公开(公告)号：WO2004076394B1

公开(公告)日：2004-10-28

申请号：PCT/US2004001118

申请日：2004-01-16

Applicant: DOW GLOBAL TECHNOLOGIES INC ,  DOW DEUTSCHLAND GMBH & CO OHG ,  PATRASCU EMIL ,  FREY JOHANN-WILHELM ,  HAGEL MANFRED

Inventor： PATRASCU EMIL ,  FREY JOHANN-WILHELM ,  HAGEL MANFRED

IPC: C07C37/68 ,  C07C37/82 ,  C07C39/16

CPC classification number: C07C37/70 ,  C07C37/68 ,  C07C37/685 ,  C07C37/74 ,  C07C37/82 ,  C07C37/84 ,  C07C39/16

Abstract: A process for recovering a solid adduct of a bis(4-hydroxyaryl)alkane and a phenolic compound from a suspension comprising the addict is disclosed. The process comprises the steps of a) supplying the suspension to a rotary filter, b) filtering the supplied suspension in the rotary filter to retain adduct as an adduct cake, c) pre-drying the adduct cake with an inert gas, d) washing the pre-dried adduct cake, e) optionally drying the washed adduct cake, and f) discharging the washed adduct cake from the rotary filter.

Abstract translation: 公开了从包含瘾君子的悬浮液中回收双（4-羟基芳基）烷烃和酚类化合物的固体加合物的方法。 该方法包括以下步骤：a）将悬浮液供应到旋转过滤器，b）过滤旋转过滤器中提供的悬浮液以保留作为加合物饼的加合物，c）用惰性气体预干燥加合饼，d）洗涤 预干燥的加合物滤饼，e）任选地干燥洗涤的加合物滤饼，和f）从洗涤的滤纸中排出洗涤的加合物饼。

公开(公告)号：WO2011068644A1

公开(公告)日：2011-06-09

申请号：PCT/US2010/056102

申请日：2010-11-10

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  METRAL, Guillaume ,  FREY, Johann-Wilhelm ,  HOEVEL, Bernd ,  HEFNER, Robert, E., Jr. ,  MULLINS, Michael J

Inventor： METRAL, Guillaume ,  FREY, Johann-Wilhelm ,  HOEVEL, Bernd ,  HEFNER, Robert, E., Jr. ,  MULLINS, Michael J

IPC: C08G59/06 ,  C08G59/22 ,  C08G59/40

CPC classification number: C08G59/182 ,  C08G59/4021

Abstract: An epoxy resin composition prepared from a dihydroxydiphenyl-cycloalkane compound to form a diglycidyl ether of dihydroxydiphenyl cycloalkane compound which may be useful for making various products including, for example, powder coatings, composites and electrical laminates.

Abstract translation: 由二羟基二苯基 - 环烷烃化合物制备的环氧树脂组合物，以形成二羟基二苯基环烷烃化合物的二缩水甘油醚，其可用于制备各种产品，包括例如粉末涂料，复合材料和电层压材料。

公开(公告)号：WO2004048430A3

公开(公告)日：2004-10-07

申请号：PCT/US0335900

申请日：2003-11-12

Applicant: DOW GLOBAL TECHNOLOGIES INC ,  YOUNG THOMAS C ,  FEORD DAMIAN M ,  FREY JOHANN-WILHELM

Inventor： YOUNG THOMAS C ,  FEORD DAMIAN M ,  FREY JOHANN-WILHELM

IPC: C07C37/84 ,  C07C39/16

CPC classification number: C07C37/68 ,  C07C37/00 ,  C07C37/685 ,  C07C37/72 ,  C07C37/74 ,  C07C37/84 ,  C07C39/16

Abstract: Bisphenol-A is purified in a process which comprises the following steps: a) cooling a liquid mixture comprising bisphenol-A and water in a bisphenol-A crystallizer to form bisphenol-A crystals in a liquid phase; b) separating the bisphenol-A crystals from the liquid phase; c) dividing at least a portion of the liquid phase into a bisphenol-rich organic phase and a water-rich phase; d) feeding phenol and at least a portion of the bisphenol-rich organic phase into a adduct crystallizer to form a crystalline adduct of phenol and bisphenol-A in a mother liquor; and e) separating the crystalline adduct from the mother liquor. Bisphenol-A of high purity at a high yield is obtained.

