(公告)日：1995-05-16

申请号：US173768

申请日：1993-12-27

申请人： John L. Van Haften ,  Roger P. Cahoy

发明人： John L. Van Haften ,  Roger P. Cahoy

IPC分类号： A01N25/08 ,  A01N37/40 ,  A01N37/44 ,  A01N39/02 ,  A01N39/04 ,  A01N37/10

CPC分类号： A01N25/08 ,  A01N37/40 ,  A01N37/44 ,  A01N39/02 ,  A01N39/04

摘要： A dry, water-soluble, substituted phenoxy and/or benzoic acid herbicide is prepared by grinding and dry blending the herbicide in acid form with anhydrous trisodium phosphate or tripotassium phosphate which functions as a solid solubilization medium. From about 0.6 mole to about 16.9 moles of the medium is provided for each mole of active herbicidal agent in the initially dry blended mixture. Herbicidal agents are selected from the group consisting of 2,4-D, 2,4-DB, MCPP, MCPA, dichlorprop, dicamba, and chloramben.

摘要翻译： 通过研磨和干燥将酸形式的除草剂与作为固体溶解介质起作用的无水磷酸三钠或磷酸三钾来制备干燥的水溶性取代的苯氧基和/或苯甲酸除草剂。 在初始干混混合物中每摩尔活性除草剂提供约0.6摩尔至约16.9摩尔的培养基。 除草剂选自2,4-D，2,4-DB，MCPP，MCPA，二氯丙酸，麦草畏和氯林本。

公开(公告)号：US20230284621A1

公开(公告)日：2023-09-14

申请号：US18181706

申请日：2023-03-10

申请人： PBI-Gordon Corporation

发明人： Dale Sanson ,  Jed G. Archuleta ,  Jeffrey W. Marvin

IPC分类号： A01N43/653 ,  A01N37/40

CPC分类号： A01N43/653 ,  A01N37/40

摘要： Stable, aqueous herbicidal compositions are provided, which comprise a phenoxy acid, a benzoic acid compound, a quinoline carboxylic acid, a triazolinone herbicide, a HPPD inhibitor, and a nonionic surfactant dissolved in water. In preferred embodiments, the herbicidal compositions also utilize a basic pH adjuster to provide compositions comprising a solubilized protox inhibitor or a solubilized HPPD inhibitor. The compositions may be provided as a concentrate or ready-to-use herbicidal compositions. Advantageously, compositions of the present invention are both physically and chemically stable when stored for prolonged periods in both ambient and extreme temperature. Additionally, the inventive compositions can provide improved broad control of undesired vegetation by controlling both adult plants and seedlings.

公开(公告)号：US20080311221A1

公开(公告)日：2008-12-18

申请号：US11763038

申请日：2007-06-14

申请人： Dale Sanson ,  James A. Armbruster

发明人： Dale Sanson ,  James A. Armbruster

IPC分类号： A01N25/04 ,  A01N37/10 ,  A01N43/16 ,  A01N43/40 ,  A01N43/42 ,  A01N43/56 ,  A01N59/26 ,  A01P15/00

CPC分类号： A01N25/04

摘要： A chemically and physically stable, transparent, hybrid pesticide concentrate is provided for preparation of a water-based microemulsion formulation. The pesticides preferably comprise an oil-soluble pesticide component, and a pesticide component having a Lewis acid pesticide portion and a pesticide complex portion. An inactive biphasic coupling agent for the pesticide ingredients includes a solvent capable of solvating the oil-soluble pesticide component, and two organic cosolvents capable of solvating the Lewis acid pesticide portion and the pesticide complex portion pesticide ingredients, respectively. A selected emulsifier is incorporated in the concentrate. A sufficient quantity of a complexing agent is provided to maintain the electrical potential of the final concentrate at a value of about −150 mV to about +150 mV. The inactive coupling agent and the complexing agent are sufficient relative to the quantity of the active pesticide ingredients to cause the concentrate to spontaneously form a microemulsion made up of particles that are less than 1μ when the concentrate is diluted with water.

