公开(公告)号：US12012474B2

公开(公告)日：2024-06-18

申请号：US15734328

申请日：2019-06-05

Applicant: RIMTEC Corporation

Inventor： Masaki Takeuchi

IPC: C08F279/00 ,  C08J5/24

CPC classification number: C08F279/00 ,  C08J5/243 ,  C08J5/244 ,  C08J5/247 ,  C08J5/248 ,  C08J2351/00

Abstract: A composite material obtained by impregnating a fibrous filler to which a hydrocarbon-based resin is attached with a polymerizable composition containing a cycloolefin monomer and a metathesis polymerization catalyst is provided. According to the present invention, it is possible to provide a composite material which has no impregnation unevenness and can give a composite material molded article having excellent strength.

公开(公告)号：US20220259355A1

公开(公告)日：2022-08-18

申请号：US17630573

申请日：2020-07-31

Applicant: RIMTEC Corporation

Inventor： Nobuhito Kamei

IPC: C08F236/20 ,  C09J147/00 ,  B32B27/20 ,  B32B15/082 ,  B32B27/30 ,  B32B27/32 ,  B32B15/085 ,  B32B15/20

Abstract: Provided is a polymerizable composition comprising a cycloolefin-based monomer having a specific structure, a silane coupling agent having at least one hydrocarbon group having a norbornene structure, and a metathesis polymerization catalyst.

公开(公告)号：US11066497B2

公开(公告)日：2021-07-20

申请号：US16728549

申请日：2019-12-27

Applicant: RIMTEC CORPORATION

Inventor： Michiru Kamada

IPC: C08F32/08 ,  B29B7/02 ,  C08G61/08 ,  B29C67/24 ,  B29B7/00 ,  B29C45/00 ,  C08J5/00 ,  B29K45/00

Abstract: A method for manufacturing a liquid formulation for reaction injection molding for polymerizing a norbornene-based monomer in the presence of a metathesis polymerization catalyst comprising tungsten as a center metal, the liquid formulation comprising a norbornene-based monomer, provided that in case where the norbornene-based monomer includes exo-dicyclopentadiene, a content of exo-dicyclopentadiene is from 0 to 2% by mass of the norbornene-based monomer, an activator of the catalyst, and a specific ether compound.

公开(公告)号：US10946568B2

公开(公告)日：2021-03-16

申请号：US15381911

申请日：2016-12-16

Applicant: RIMTEC CORPORATION

Inventor： Gilles Recher ,  Sylvain Allain ,  Frederic Demoutiez

IPC: B29C45/14 ,  C09D5/08 ,  C09D163/00 ,  C09J151/06 ,  F16L58/18 ,  C08G61/08 ,  F16L58/10 ,  F16L13/02 ,  B29K63/00 ,  B29L23/00

Abstract: The invention relates to a field joint coating material based on a fast curable olefin liquid formulation and a process of making a field joint wherein this coating material is used.

公开(公告)号：US20170037202A1

公开(公告)日：2017-02-09

申请号：US15106731

申请日：2014-12-17

Applicant: RIMTEC Corporation

Inventor： Masaki TAKEUCHI

IPC: C08J5/04

CPC classification number: C08J5/043 ,  C08F283/14 ,  C08G61/08 ,  C08G2261/418 ,  C08J5/24 ,  C08J2323/18 ,  C08J2323/20 ,  C08J2345/00 ,  C08L65/00

Abstract: The present invention relates to a method for producing a composite molded article having a flexural modulus at 150° C. of 25% or more of a flexural modulus at 23° C., including the steps of (1) placing glass fibers in a mold; (2) impregnating glass fibers with a polymerizable composition containing a cycloolefin monomer, a metathesis polymerization catalyst, a radical generator, and a compound represented by the general formula (I); (3) subjecting the above polymerizable composition with which the glass fibers are impregnated to a bulk polymerization to provide a composite molded article; and (4) demolding the composite molded article; and a composite molded article obtained by the above method. According to the method of the present invention, a composite molded article containing glass fibers, the composite molded article having excellent mechanical strength can be produced.

Abstract translation: 本发明涉及一种在230℃下弯曲弹性模量在25℃下的挠曲模量为25％以上的复合成形体的制造方法，其特征在于，包括以下工序（1）将玻璃纤维置于模具 ; （2）用含有环烯烃单体，易位聚合催化剂，自由基发生剂和由通式（I）表示的化合物的聚合性组合物浸渍玻璃纤维; （3）对上述聚合性组合物进行浸渍的本体聚合，得到复合成形品; 和（4）使复合成型体脱模; 和通过上述方法获得的复合成型体。 根据本发明的方法，可以制造含有玻璃纤维的复合成型体，该复合成形体具有优异的机械强度。

公开(公告)号：US20160244540A1

公开(公告)日：2016-08-25

申请号：US15025113

申请日：2014-09-19

Applicant: RIMTEC CORPORATION

Inventor： Nobuto Kamei

IPC: C08F132/08

CPC classification number: C08F132/08 ,  C08G61/08 ,  C08G2261/135 ,  C08G2261/3324 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/592 ,  C08G2261/65 ,  C08G2261/76 ,  H01L23/293

Abstract: The present invention relates to a norbornene-based crosslinked polymer containing at least one member selected from the group consisting of dicyclopentadiene-based monomer units, tetracyclododecene-based monomer units, and tricyclopentadiene-based monomer units in an amount of 50% by mass or more, wherein the norbornene-based crosslinked polymer has a glass transition temperature of 240° C. or higher. Further, the present invention relates to a method for producing a norbornene-based crosslinked polymer as defined above, including step (1): heating a blend containing at least one member of the above monomer components, and a metathesis polymerization catalyst to a temperature lower than a deactivation temperature of the metathesis polymerization catalyst to carry out a primary curing; and step (2): heating a cured product obtained in the step (1) to a temperature equal to or higher than the deactivation temperature of the above metathesis polymerization catalyst to carry out a secondary curing.

