公开(公告)号：US06596935B2

公开(公告)日：2003-07-22

申请号：US10141654

申请日：2002-05-08

申请人： Jonathan S. Lindsey ,  Gerald J. Meyer

发明人： Jonathan S. Lindsey ,  Gerald J. Meyer

IPC分类号： H01L310248

CPC分类号： H01L51/0035 ,  B82Y30/00 ,  C09B47/00 ,  C09B69/008 ,  C09B69/108 ,  H01G9/2031 ,  H01G9/2059 ,  H01G9/209 ,  H01L51/0077 ,  H01L51/009 ,  H01L51/4226 ,  Y02E10/542 ,  Y02E10/549 ,  Y02T10/7022

摘要： A solar cell incorporates a light harvesting array that comprises: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to the first electrode, each of the light harvesting rods comprising a polymer of Formula I: X 1 ⁢ — ( X m + 1 ) m ( I ) wherein m is at least 1, and may be from two, three or four to 20 or more; X1 is a charge separation group (and preferably a porphyrinic macrocycle, which may be one ligand of a double-decker sandwich compound) having an excited-state of energy equal to or lower than that of X2; and X2 through Xm+1 are chromophores (and again are preferably porphyrinic macrocycles).

公开(公告)号：US06559374B2

公开(公告)日：2003-05-06

申请号：US09852560

申请日：2001-05-10

申请人： Jonathan S. Lindsey ,  Thiagarajan Balasubramanian

发明人： Jonathan S. Lindsey ,  Thiagarajan Balasubramanian

IPC分类号： H01L310248

CPC分类号： H01L51/009 ,  B82Y10/00 ,  C07D487/22 ,  C09B47/00 ,  C09B69/109 ,  H01G9/2059 ,  H01G9/209 ,  H01L51/0077 ,  H01L51/0595 ,  Y02E10/542

摘要： Trans beta substituted chlorins and methods of making the same are disclosed, along with polymers formed from or containing such trans beta substituted chlorins as one or more monomeric units therein, light harvesting rods formed from such polymers, and electrodes carrying such polymers.

公开(公告)号：US06420648B1

公开(公告)日：2002-07-16

申请号：US09621797

申请日：2000-07-21

申请人： Jonathan S. Lindsey

发明人： Jonathan S. Lindsey

IPC分类号： H01L310248

CPC分类号： H01L51/009 ,  B82Y10/00 ,  C07D487/22 ,  C09B47/00 ,  C09B69/108 ,  H01G9/2059 ,  H01G9/209 ,  H01L51/0077 ,  H01L51/0595 ,  H01L51/447 ,  Y02E10/542 ,  Y02E10/549

摘要： A light harvesting array useful for the manufacture of devices such as solar cells comprises: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to the first electrode, each of the light harvesting rods comprising a polymer of Formula I: X1&Parenopenst;Xm+1)m  (I) wherein m is at least 1, and may be from two, three or four to 20 or more; X1 is a charge separation group (and preferably a porphyrinic macrocycle, which may be one ligand of a double-decker sandwich compound) having an excited-state of energy equal to or lower than that of X2, and X2 through Xm+1 are chromophores (and again are preferably porphyrinic macrocycles).

摘要翻译： 用于制造诸如太阳能电池的装置的光收集阵列包括：（a）包括第一电极的第一基板; 和（b）电耦合到第一电极的光收集杆层，每个光收集杆包含式I的聚合物：其中m至少为1，并且可以是二，三或四至二十或更多 ; X1是能量等于或低于X2的能量激发态的电荷分离组（优选卟啉大环，其可以是双层夹心化合物的一种配体），X2至Xm + 1是发色团 （又优选为卟啉大环）。

公开(公告)号：US06603070B2

公开(公告)日：2003-08-05

申请号：US09939010

申请日：2001-08-24

申请人： Jonathan S. Lindsey ,  Robert S. Loewe

发明人： Jonathan S. Lindsey ,  Robert S. Loewe

IPC分类号： H01L310248

CPC分类号： C09K11/06 ,  B82Y10/00 ,  C07D487/22 ,  C09B47/00 ,  C09B69/109 ,  C09K2211/1029 ,  C09K2211/1074 ,  C09K2211/186 ,  C09K2211/188 ,  H01G9/2059 ,  H01G9/209 ,  H01L51/0034 ,  H01L51/0035 ,  H01L51/0077 ,  H01L51/0078 ,  H01L51/009 ,  H01L51/0093 ,  H01L51/0595 ,  H01L51/4206 ,  Y02E10/542 ,  Y02E10/549 ,  Y02P70/521 ,  Y02T10/7022

摘要： The present invention provides a convergent method for the synthesis of light harvesting rods. The rods are oligomers of the formula A1(Ab+1)b, wherein b is at least 1, A1 through Ab+1 are covalently coupled rod segments, and each rod segment A1 through A1+b comprises a compound of the formula X1(Xm+1)m wherein m is at least 1 and X1 through Xm+1 are covalently coupled porphyrinic macrocycles. Light harvesting arrays and solar cells containing such light harvesting rods are also described, along with intermediates useful in such methods and rods produced by such methods.

摘要翻译： 本发明提供了一种用于合成光收集杆的收敛方法。 棒是式A1（Ab + 1）b的低聚物，其中b至少为1，Al至Ab + 1为共价键，每个棒段A1至A1 + b包含式X1化合物 Xm + 1）m，其中m为至少1，X1至Xm + 1为共价偶联的卟啉大环。 还描述了含有这种光收获杆的光收集阵列和太阳能电池，以及可用于通过这种方法制备的这种方法和棒中的中间体。

公开(公告)号：US06407330B1

公开(公告)日：2002-06-18

申请号：US09621091

申请日：2000-07-21

申请人： Jonathan S. Lindsey ,  Gerald J. Meyer

发明人： Jonathan S. Lindsey ,  Gerald J. Meyer

IPC分类号： H01L310248

CPC分类号： H01L51/0035 ,  B82Y30/00 ,  C09B47/00 ,  C09B69/008 ,  C09B69/108 ,  H01G9/2031 ,  H01G9/2059 ,  H01G9/209 ,  H01L51/0077 ,  H01L51/009 ,  H01L51/4226 ,  Y02E10/542 ,  Y02E10/549 ,  Y02T10/7022

摘要： A solar cell incorporates a light harvesting array that comprises: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to the first electrode, each of the light harvesting rods comprising a polymer of Formula I: X1&Parenopenst;Xm+1)m  (I) wherein m is at least 1, and may be from two, three or four to 20 or more; X1 is a charge separation group (and preferably a porphyrinic macrocycle, which may be one ligand of a double-decker sandwich compound) having an excited-state of energy equal to or lower than that of X2; and X2 through Xm+1 are chromophores (and again are preferably porphyrinic macrocycles).

摘要翻译： 太阳能电池结合光收集阵列，其包括：（a）包括第一电极的第一衬底; 和（b）电耦合到第一电极的光收集杆层，每个光收集杆包含式I的聚合物：其中m至少为1，并且可以是二，三或四至二十或更多 ; X1是能量等于或低于X2的能量激发态的电荷分离组（优选卟啉大环，其可以是双层夹心化合物的一种配体） X2〜Xm + 1为发色团（再次优选为卟啉大环化合物）。