摘要翻译： 提供化学和物理稳定，透明的混合农药浓缩物用于制备水基微乳液制剂。 农药优选包含油溶性农药组分和具有路易斯酸农药部分和农药复合物部分的农药组分。 用于农药成分的无活性双相偶联剂包括能够溶解油溶性农药组分的溶剂和能够分别溶解路易斯酸农药部分和农药复合部分农药成分的两种有机助溶剂。 选择的乳化剂掺入浓缩物中。 提供足量的络合剂以将最终浓缩物的电位保持在约-150mV至约+ 150mV的值。 惰性偶联剂和络合剂相对于活性农药成分的量是足够的，当浓缩物用水稀释时，浓缩物自发形成由小于1mu的颗粒组成的微乳液。

公开(公告)号：US20080090780A1

公开(公告)日：2008-04-17

申请号：US11549451

申请日：2006-10-13

申请人： Dale R. Sanson ,  James A. Armbruster

发明人： Dale R. Sanson ,  James A. Armbruster

IPC分类号： A01N65/00 ,  A01N37/08 ,  A01N43/02 ,  A01N37/34

CPC分类号： A01N65/00 ,  A01N49/00 ,  A01N65/12 ,  A01N65/26 ,  Y02A50/354 ,  A01N25/04 ,  A01N53/00

摘要： A storage stable, efficacious pesticide formulation is provided that is dilutable by the user and contains azadirachtin (AZA) and a pyrethrin or pyrethroid (PYR), and optionally an aprotic solvent and non-ionic, substantially water-free emulsifier. A sufficient amount of the PYR is provided to complex with the AZA A on opposite sides of the molecular structure thereof, thereby preventing rearrangement of the AZA A molecule in the presence of moisture that would result in hydrolysis and decomposition of AZA A. The AZA-PYR combination is sufficiently chemically stable such that less than 10% of the AZA A is decomposed when the formulation is subjected to an accelerated aging test for 30 days at 40° C. in a sealed container. The molar ratio of PYR to AZA A is preferably within the range of 0.5/1-10.5/1, more preferably within the range of 1.5/1-7/1, and most preferably with the range of 3/1-6/1. A solvent, when provided, should be in the range of about 70% to about 90% by weight based on the weight of the formulation, and the emulsifier should be within the range of about 0% to about 20%.

摘要翻译： 提供储存稳定，有效的农药制剂，其可由用户稀释，并含有印苦楝子素（AZA）和除虫菊酯或拟除虫菊酯（PYR），以及任选的非质子溶剂和非离子基本上无水的乳化剂。 提供足够量的PYR与其分子结构的相对侧上的AZA A复合，从而防止在存在导致AZA A的水解和分解的水分存在下的AZA A分子的重排。AZA- PYR组合具有足够的化学稳定性，使得当制剂在40℃下在密封容器中进行30天的加速老化试验时，少于10％的AZA A分解。 PYR与AZAA的摩尔比优选在0.5 / 1-10.5 / 1的范围内，更优选在1.5 / 1-7 / 1的范围内，最优选在3 / 1-6 / 1的范围内 。 当提供时，溶剂应基于制剂的重量计在约70％至约90％的范围内，并且乳化剂应在约0％至约20％的范围内。

公开(公告)号：US5280008A

公开(公告)日：1994-01-18

申请号：US76453

申请日：1993-06-14

申请人： Roger P. Cahoy ,  John L. Van Haften

发明人： Roger P. Cahoy ,  John L. Van Haften

IPC分类号： A01N43/40 ,  A01N25/08 ,  A01N25/12 ,  A01N37/10 ,  A01N37/34 ,  A01N37/40 ,  A01N37/44 ,  A01N39/02 ,  A01N39/04 ,  A01N43/42 ,  A01N43/88

