Carbonyl iron silicide powder
    1.
    发明授权
    Carbonyl iron silicide powder 失效
    羰基铁硅化物粉末

    公开(公告)号:US06309620B1

    公开(公告)日:2001-10-30

    申请号:US09358475

    申请日:1999-07-21

    IPC分类号: C22C2912

    摘要: A process for preparing carbonyl iron silicide comprises heat treatment of an iron/silicon mixture comprising a) from 20 to 99.9% by weight of finely divided carbonyl iron and b) from 0.1 to 80% by weight of finely divided silicon powder. Also provided are a carbonyl iron silicide obtainable by alloying carbonyl iron with silicon and a carbonyl iron suicide which has a higher inductance than carbonyl iron powder.

    摘要翻译: 制备羰基铁硅化物的方法包括热处理铁/硅混合物,其包含a)20至99.9重量%的细碎羰基铁和b)0.1至80重量%的细碎硅粉末。 还提供了通过使羰基铁与硅合金化的羰基铁硅化物和具有比羰基铁粉更高的电感的羰基铁硅化物。

    Cermet inert anode materials and method of making same
    2.
    发明授权
    Cermet inert anode materials and method of making same 失效
    金属陶瓷惰性阳极材料及其制备方法

    公开(公告)号:US06821312B2

    公开(公告)日:2004-11-23

    申请号:US10115112

    申请日:2002-04-01

    IPC分类号: C22C2912

    摘要: A method of making cermet inert anodes for the electrolytic production of metals such as aluminum is disclosed. The method includes the step of spray drying a slurry comprising ceramic phase particles and metal phase particles. The resultant spray dried powder, which comprises agglomerates of both the ceramic phase and metal phase particles, may then be consolidated by techniques such as pressing and sintering to produce a cermet inert anode material. The ceramic phase may comprise oxides of Ni, Fe and at least one additional metal selected from Zn, Co, Al, Li, Cu, Ti, V, Cr, Zr, Nb, Ta, W, Mo, Hf and rare earths. The metal phase may comprise Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The consolidated cermet inert anode material exhibits improved properties such as reduced porosity. The cermet inert anodes may be used in electrolytic reduction cells for the production of commercial purity aluminum as well as other metals.

    摘要翻译: 公开了一种制造用于电解生产金属如铝的金属陶瓷惰性阳极的方法。 该方法包括喷雾干燥包含陶瓷相颗粒和金属相颗粒的浆料的步骤。 然后可以通过诸如压制和烧结的技术来固化包含陶瓷相和金属相颗粒的附聚物的所得喷雾干燥粉末以产生金属陶瓷惰性阳极材料。 陶瓷相可以包括Ni,Fe和选自Zn,Co,Al,Li,Cu,Ti,V,Cr,Zr,Nb,Ta,W,Mo,Hf和稀土中的至少一种另外的金属的氧化物。 金属相可以包括Cu,Ag,Pd,Pt,Au,Rh,Ru,Ir和/或Os。 固结的金属陶瓷惰性阳极材料表现出改善的性能,例如孔隙率降低。 金属陶瓷惰性阳极可以用于生产商业纯度的铝以及其它金属的电解还原电池中。

    Nickel cermet anodic material for fuel cell anode
    4.
    发明授权
    Nickel cermet anodic material for fuel cell anode 失效
    用于燃料电池阳极的镍金属陶瓷阳极材料

    公开(公告)号:US06379417B2

    公开(公告)日:2002-04-30

    申请号:US09317186

    申请日:1999-05-24

    IPC分类号: C22C2912

    摘要: The present invention provides a nickel cermet, which includes: 35% to 70% by weight of a nickel phase, and 65% to 30% by weight of zirconium oxide phase, wherein the zirconium oxide is stabilized in cubic form by 5 to 20 moles of yttrium oxide for each 100 moles of said zirconium oxide, and the metal nickel and zirconium oxide phases, upon X ray diffraction analysis are distinct and homogeneously distributed; and is prepared by a process that includes: a) dispersing zirconia stabilized by yttria having a particle size of between 1 and 40 &mgr;m , in demineralized water to prepare a suspension; b) dissolving a hydrosoluble and thermodecomposable nickel salt in demineralized d water to prepare a solution; c) mixing the nickel solution with the suspension and homogenizing the resulting dispersion by magnetic stirring for a time of between 5 and 40 minutes; d) eliminating the water from the dispersion by a system capable of operating without, or almost without, decomposition phenomena to obtain a solid that includes particles of zirconia stabilized by yttria covered with nickel salt; e) calcining under oxidating conditions the solid to cause the formation of a solid that includes particles of zirconia stabilized by yttria covered with nickel oxide; and f) treating with hydrogen the solid obtained in step (e) to reduce the nickel oxide to metal nickel and obtain the nickel cermet.

    摘要翻译: 本发明提供一种镍金属陶瓷,其包括:35重量%至70重量%的镍相和65重量%至30重量%的氧化锆相,其中所述氧化锆以立方体形式稳定5至20摩尔 在X射线衍射分析时,每100摩尔所述氧化锆和金属镍和氧化锆相的氧化钇是不同且均匀分布的; 并且通过包括以下步骤制备的方法:a)在软化水中分散具有1至40μm的粒度的氧化钇稳定的氧化锆以制备悬浮液; b)将水溶性和热可分解的镍盐溶解在软化的d水中以制备 溶液; c)将镍溶液与悬浮液混合,并通过磁力搅拌将所得分散体均质化5至40分钟; d)通过能够在没有或几乎不存在的情况下操作的系统从分散体中除去水, 分解现象,以获得包括由镍盐覆盖的氧化钇稳定的氧化锆颗粒的固体; e)在氧化条件下煅烧形成固体的固体,其包括用氧化镍覆盖的氧化钇稳定的氧化锆颗粒; 和)用氢气处理步骤(e)中获得的固体,以将氧化镍还原为金属镍并获得镍金属陶瓷。