公开(公告)号：US20040254406A1

公开(公告)日：2004-12-16

申请号：US10489362

申请日：2004-03-12

发明人： Noritaka Nagasaki ,  Tsuyoshi Kawamura ,  Kazunori Nukui ,  Shoji Arai

IPC分类号： C07C029/124

CPC分类号： C07C29/124 ,  C07C31/38

摘要： The invention provides a process for the preparation of 2,2,2-trifluoroethanol by reacting a null-hydroxybutyric acid salt with 1,1,1-trifluoro-2-chloroethane which brings about an increase in the yield of 2,2,2-trifluoroethanol and enables easy separation of by-product salts and recovery and recycling of an aprotic polar solvent. The invention relates to a process for the preparation of 2,2,2-trifluoroethanol by reacting a null-hydroxybutyric acid salt with 1,1,1-trifluoro-2-chloroethane in an aprotic polar solvent, characterized by using a null-hydroxybutyric acid salt having a 4,4null-oxydibutyric acid content of 6 wt % or below.

摘要翻译： 本发明提供了一种通过使γ-羟基丁酸盐与1,1,1-三氟-2-氯乙烷反应来制备2,2,2-三氟乙醇的方法，导致产率增加了2,2,2 可以容易地分离副产物盐，并回收和再循环非质子极性溶剂。 本发明涉及通过在非质子极性溶剂中使γ-羟基丁酸盐与1,1,1-三氟-2-氯乙烷反应来制备2,2,2-三氟乙醇的方法，其特征在于使用γ-羟基丁酸 具有6重量％以下的4,4'-氧杂二丁酸含量的酸式盐。

公开(公告)号：US20020198416A1

公开(公告)日：2002-12-26

申请号：US10054004

申请日：2002-01-24

发明人： Xiao Ping Zhou ,  Ivan Marc Lorkovic ,  Jeffrey H. Sherman

IPC分类号： C07C029/124

CPC分类号： C07D301/26 ,  C07C17/10 ,  C07C29/124 ,  C07C41/01 ,  C07C45/27 ,  Y02P20/125 ,  C07C19/075 ,  C07C47/06 ,  C07C31/04 ,  C07C43/06 ,  C07C43/043

摘要： Alcohols, ethers, and olefins are manufactured from alkanes by mixing an alkane and bromine in a reactor to form alkyl bromide and hydrogen bromide. The alkyl bromide only or the alkyl bromide and the hydrogen bromide are directed into contact with metal oxide to form an alcohol and/or an ether, or an olefin and metal bromide. The metal bromide is oxidized to form original metal oxide and bromine, both of which are recycled.

摘要翻译： 通过在反应器中混合烷烃和溴以形成烷基溴和溴化氢，由烷烃制备醇，醚和烯烃。 仅将烷基溴或烷基溴和溴化氢引导与金属氧化物接触以形成醇和/或醚，或烯烃和金属溴化物。 金属溴化物被氧化以形成原始的金属氧化物和溴，这两者都被再循环。

公开(公告)号：US20030100804A1

公开(公告)日：2003-05-29

申请号：US10242688

申请日：2002-09-13

发明人： Toshiyuki Katsube ,  Yuuki Matsuda ,  Jun Miki

IPC分类号： C07C029/124 ,  B01J029/04 ,  B01J029/87

CPC分类号： B01J29/85 ,  B01J29/064 ,  B01J29/072 ,  B01J29/83 ,  C07C29/124 ,  C07C31/38

摘要： A process for preparing a fluorine-containing alcohol compound, the process comprising the step of reacting water with a halogenated fluorine compound in the presence of a catalyst for preparing a fluorine-containing alcohol compound, the catalyst obtained by supporting an ammine complex containing at least one component selected from the group consisting of the elements in Group 1B, Group 2B, Group 6A, Group 7A and Group 8 of the periodic table on at least one complex oxide selected from the group consisting of SinullAl complex oxides, AlnullP complex oxides and SinullAlnullP complex oxides.

摘要翻译： 一种制备含氟醇化合物的方法，该方法包括在用于制备含氟醇化合物的催化剂存在下使水与卤代氟化合物反应的步骤，所述催化剂通过将至少含有至少 选自元素周期表第1B族，第2B族，第6A族，第7A族和第8族元素中的至少一种选自Si-Al复合氧化物，Al-P 复合氧化物和Si-Al-P复合氧化物。

公开(公告)号：US20020156328A1

公开(公告)日：2002-10-24

申请号：US10114579

申请日：2002-04-02

发明人： Philip Grosso

IPC分类号： C07C027/10 ,  C07C029/124

CPC分类号： C07C29/124 ,  C07C41/16 ,  C07C31/04 ,  C07C43/043

摘要： In a method of converting alkanes to their corresponding alcohols and ethers a vessel comprises a hollow, unsegregated interior defined first, second, and third zones. In a first embodiment of the invention oxygen reacts with metal bromide in the first zone to provide bromine; bromine reacts with the alkane in the second zone to form alkyl bromide; and the alkyl bromide reacts with metal oxide in the third zone to form the corresponding alcohol and/or ether. Metal bromide from the third zone is transported through the vessel to the first zone and metal oxide from the first zone is recycled to the third zone. A second embodiment of the invention differs from the first embodiment in that metal oxide is transported through the vessel from the first zone to the third zone and metal bromide is recycled from the third zone to the first zone. In a third embodiment of the invention the flow of gases through the vessel is reversed to convert the metal oxide back to metal bromide and to convert the metal bromide back to the metal oxide.

摘要翻译： 在将烷烃转化成其相应的醇和醚的方法中，容器包括中空的未分离的内部限定的第一，第二和第三区域。 在本发明的第一个实施方案中，氧与第一区中的金属溴化物反应以提供溴; 溴与第二区中的烷烃反应形成烷基溴; 并且烷基溴与第三区中的金属氧化物反应形成相应的醇和/或醚。 来自第三区域的金属溴化物通过容器运输到第一区域，并且来自第一区域的金属氧化物被再循环到第三区域。 本发明的第二实施例与第一实施例的不同之处在于金属氧化物通过容器从第一区域传送到第三区域，金属溴化物从第三区域再循环到第一区域。 在本发明的第三个实施方案中，反过来通过容器的气体流将金属氧化物转换回金属溴化物并将金属溴化物转化回金属氧化物。