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    Process for the carbonylation of methanol or a reactive derivative thereof
    2.
    发明授权
    Process for the carbonylation of methanol or a reactive derivative thereof 失效
    甲醇或其活性衍生物的羰基化方法

    公开(公告)号：US5488153A

    公开(公告)日：1996-01-30

    申请号：US262955

    申请日：1994-06-21

    申请人： Michael J. Baker ,  Jonathan R. Dilworth ,  John G. Sunley ,  Nigel Wheatley

    发明人： Michael J. Baker ,  Jonathan R. Dilworth ,  John G. Sunley ,  Nigel Wheatley

    IPC分类号： B01J31/22 ,  B01J23/46 ,  B01J31/18 ,  C07B61/00 ,  C07C51/12 ,  C07C53/08 ,  C07C67/36 ,  C07C69/14 ,  C07F9/50 ,  C07F9/53 ,  B01J31/00 ,  C07F15/00

    CPC分类号： C07F9/5308 ,  C07C51/12 ,  C07C67/36 ,  C07F9/5004 ,  C07F9/5022

    摘要： A process or the liquid phase carbonylation of methanol or a reactive derivative thereof comprises contacting carbon monoxide with a liquid reaction composition comprising methanol or a reactive derivative thereof, a halogen promoter and a rhodium catalyst system comprising a rhodium component and a bidentate phosphorus-sulphur ligand, the ligand comprising a phosphorus dative center linked to a sulphur dative or anionic center by a substantially unreactive backbone structure comprising two connecting carbon atoms or a connecting carbon and a connecting phosphorus atom. Novel rhodium ligand complexes of formula [Rh(CO)L].sub.m and Rh(CO)LY] wherein Y is a halogen, m is a number less than 10 and L is ##STR1## wherein the R groups are independently selected from C.sub.1 to C.sub.20 alkyl, cycloalkyl, aryl, substituted aryl and optionally substituted aralkyl; the R.sup.5 groups are selected from hydrogen, C.sub.1 to C.sub.20 alkyl, cycloalkyl, aryl, substituted aryl, aryl and optionally substituted aralkyl groups; the R.sup.1 to R.sup.4 groups are independently selected from hydrogen, C.sub.1 to C.sub.20 alkyl and optionally substituted aralkyl; X is a non-coordinating substitutent such as C.sub.1 to C.sub.20 alkyl, cycloalkyl, aryl, substituted aryl, C.sub.1 to C.sub.20 alkoxy, C.sub.1 to C.sub.20 alkylthio, trialkylsilyl or triarylsilyl, preferably, Si(CH.sub.3).sub.3 or methyl and n is 0 to 4 preferably 0 or 1.

    摘要翻译： 甲醇或其活性衍生物的液相羰基化方法包括使一氧化碳与包含甲醇或其活性衍生物的液体反应组合物，卤素促进剂和包含铑组分和二齿磷硫配体的铑催化剂体系接触， 所述配体包含通过包含两个连接碳原子或连接碳和连接的磷原子的基本上不反应的主链结构连接到硫对位或阴离子中心的磷中心。 式[Rh（CO）L] m和Rh（CO）LY]的新型铑配体络合物，其中Y是卤素，m是小于10的数，L是独立地选择的R基团 C 1 -C 20烷基，环烷基，芳基，取代的芳基和任选取代的芳烷基; R5基团选自氢，C1至C20烷基，环烷基，芳基，取代的芳基，芳基和任选取代的芳烷基; R 1至R 4基团独立地选自氢，C 1至C 20烷基和任选取代的芳烷基; X是非配位取代基，例如C1至C20烷基，环烷基，芳基，取代的芳基，C1至C20烷氧基，C1至C20烷硫基，三烷基甲硅烷基或三芳基甲硅烷基，优选Si（CH3）3或甲基，n为0-4 优选0或1。

    Novel catalysts useful for catalyzing the coupling of arylhalides with arylboronic acids
    4.
    发明申请
    Novel catalysts useful for catalyzing the coupling of arylhalides with arylboronic acids 失效
    用于催化芳基卤化物与芳基硼酸的偶联的新型催化剂

    公开(公告)号：US20060281923A1

    公开(公告)日：2006-12-14

    申请号：US11013679

    申请日：2004-12-16

    申请人： Alex Ionkin

    发明人： Alex Ionkin

    IPC分类号： C07F7/10

    CPC分类号： C07F9/5308 ,  C07F7/083

    摘要： The present invention relates to a new method of cross-coupling aryl moieties comprising reacting an arylhalide with an arylboronic acid in the presence of a palladium compound and a compound comprising a di-alkylphosphine moiety.

    摘要翻译： 本发明涉及一种交叉偶联芳基部分的新方法，包括在钯化合物和包含二烷基膦部分的化合物的存在下使芳基卤与芳基硼酸反应。

    Catalysts useful for catalyzing the coupling of arylhalides with arylboronic acids
    6.
    发明授权
    Catalysts useful for catalyzing the coupling of arylhalides with arylboronic acids 失效
    用于催化芳基卤与芳基硼酸的偶合的催化剂

    公开(公告)号：US08153794B2

    公开(公告)日：2012-04-10

    申请号：US12244935

    申请日：2008-10-03

    申请人： Alex Sergey Ionkin

    发明人： Alex Sergey Ionkin

    IPC分类号： C07F7/02 ,  C07D213/04

    CPC分类号： C07F9/5308 ,  C07F7/083

    摘要： The present invention relates to a new method of cross-coupling aryl moieties comprising reacting an arylhalide with an arylboronic acid in the presence of a palladium compound and a compound comprising a di-alkylphosphine moiety.

    摘要翻译： 本发明涉及一种交叉偶联芳基部分的新方法，包括在钯化合物和包含二烷基膦部分的化合物的存在下使芳基卤与芳基硼酸反应。

    Catalysts useful for catalyzing the coupling of arylhalides with arylboronic acids
    8.
    发明授权
    Catalysts useful for catalyzing the coupling of arylhalides with arylboronic acids 失效
    用于催化芳基卤与芳基硼酸的偶合的催化剂

    公开(公告)号：US07449601B2

    公开(公告)日：2008-11-11

    申请号：US11013679

    申请日：2004-12-16

    申请人： Alex Sergey Ionkin

    发明人： Alex Sergey Ionkin

    IPC分类号： C07C211/46 ,  C07F7/10

    CPC分类号： C07F9/5308 ,  C07F7/083

    摘要： The present invention relates to a new method of cross-coupling aryl moieties comprising reacting an arylhalide with an arylboronic acid in the presence of a palladium compound and a compound comprising a di-alkylphosphine moiety.

    摘要翻译： 本发明涉及一种交叉偶联芳基部分的新方法，包括在钯化合物和包含二烷基膦部分的化合物的存在下使芳基卤与芳基硼酸反应。