Abstract translation: 双酚A在包括以下步骤的方法中纯化：a）在双酚A结晶器中冷却包含双酚A和水的液体混合物以形成液相中的双酚A晶体; b）从液相中分离出双酚A晶体; c）将至少一部分液相分成富含双酚的有机相和富水相; d）将苯酚和至少一部分富含双酚的有机相进料到加合物结晶器中以在母液中形成苯酚和双酚-A的结晶加合物; 和e）从母液中分离晶体加合物。 获得高纯度的双酚A。

公开(公告)号：WO0224335A3

公开(公告)日：2003-11-06

申请号：PCT/US0128215

申请日：2001-09-06

Applicant: DOW GLOBAL TECHNOLOGIES INC ,  PALIURAS MIHAIL ,  FEORD DAMIAN M ,  FREY JOHANN-WILHELM

Inventor： PALIURAS MIHAIL ,  FEORD DAMIAN M ,  FREY JOHANN-WILHELM

IPC: B01J31/10 ,  B01J39/00 ,  B01J39/04 ,  B01J39/20 ,  C07B61/00 ,  C07C37/00 ,  C07C37/20 ,  C07C39/16 ,  C07C327/30 ,  C08C19/00 ,  C08F8/44 ,  C08J5/20 ,  B01J47/00

CPC classification number: C08F8/44 ,  B01J31/10 ,  B01J39/20 ,  B01J2231/342 ,  B01J2231/347 ,  B01J2231/52 ,  C07C37/00 ,  C07C37/20 ,  C07C39/16

Abstract: A strong-acid cation exchange resin in acid form is contacted with an alkylcarbamoyl alkylthioester in the presence of water for producing a strong-acid cation exchange resin comprising a plurality of acid groups being partially neutralized with a mercaptoalkylamine. The produced partially neutralized cation exchange resin is useful as a catalyst in a process of producing a bisphenol by reaction of a phenolic compound with a carbonyl compound.

Abstract translation: 酸性强酸阳离子交换树脂在水存在下与烷基氨基甲酰基烷基硫酯接触，以产生包含多个酸基团的部分中和的巯基烷基胺的强酸性阳离子交换树脂。 所制备的部分中和的阳离子交换树脂可用作通过酚类化合物与羰基化合物反应生产双酚的方法中的催化剂。

公开(公告)号：WO2004048430A2

公开(公告)日：2004-06-10

申请号：PCT/US2003/035900

申请日：2003-11-12

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  YOUNG, Thomas, C. ,  FEORD, Damian, M. ,  FREY, Johann-Wilhelm

Inventor： YOUNG, Thomas, C. ,  FEORD, Damian, M. ,  FREY, Johann-Wilhelm

IPC: C08G

CPC classification number: C07C37/68 ,  C07C37/00 ,  C07C37/685 ,  C07C37/72 ,  C07C37/74 ,  C07C37/84 ,  C07C39/16

Abstract: Bisphenol-A is purified in a process which comprises the following steps: a) cooling a liquid mixture comprising bisphenol-A and water in a bisphenol-A crystallizer to form bisphenol-A crystals in a liquid phase; b) separating the bisphenol-A crystals from the liquid phase; c) dividing at least a portion of the liquid phase into a bisphenol-rich organic phase and a water-rich phase; d) feeding phenol and at least a portion of the bisphenol-rich organic phase into a adduct crystallizer to form a crystalline adduct of phenol and bisphenol-A in a mother liquor; and e) separating the crystalline adduct from the mother liquor. Bisphenol-A of high purity at a high yield is obtained.

Abstract translation: 在包括以下步骤的方法中纯化双酚-A：a）在双酚-A结晶器中冷却包含双酚-A和水的液体混合物以在液相中形成双酚-A晶体 ; b）从液相中分离双酚A晶体; c）将至少一部分液相分成富含双酚的有机相和富水相; d）将苯酚和至少一部分富含双酚的有机相加入加合物结晶器中以在母液中形成苯酚和双酚-A的结晶加合物; 和e）从母液中分离结晶加合物。 高纯度的双酚-A以高收率获得。

公开(公告)号：WO2004076394A1

公开(公告)日：2004-09-10

申请号：PCT/US2004/001118

申请日：2004-01-16

Applicant: DOW GLOBAL TECHNOLOGIES, INC. ,  DOW DEUTSCHLAND GMBH & CO. OHG ,  PATRASCU, Emil ,  FREY, Johann-Wilhelm ,  HAGEL, Manfred

Inventor： PATRASCU, Emil ,  FREY, Johann-Wilhelm ,  HAGEL, Manfred

IPC: C07C37/82

CPC classification number: C07C37/70 ,  C07C37/68 ,  C07C37/685 ,  C07C37/74 ,  C07C37/82 ,  C07C37/84 ,  C07C39/16

Abstract: A process for recovering a solid adduct of a bis(4-hydroxyaryl)alkane and a phenolic compound from a suspension comprising the addict is disclosed. The process comprises the steps of a) supplying the suspension to a rotary filter, b) filtering the supplied suspension in the rotary filter to retain adduct as an adduct cake, c) pre-drying the adduct cake with an inert gas, d) washing the pre-dried adduct cake, e) optionally drying the washed adduct cake, and f) discharging the washed adduct cake from the rotary filter.

Abstract translation: 公开了一种从包含该吸附剂的悬浮液中回收二（4-羟基芳基）烷烃和酚类化合物的固体加合物的方法。 该方法包括以下步骤：a）将悬浮液供应到旋转过滤器，b）过滤旋转过滤器中供应的悬浮液以保留加合物作为加合物饼，c）用惰性气体预干燥加合物饼，d）洗涤 预干燥的加合物滤饼，e）任选干燥洗涤过的加合物滤饼，和f）从旋转过滤器中排出洗涤过的加合物滤饼。