公开(公告)号：US06528441B1

公开(公告)日：2003-03-04

申请号：US08718653

申请日：1996-09-26

Applicant: Leung K Heung ,  George G. Wicks

Inventor： Leung K Heung ,  George G. Wicks

IPC: B01J2006

CPC classification number: B01J20/28026 ,  B01J20/02 ,  B01J20/10 ,  B01J2220/42 ,  C01B3/0078 ,  F17C11/005 ,  H01M4/383 ,  Y02E60/321 ,  Y02E60/324 ,  Y02P20/544 ,  Y10S420/90

Abstract: A hydrogen storage composition based on a metal hydride dispersed in an aerogel prepared by a sol-gel process. The starting material for the aerogel is an organometallic compound, including the alkoxysilanes, organometals of the form M(OR)x and MOxRy, where R is an alkyl group of the form CnH2n+1, M is an oxide-forming metal, n, x, and y are integers, and y is two less than the valence of M. A sol is prepared by combining the starting material, alcohol, water, and an acid. The sol is conditioned to the proper viscosity and a hydride in the form of a fine powder is added. The mixture is polymerized and dried under supercritical conditions. The final product is a composition having a hydride uniformly dispersed throughout an inert, stable and highly porous matrix. It is capable of absorbing up to 30 moles of hydrogen per kilogram at room temperature and pressure, rapidly and reversibly. Hydrogen absorbed by the composition can be readily be recovered by heat or evacuation.

Abstract translation: 一种基于分散在通过溶胶 - 凝胶法制备的气凝胶中的金属氢化物的储氢组合物。 气凝胶的原料是有机金属化合物，包括烷氧基硅烷，M（OR）x和MOxRy形式的有机金属，其中R是CnH2n + 1形式的烷基，M是氧化物形成金属，n， x和y为整数，y为M的价数2。通过组合原料，醇，水和酸制备溶胶。 将溶胶调节至适当的粘度，并加入细粉末形式的氢化物。 将混合物在超临界条件下聚合并干燥。 最终产物是具有均匀分散在整个惰性，稳定和高度多孔的基质中的氢化物的组合物。 它能够在室温和压力下快速可逆地吸收高达30摩尔氢/千克。 由组合物吸收的氢可以通过加热或排空而容易地回收。

公开(公告)号：US06589494B1

公开(公告)日：2003-07-08

申请号：US09676786

申请日：2000-10-02

Applicant: Christophe Nedez

Inventor： Christophe Nedez

IPC: B01J2006

CPC classification number: B01D15/00 ,  B01D53/68 ,  B01J20/06 ,  Y10S210/915

Abstract: The present invention provides a process for eliminating halogen-containing compounds contained in a gas or a liquid, characterized in that the gas or liquid is brought into contact with a composition based on an alumina and/or a hydrated alumina and at least one compound (A) comprising at least one metallic element selected from metals from groups VIII, IB and/or IIB of the periodic table, and in that the total metallic element(s) content is at most 45% by weight with respect to the total composition weight, the complement by weight preferably comprising in a major part alumina and/or hydrated alumina.

Abstract translation: 本发明提供了一种消除气体或液体中含有的含卤化合物的方法，其特征在于，使气体或液体与基于氧化铝和/或水合氧化铝的组合物和至少一种化合物（ A）包括选自元素周期表第VIII，IB和/或IIB族金属的至少一种金属元素，并且总金属元素含量相对于总组合物重量为至多45重量％ ，重量份的补充优选主要包括氧化铝和/或水合氧化铝。