摘要:
The invention relates to a method for producing products based on non-woody biomass as raw material, characterised in that non-woody biomass which contains cellulose, hemicelluloses and lignin and is in the form of particles is subjected to an extraction treatment with an extractant which comprises one or more organic solvents in an organic aqueous mixture of the solvent or solvents with water, wherein the content of fatty acids in the particles is reduced by the extraction treatment of the particles with the solvent by at least 70%, measured as hexanal content in wt. % after accelerated ageing for 72 hours at 90° C., but the content of cellulose, hemicelluloses and lignin is substantially preserved in this extraction treatment.
摘要:
Chemical cellulose pulp is made from sawdust utilizing a static down-flow retention vessel. By adding steam and cooking liquor to a flow of sawdust a heated slurry, at a cooking temperature of about 250-350null F., is produced. The heated slurry is, at superatmospheric pressure, moved downwardly in the static down-flow retention vessel while cooking temperature is maintained, for a time period of about 0.5-6 (preferably 1 to 3) hours, the slurry having a consistency of about 5-30%. At superatmospheric pressure, without significant reduction in pressure from the retention vessel, the slurry is cooled to well below cooking temperature by diffusing cooling liquid through it, as in a conventional pressure diffuser. The discharge from the retention vessel is preferably substantially solely gravity action (e.g. using a discharge with single convergence and side relief). Various mixing, diluting, thickening, steaming, and pumping devices are utilized in the system from initial steaming of the sawdust to passage into the top of the retention vessel.
摘要:
A two-stage chemical treatment process is disclosed for increasing the density, strength and brightness properties of mechanical wood pulp. The method comprises the steps of: applying an aqueous solution of sodium sulfite in the range of about 1%-10% sodium sulfite based on bone dry weight of wood to wood particles, the solution having a pH in the range of about 4.5-11; heating the sodium sulfite treated wood particles to a temperature in the range of about 100.degree.-160.degree. C. and maintaining the particles in the temperature range for a period of time in the range of about 20 seconds to 10 minutes; refining the heated sodium sulfite treated wood particles into mechanical wood pulp; separating the pulp into a reject fraction and an accept fraction, the reject fraction containing a higher proportion of shives and long fiber material; applying an aqueous solution of sodium sulfite, in the range of about 4%-50% sodium sulfite based on bone dry weight of wood, to the reject fraction, the solution having a pH in the range of about 4.5-11; cooking the sodium sulfite treated reject fraction at a temperature in the range of about 100.degree.-160.degree. C. for a period of time in the range of about 2-120 minutes; refining the cooked sodium sulfite treated reject fraction; and recombining at least part of the refined reject fraction with at least part of the accept fraction.
摘要:
A method and apparatus for the continuous production of cellulosic pulp for use in a papermaking process. The apparatus includes a vessel containing a pulping liquor and the vessel consists of a first impregnation zone and a second attrition zone. Wood chips are continuously fed into the upper end of the first zone and are subject to gentle agitation to impregnate the chips with the liquor. The impregnated chips then flow into the second zone where they are heated to a low temperature of 80.degree. to 120.degree. C. and subjected to more severe agitation to break down the chips and liberate the individual fibers. The liquid level in the first zone is higher than in the second zone, causing the liquid to flow upwardly in the second zone with the cooking liquor and the liberated fibers being continuously discharged from the upper end of the second zone, while larger wood chips are retained in the second zone for further attrition. The liberated fibers are removed from the cooking conditions as they are liberated to thereby prevent overcooking and discoloration of the pulp.
摘要:
A two stage sulfonation system includes a mixing tank, a retention tank, a thickening press, a pressurized vessel, and a liquor recovery press in series relation.The system is designed to receive mechanical pulp, in a slurry form, first introduced into the mixing tank simultaneously with a metered charge of sodium sulfite solution from the holding tank, the sodium sulfite content of which is at a level from about 40 to about 200 g/l. The solution is mixed into the slurry to provide a relatively uniform and intimate contact thereof with its fiber content. This slurry is transferred to the retention tank and there held subject to a sub-boiling temperature between 140 to 210 degrees F., producing a first stage sulfonation of the fiber content. The slurry is then passed to the pressurized vessel, in the course of which it is subjected to a pressing action, extracting liquor which inherently contains a majority of the original sodium sulfite charge directed to the mixing tank. A second stage sulfonation occurs in the pressurized vessel, producing a fiber which after refining is suited for use as reinforcing pulp in newsprint or specialty grade paper, without need for addition of conventional chemical pulp.
摘要翻译:两阶段磺化体系包括混合槽,保留槽,增稠压机,加压容器和串联的液体回收机。 该系统被设计成接收以浆料形式的机械纸浆,首先通过来自储存罐的计量加入的亚硫酸钠溶液引入混合罐,亚硫酸钠含量为约40至约200 g / l。 将溶液混合到浆料中以提供与其纤维含量相对均匀且紧密的接触。 将该浆料转移到保留罐中,并保持在140至210华氏度之间的亚沸点温度,产生纤维含量的第一阶段磺化。 然后将浆料通入加压容器,在该压力容器中进行加压作用,提取固有地含有大部分原始的亚硫酸氢钠进料到混合罐中的液体。 在加压容器中发生第二阶段磺化,产生在精制后适合用作新闻纸或特种级纸中的增强纸浆的纤维,而不需要添加常规化学纸浆。
摘要:
A process for pulping hardwood to produce cellulose pulp in good yield and of high quality, with a low requirement for causticized pulping liquor, which comprises in a first pulping stage pulping the hardwood in an alkaline pulping liquor containing sodium sulfide at a pH of about 10.5 to about 13 and at a temperature within the range from about 110.degree. to about 170.degree. C while generating hydrogen sulfide in situ by reaction of sodium sulfide with organic acids liberated in the pulping; and then in a second pulping stage, following directly after the first pulping stage, continuing the pulping at a pH higher than said first stage pH, within the range of about 12.5 to about 14 and at a temperature higher than said first stage temperature within the range from about 145.degree. to about 190.degree. C, in the presence of added alkaline pulping liquor comprising sodium hydroxide and sodium sulfide until cellulose pulp is produced.