CPC分类号： A01N25/08 ,  A01N25/12 ,  A01N37/40 ,  A01N37/44 ,  A01N39/02 ,  A01N39/04

摘要： Dry, water-soluble powder, substituted heterocyclic acid, substituted phenol herbicidal compositions, combinations thereof, or in combination with phenoxy and/or benzoic acid herbicides, are prepared by grinding and dry blending the herbicide in acid form with a dry, particulate solubilization medium selected from the group consisting of diammonium phosphate, dipotassium phosphate, disodium phosphate, trisodium phosphate or tripotassium phosphate. At least about 1 mole of the medium is provided for each mole of active herbicidal agent in the initially dry blended mixture. The dry blended mixture may be packaged in suitable containers such as paper bags, and added directly to a quantity of water to form a solubilized herbicidal formulation containing from about 0.1% to about 2-1/2% of the active herbicide and which is suitable for direct application to vegetation to be controlled.

摘要翻译： 干燥的水溶性粉末，取代的杂环酸，取代的苯酚除草组合物，其组合，或与苯氧基和/或苯甲酸除草剂组合，通过研磨和干燥酸形式的除草剂与干燥的颗粒增溶介质 选自磷酸二铵，磷酸氢二钾，磷酸二钠，磷酸三钠或磷酸三钾。 在初始干混混合物中每摩尔活性除草剂提供至少约1摩尔的培养基。 干混合的混合物可以包装在合适的容器如纸袋中，并直接加入一定量的水中以形成含有约0.1％至约2-1 / 2％活性除草剂的溶解的除草制剂，并且其是合适的 用于直接应用于要控制的植被。

公开(公告)号：US3937826A

公开(公告)日：1976-02-10

申请号：US466781

申请日：1974-05-03

申请人： Lewis P. Harris

发明人： Lewis P. Harris

IPC分类号： A01N25/00 ,  A01N9/36

CPC分类号： A01N25/006

摘要： A fly killing composition in granular form characterized by synergistic attractant properties, an unusually long useful life, and substantial resistance to inactivation due to moisture. The composition comprises a combination base of granular, dark colored fly attractant such as fish food containing meat by-product material, in conjunction with a cooked, bright yellow, sugar-based attractant. These materials are coated with and absorb into the interstices thereof fly-toxic quantities of a mixture of 2,2-dichlorovinyl 0,0-dimethyl phosphate and 0,0-dimethyl 0-2,4,5-trichlorophenylphosphorothioate. A dusting powder applied to the insecticide impregnated particles assures that the surfaces thereof present a dull appearance notwithstanding the presence of a substantial amount of sugar in the bait formulation. The resultant fly killing composition is extremely effective in attracting flies thereto, and by virtue of the fact that the toxicants thereof are absorbed into the attractant base, the bait is not susceptible to moisture inactivation and flies alighting thereon are not repelled by the toxicant but rather are quickly killed thereby. The preferred method of use comprises spreading a thin layer of granular bait on the ground or other surface proximal to areas where flies tend to congregate, for example in dairy barns or poultry-keeping pens.

公开(公告)号：US08053392B2

公开(公告)日：2011-11-08

申请号：US11626212

申请日：2007-01-23

申请人： Dale Sanson ,  James A. Armbruster

发明人： Dale Sanson ,  James A. Armbruster

IPC分类号： A01N25/00 ,  A01N63/00

CPC分类号： A01N25/04 ,  A01N25/22 ,  A01N39/02 ,  A01N39/04 ,  A01N43/40 ,  A01N43/56 ,  A01N37/40 ,  A01N2300/00

摘要： An auxin acid-catalyzed stable microemulsion pesticide formulation is provided that is clear and stable under a wide range of temperature conditions encountered during distribution, storage, and use of the pesticide formulation. A precursor for the microemulsion includes an auxin ester, a protox inhibitor, and an auxin acid stabilizing agent as active ingredients. Inactive ingredients in the precursor include a microemulsifier, a stabilizing co-emulsifier, a dispersant, and a solvent present in amounts such that when the precursor is added to water of dilution to form a concentrate or a ready-to-use formulation, the clear and stable microemulsion that is spontaneously formed has oily active ingredient-containing nano-sized particles no larger than about 1μ dispersed in the water.

