WEATHER-RESISTANT PEARLESCENT PIGMENTS BASED ON SMALL THIN GLASS PLATES, AND METHOD FOR THE PRODUCTION THEREOF
    5.
    发明申请
    WEATHER-RESISTANT PEARLESCENT PIGMENTS BASED ON SMALL THIN GLASS PLATES, AND METHOD FOR THE PRODUCTION THEREOF 审中-公开
    天气稳定的珠光颜料基于薄玻璃板及其方法

    公开(公告)号:WO2007098897A3

    公开(公告)日:2007-10-25

    申请号:PCT/EP2007001603

    申请日:2007-02-23

    Abstract: The invention relates to weather-resistant pearlescent pigments which have improved application properties and are based on a small glass plate that is coated with highly refractive metal oxides and a protective coating located on the top metal oxide layer. The inventive pigments are characterized in that the small glass plate has an average thickness of 50 to 500 nm. According to variant A, a metal oxide layer whose refractive index n exceeds 1.8 and which comprises TiO 2 having a rutile concentration ranging from 80 to 100 percent by weight as well as a protective SiO 2 coating are applied. According to variant B, a metal oxide layer whose refractive index n exceeds 1.8 and which comprises TiO 2 having a rutile concentration ranging from 80 to 100 percent by weight as well as a protective coating containing a first protective layer with cerium oxide and/or cerium oxide hydrate and/or cerium hydroxide and a second protective SiO 2 layer are applied. Additionally, an organic chemical surface coating is applied to the metal oxide layer of the protective coating of A or B. The invention further relates to a method for producing said pigments and the use thereof.

    Abstract translation: 本发明涉及天气与涂覆的基础上与高折射金属氧化物,玻璃板与位于最上层的金属氧化物层上的保护覆盖层上改进应用性能耐珠光颜料。 本发明的颜料的特征在于,所述玻璃血小板具有50至500nm的平均厚度,向其中按照一个变体A,其具有折射率n大于1.8,%的金属氧化物,通过该TiO2的具有80至100的金红石含量 - 。% 包括和SiO 2的保护层,或根据变体B,A,具有折射率n大于1.8,其重量的TiO 2 为80至100的金红石含量的金属氧化物 - 包括%和包含保护涂层。 用氧化铈和/或铈氧化物水合物和/或氢氧化铈和SiO 2 的第二保护层上的一个或B中的保护性外涂层的金属氧化物层的第一保护层是有机化学表面涂层施加。 本发明还涉及用于这些颜料和它们的使用的制备方法。

    PEARLESCENT PIGMENTS HAVING A SECONDARY COATING COMPRISING a-SILANES AND METHOD FOR THE PRODUCITON THEREOF
    6.
    发明申请
    PEARLESCENT PIGMENTS HAVING A SECONDARY COATING COMPRISING a-SILANES AND METHOD FOR THE PRODUCITON THEREOF 审中-公开
    有Aftercoating包含硅烷和方法产区天气稳定珠光颜料

    公开(公告)号:WO2007098887A3

    公开(公告)日:2007-10-18

    申请号:PCT/EP2007001573

    申请日:2007-02-23

    Abstract: The invention relates to a pearlescent pigment comprising a metal-oxide containing, lamellar substrate comprising a first and a second protective layer, the metal oxide layer having a refractive index of more than 1,8. The first protective layer comprises cerium oxide and/or cerium hydrate and/or cerium hydroxide, the secodn protective layer is made, essentailly, preferably completely of SiO 2 . The second protective layer is arranged downstream from the first protective layer and between the first and the second protective layers, metal oxide layers, which are different from cerium oxide and/or cerium hydrate and/or cerium hydroxide and SiO 2 can be arranged. The second protective layer comprises an organic-chemical secondary coating which comprises at least one a-silane of formula (I): -O (4-n-m) -Si(-R 1 ) m (-CH 2 -Y) n , which is bound to the second protective layer by means of at least one oyxgen atom, wherein 1 = n+m = 3; m = 0 - 2; n = 1 - 3 ist and R 1 represents a hydrogen atom or a Si-C bound C 1 -C 20 -hydrocarbon radical or a C 1 -C 15 -hydrocarbon radical, wherein, respectively, one or more non-adjacent methylene units by have been replaced by groups -O-, -CO-, -COO-, -OCO-, or -OCOO-, -S-, or -NR X - and in which one or more non-adjacent methine units may have been replaced by groups -N=, -N=N-, oder -P=, wherein R 1 can be identical or different, identical or different, R x can be a hydrogen atom or a linearer, branched and/or cyclic C 1 -C 15 - carbon, hydrogen or aryl radical, and Y is a reactive functional binding group comprising a binding agent system.