Abstract translation: 本发明涉及含有50质量％以上的选自二环戊二烯类单体单元，四环十二碳烯类单体单元和三环戊二烯系单体单元中的至少一种的降冰片烯系交联聚合物 其中，所述降冰片烯系交联聚合物的玻璃化转变温度为240℃以上。 此外，本发明涉及如上所述的降冰片烯系交联聚合物的制造方法，其包括步骤（1）：将含有至少一种上述单体成分的共混物和易位聚合催化剂加热至低于 比易位聚合催化剂的去活化温度进行初级固化; 和步骤（2）：将步骤（1）中获得的固化产物加热至等于或高于上述易位聚合催化剂的失活温度的温度，进行二次固化。

公开(公告)号：US20150080581A1

公开(公告)日：2015-03-19

申请号：US14553122

申请日：2014-11-25

Applicant: RIMTEC Corporation

Inventor： David SCHAUBROECK ,  Stijn MONSAERT ,  Nele LEDOUX ,  Francis Walter Cornelius VERPOORT ,  Renata A. DROZDZAK

IPC: B01J31/22 ,  C07F15/00

CPC classification number: B01J31/2295 ,  B01J31/2273 ,  B01J31/2278 ,  B01J2231/12 ,  B01J2231/54 ,  B01J2531/821 ,  C07F15/0046 ,  C07F17/02 ,  C08G61/06 ,  C08G61/08

Abstract: Improved catalysts useful in alkyne or olefin metathesis are made by bringing into contact a multi-coordinated metal complex comprising a multidentate Schiff base ligand, and one or more other ligands, with a selected activating compound under conditions such that at least partial cleavage of a bond between the metal and the multidentate Schiff base ligand of said metal complex occurs.

Abstract translation: 用于炔烃或烯烃复分解的改进的催化剂是通过使包含多齿席夫碱配体的多配位金属络合物和一种或多种其它配体与选择的活化化合物接触的条件制备的，使得至少部分切割键 在所述金属络合物的金属和多齿席氏碱配位体之间发生。

公开(公告)号：US20230192942A1

公开(公告)日：2023-06-22

申请号：US17918367

申请日：2021-04-23

Applicant: RIMTEC Corporation

Inventor： Naoki Fukumoto ,  Nobuhito Kamei

IPC: C08G61/08 ,  B01F27/94 ,  B01F35/90

CPC classification number: C08G61/08 ,  B01F27/941 ,  B01F35/90 ,  C08G2261/11 ,  C08G2261/3321 ,  B01F2101/2204

Abstract: A mixing head 3 which mixes a first preparative liquid formulation containing a norbornene-based monomer with a second preparative liquid formulation containing a metathesis polymerization catalyst includes a casing 4, a cap 7, and a mixing rotor 6. A plurality of protrusions 622 includes first protrusions 622a having a width in the axial direction of the mixing rotor 6 larger than that in the circumferential direction, and second protrusions 622b having a width in the axial direction of the mixing rotor 6 smaller than that in the circumferential direction. First and second protrusion rows 623a and 623b are alternately arranged, the first protrusion rows 623a being formed of the first protrusions 622a aligned at a predetermined interval, the second protrusion rows 623b being formed of the second protrusions 622b aligned at a predetermined interval.

公开(公告)号：US20200058425A1

公开(公告)日：2020-02-20

申请号：US16609375

申请日：2018-05-10

Applicant: RAILWAY TECHNICAL RESEARCH INSTITUTE ,  RIMTEC CORPORATION

Inventor： Katsutoshi Mizuno ,  Minoru Tanaka ,  Masaki Takeuchi

IPC: H01F6/06 ,  H01F6/04 ,  C08G61/08

Abstract: A superconducting coil device (10) includes: a coil case (20) housing a superconducting coil (30); a superconducting coil (30) housed in the coil case (20); and a resin part (50) formed of a polymer (51) filled in a gap between an inner wall of the coil case (20) and the superconducting coil (30). The resin part (50) is formed of a polymer (51) obtained by polymerizing a polymerizable composition containing a first monomer having a norbornene ring structure.

公开(公告)号：US20190256648A1

公开(公告)日：2019-08-22

申请号：US16405159

申请日：2019-05-07

Applicant: RIMTEC CORPORATION

Inventor： Michiru Kamada

IPC: C08G61/08 ,  C08K5/06 ,  B29C45/18 ,  B29C45/76

Abstract: The present invention provides: a reaction injection molding liquid mixture comprising a norbornene-based monomer, a metathesis polymerization catalyst that includes tungsten as a center metal, an activator, and an ether compound represented by a formula (1), wherein R1 to R4 are independently an alkyl group having 1 to 6 carbon atoms, the reaction injection molding liquid mixture comprising the activator and the ether compound in a molar ratio (ether compound/activator) of 0.7/1 to 30/1; a method for producing a reaction injection molded product comprising a reaction injection molding step that includes subjecting the reaction injection molding liquid mixture according to any one of claims 1 to 4 to bulk polymerization inside a mold; a reaction injection molded product obtained using the method for producing a reaction injection molded product. Consequently, the present invention provides: a reaction injection molding liquid mixture that makes it possible to obtain a reaction injection molded product that has an excellent surface (surface state) and exhibits excellent strength while preventing a situation in which the resin remains on the surface of the mold when the resin is removed from the mold, a method for producing a reaction injection molded product using the same, and a reaction injection molded product obtained using the method.