摘要翻译： 提供生长素酸催化的稳定的微乳液农药制剂，其在分配，储存和使用农药制剂期间遇到的宽范围的温度条件下是清澈和稳定的。 微乳液的前体包括生长素酯，前毒素抑制剂和生长素酸稳定剂作为活性成分。 前体中的非活性成分包括微乳化剂，稳定助乳化剂，分散剂和溶剂，其用量使得当将前体加入到稀释水中以形成浓缩物或即用型制剂时，清澈 并且自发形成的稳定的微乳液具有分散在水中的不大于约1μ的含油活性成分的纳米尺寸颗粒。

公开(公告)号：US5221319A

公开(公告)日：1993-06-22

申请号：US745866

申请日：1991-08-16

申请人： John L. Van Haften ,  Roger P. Cahoy

发明人： John L. Van Haften ,  Roger P. Cahoy

IPC分类号： A01N25/08 ,  A01N37/40 ,  A01N37/44 ,  A01N39/02 ,  A01N39/04

CPC分类号： A01N37/44 ,  A01N25/08 ,  A01N37/40 ,  A01N39/02 ,  A01N39/04

摘要： A dry, water-soluble, substituted phenoxy and/or benzoic acid herbicide is prepared by dry blending the herbicide in acid form with a dry solid solubilization medium selected from the group consisting of diammonium phosphate, dipotassium phosphate, and disodium phosphate. At least about 1.15 moles of the medium are provided for each mole of active herbicidal agent in the initially dry blended mixture.

摘要翻译： 干燥的水溶性取代的苯氧基和/或苯甲酸除草剂通过将酸形式的除草剂与选自磷酸二氢铵，磷酸氢二钾和磷酸二钠的干固体溶解介质干混来制备。 在初始干混混合物中每摩尔活性除草剂提供至少约1.15摩尔的培养基。

公开(公告)号：US20080176921A1

公开(公告)日：2008-07-24

申请号：US11626212

申请日：2007-01-23

申请人： Dale Sanson ,  James A. Armbruster

发明人： Dale Sanson ,  James A. Armbruster

IPC分类号： A01N43/56 ,  A01N53/10 ,  A01N25/00

CPC分类号： A01N25/04 ,  A01N25/22 ,  A01N39/02 ,  A01N39/04 ,  A01N43/40 ,  A01N43/56 ,  A01N37/40 ,  A01N2300/00

摘要： An auxin acid-catalyzed stable microemulsion pesticide formulation is provided that is clear and stable under a wide range of temperature conditions encountered during distribution, storage, and use of the pesticide formulation. A precursor for the microemulsion includes an auxin ester, a protox inhibitor, and an auxin acid stabilizing agent as active ingredients. Inactive ingredients in the precursor include a microemulsifier, a stabilizing co-emulsifier, a dispersant, and a solvent present in amounts such that when the precursor is added to water of dilution to form a concentrate or a ready-to-use formulation, the clear and stable microemulsion that is spontaneously formed has oily active ingredient-containing nano-sized particles no larger than about 1μ dispersed in the water.

摘要翻译： 提供生长素酸催化的稳定的微乳液农药制剂，其在分配，储存和使用农药制剂期间遇到的宽范围的温度条件下是清澈和稳定的。 微乳液的前体包括生长素酯，前毒素抑制剂和生长素酸稳定剂作为活性成分。 前体中的非活性成分包括微乳化剂，稳定助乳化剂，分散剂和溶剂，其用量使得当将前体加入到稀释水中以形成浓缩物或即用型制剂时，清澈 并且自发形成的稳定的微乳液具有分散在水中的不大于约1mu的含有油性活性成分的纳米尺寸颗粒。