    Abstract translation: 本发明涉及一种珠光颜料具有含金属氧化物的,片状基底,并具有第一和第二保护层,其中所述金属氧化物具有的折射率大于1.8,大于其中氧化铈和/或铈氧化物水合物和/或氢氧化铈包括在第一保护层 ,第二保护层由基本上,优选完全由SiO的 2,其中,所述第二保护层被布置在第一保护层之后且在所述第一和除氧化铈和/或铈以外的第二保护层中的金属氧化物层之间 水合物和/或氢氧化铈和SiO 2 的,可以被布置,其中,所述第二保护层包括有机化学aftercoat和通过至少一个氧原子的有机化学aftercoat至少一个所述第二保护层上键合的 硅烷具有式(I):-O (4- nm)的的Si(-R 1 (-CH 2 - Y)包括 n ,其中1 = n + m = 3; m = 0-2; N = 1 - 3,且R 1 表示氢原子或Si-C键合ç 1 -C 20 烃基或C 1 -C 15 -Kohlenwasserstoffoxyrest,在每种情况下的一个或多个不相邻的亚甲基单元可以被-O - , - CO - , - COO - , - OCO - ,或 - OCOO - , - S-,或-NR X - 可以被替换,并且其中通过将一个或多个不相邻的次甲基单元-N =, - N = N-,或-P = 可以被替换,其中R 1 可以独立地是相同或不同的,R X 代表氢原子或直链,支链和/或环状的C 1 -C 15碳可以是氢或芳基,并且Y是与粘合剂体系反应的官能团。

    HIGH-GLOSS MULTILAYER EFFECT PIGMENTS HAVING A NARROW SIZE DISTRIBUTION, AND METHOD FOR THE PRODUCTION THEREOF
    8.
    发明申请
    HIGH-GLOSS MULTILAYER EFFECT PIGMENTS HAVING A NARROW SIZE DISTRIBUTION, AND METHOD FOR THE PRODUCTION THEREOF 审中-公开
    随着对粒径分布窄法高翊MEHRSCHICHTPERLGLANZPIGMENTE及其

    公开(公告)号:WO2011020569A8

    公开(公告)日:2011-04-21

    申请号:PCT/EP2010004864

    申请日:2010-08-09

    Abstract: The invention relates to multilayer effect pigments based on laminar transparent substrates having an optically effective coating which comprises at least a) a non-absorbing high-refractive layer A having a refractive index n = 1.8, b) a low-refractive layer B having a refractive index n 150 nm, c) an absorbing high-refractive layer C having a refractive index n = 1.8, and d) an optional outer protective layer D. Said multilayer effect pigments have a cumulative frequency distribution of the volume-averaged size distribution function having the reference numbers D10, D50, D90 and a span ?D ranging from 0.7 to 1.4, the span ?D being calculated according to formula ?D = (D90 - D10)/D50. The invention further relates to a method for producing said multilayer pigments and to the use thereof.

    Abstract translation: 本发明涉及一种Mehrschichtperlglanzpigmente基于与光学有效涂层,血小板片状透明基底,其中,所述光学活性涂层至少a)一种非吸收性的高折射率层A具有折射率n = 1.8 b)具有折射率n <1.8的低折射率层乙 用光学层厚度> 150nm的c)具有折射率n = 1.8和d的吸收性高折射率层C)任选地包含外保护层D,并且所述Mehrschichtperlglanzpigmente体积平均尺寸分​​布函数的与所述密钥数据D10,D50,D90累积频率分布和 0.7的夹紧ð - 1.4有,夹持ð根据公式D =(D90 - D10)计算值/ D50?。 本发明还涉及用于这些多层颜料的制备以及它们的用途。

    SURFACE-COATED PEARLESCENT PIGMENTS, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF
    9.
    发明申请
    SURFACE-COATED PEARLESCENT PIGMENTS, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF 审中-公开
    表面处理的周期性颜料,其生产过程及其用途

    公开(公告)号:WO2007017199A8

    公开(公告)日:2007-07-05

    申请号:PCT/EP2006007749

    申请日:2006-08-04

    Inventor: KAUPP GUENTER

    Abstract: The invention relates to surface-modified pearlescent pigments whose surface is provided with at least one organic phosphoric compound of general formula (I) R 1 R 2 P(O)(OR 3 ) and/or general formula (II) R 1 P(O)(OR 3 )(OR 4 ), wherein R 1 and R 2 independently represent hydrogen or an organic radical comprising 1 to 30 C atoms, provided that R 1 and R 2 do not simultaneously represent hydrogen, R 3 and R 4 independently represent H or alkyl comprising 1 to 10 C atoms. The invention further relates to a method for producing said pearlescent pigments and the use thereof.

    Abstract translation: 本发明涉及表面改性的珠光颜料,其中表面上的珠光颜料与至少一种具有通式(I)的有机含磷化合物; [R 1 - [R 2 P(O)OR 3 )和/或通式(II)R 1 P(O)(OR 3 )(OR 4 )被提供,其中R 1 和R 2 独立地 彼此氢或有机基团的碳原子数1〜30,条件是R 1 和R 2 不同时为氢,R 3 < 其中R 4和R 4独立地为H或1-10个碳原子的烷基。 本发明还涉及制备这些珠光颜料的方法及其用途。

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