摘要:
Embodiments of the disclosure generally provide compositions and methods related to oligomeric and polymeric urethane materials that contain hydrolyzable polythioaminal groups for use in biomedical applications.
摘要:
The invention provides a method for producing an oil-resistant elastomer being cross-linked millable polyurethane obtained by polyaddition of at least one polyester diol and at least one diisocyanate, comprising the steps of:selecting the kinds and blend proportion of the at least one polyester diol and the at least one diisocyanate, respectively, so that the resulting polyurethane has an ester group concentration of at least 25 wt. % (5.7 mmol/g) and less than 35 wt. % (8 mmol/g) and a urethane group concentration of at least 7 wt. % (1.2 mmol/g) and less than 12 wt. % (2.0 mmol/g), reacting the at least one polyester diol and at least one diisocyanate to produce a millable polyurethane, and crosslinking the millable polyurethane with a curing agent to form an oil-resistant elastomer which has a rubber hardness of JIS A 95° or less and an elongation at break of at least 100%, wherein the elastomer exhibits a percent change in weight, when exposed to IRM 903 lubricating oil, of 20% or less.
摘要:
Improved elastomers are made by cross-linking a polyurethane through double bonds derived from a diisocyanato bicyclo octene used together with a linear prepolymer to make the polyurethane.
摘要:
1. A PROCESS FOR THE PRODUCTION OF FACTICE-LIKE PRODUCTS WHICH COMPRISES BLENDING A LIQUID UNSATURATED POLYESTER WITH, BASED ON THE WEIGHT OF THE MIXTURE, FROM 5 TO 15 PERCENT BY WEIGHT SULFUR AND REACTING THE MIXTURE BY MIXING AT A TEMPERATURE WITHIN THE RANGE OF ABOUT 275* TO 375* F. FOR A PERIOD OF TIME SUFFICIENT TO FORM A SEMICURED, RUBBERY, CRUMBLY MASS, SAID LIQUID POLYESTER HAVING AN AVERAGE MOLECULAR WEIGHT OF BETWEEN ABOUT 2,000 AND 5,500 AND BEING THE CONDENSATION PRODUCT OF, IN RELATIVE PROPORTIONS; (A) 0 TO 50 OOL PERCENT OF A MEMBER SELECTED FROM THE GROUP CONSISTING OF PHTHALIC ANHYDRIDE, O-PHTHALIC ACID AND ESTERS, OF O-PHTHALIC ACID; (B) 0 TO 50 MOL PERCENT OT TERAHYDROPHTHALIC ACID OR ITS ANHYDRIDE; (C) 0 TO 50 MOL PERCENT OF TRIMETHYLOLPROPANE MONOALLYLETHER F GLYCEROL MONOALLYLETHER; (D) 0 TO 50 MOL PERCENT OF A POLYOXYALKYLENE GLYCOL HAVING AN AVERAGE MOLECULAR WEIGHT OF ABOUT 400 TO 4,000; AND (E) 0 TO 50 MOL PERCENT OF AN ALKYLENE GLYCOL OF THE FORMULA HO-R-OH WHEREIN R IS AN ALKYLENE RADICAL OF 2 TO 6 CARBON ATOMS; 50 MOL PERCENT OF SAID REACTANTS BEING SELECTED FROM THE ACID REACTANTS AND 50 MOL PERCENT OF THE REACTANTS BEING SELECTED FROM THE ALCOHOL REACTANTS WITH 5 TO 70 MOL PERCENT OF SAID REACTANTS BEING UNSATURATED AND SELECTED FROM (B) AND (C).
摘要:
The sulfur vulcanization of sulfur-vulcanizable unsaturated polyurethanes can be accelerated by using as an accelerator an organic compound having at least one alkenyl radical attached to a nitrogen atom, the accelerator being attached to the sulfurvulcanizable polyurethane molecule itself and/or being an ingredient of a sulfur-vulcanizable polyurethane mixture or recipe.
摘要:
A method for preparing an amorphous polymer chain in an elastomer which permits use of previously unavailable monomers while permitting control of crystallizability of the amorphous polymer chain. The method of the present invention thus permits an increased range of industrial scale production by broadening the range of raw materials which can be used and by increasing the design options in constructing the chain.
摘要:
Process for producing elastomer materials which are abrasion resistant in the heat, based on polyurethanes and polyoxides, by reacting aliphatic or aromatic diisocyanates, low molecular polydiols or polydiamines and hydroxyl-containing polyesters or polyethers with a molecular weight between 800 and 5000, especially between 2000 and 3000, in equimolar quantities and in liquid phase, characterized by performing the reaction in the presence of rubber powder having diene units incorporated therein, the powder being dispersed in the reaction mass in an amount of 20%-50% by weight, the reaction being carried out in the presence of sulfur or a peroxide, and the rubber powder having a particle size between 5 and 500.mu., the polyurethane reaction mass having a surplus of double bonds capable of cross-linking and casting the elastomer so produced from the liquid mass into molds. Tires made from the elastomers according to the invention are of excellent properties in their tread surfaces.