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    PHOSPHOROUS-BASED SENSORS FOR DETECTION OF MULTIPLE SOLVENTS
    1.
    发明申请
    PHOSPHOROUS-BASED SENSORS FOR DETECTION OF MULTIPLE SOLVENTS 审中-公开
    用于检测多种溶剂的基于磷光体的传感器

    公开(公告)号：WO2016183053A1

    公开(公告)日：2016-11-17

    申请号：PCT/US2016/031593

    申请日：2016-05-10

    Applicant: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM

    Inventor： HUMPHREY, Simon, M. ,  HOLLIDAY, Bradley, J. ,  MOORE, Matthew, D. ,  DUNNING, Samuel, G.

    IPC: C07D319/12 ,  C09K11/07 ,  C09K11/08 ,  G01N21/64

    CPC classification number: G01N21/78 ,  C09K11/06 ,  C09K2211/1014 ,  C09K2211/182 ,  G01N31/22 ,  G01N2021/7786

    Abstract: Embodiments of the present disclosure pertain to methods of monitoring an environment for the presence of a solvent by: (i) exposing the environment to a luminescent compound, where the relative luminescence emission intensity of the luminescent compound changes upon interaction with the solvent; and (ii) monitoring a change in the relative luminescence emission intensity of the luminescent compound, where the absence of the change indicates the absence of the solvent from the environment, and where the presence of the change indicates the presence of the solvent in the environment. The luminescent compounds include a phosphorous atom with one or more carboxyl groups, where the carboxyl groups are coordinated with one or more metallic ions (e.g., lanthanide ions and yttrium ions). The present disclosure also pertains to sensors for monitoring an environment for the presence of a solvent, where the sensors include one or more of the aforementioned luminescent compounds.

    Abstract translation: 本公开的实施方案涉及通过以下方式监测溶剂存在的环境的方法：（i）将环境暴露于发光化合物，其中发光化合物的相对发光强度随溶剂相互作用而改变; 和（ii）监测发光化合物的相对发光强度的变化，其中不存在变化表明溶剂不存在于环境中，并且如果存在变化表明溶剂在环境中的存在 。 发光化合物包括具有一个或多个羧基的磷原子，其中羧基与一种或多种金属离子（例如镧系元素离子和钇离子）配位。 本公开还涉及用于监测溶剂存在的环境的传感器，其中传感器包括一种或多种上述发光化合物。

    COMPOSITIONS AND METHODS FOR THE LIQUID-PHASE SEPARATION OF ISOMERS OF AROMATIC MOLECULES
    2.
    发明申请
    COMPOSITIONS AND METHODS FOR THE LIQUID-PHASE SEPARATION OF ISOMERS OF AROMATIC MOLECULES 审中-公开
    用于芳烃分子异构体的液相分离的组合物和方法

    公开(公告)号：WO2016089686A1

    公开(公告)日：2016-06-09

    申请号：PCT/US2015/062585

    申请日：2015-11-25

    Applicant: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM

    Inventor： HUMPHREY, Simon, M.

    IPC: C08K7/14

    CPC classification number: B01D15/08 ,  B01D17/0202 ,  B01J20/226 ,  B01J20/28011 ,  B01J20/28016 ,  B01J20/28064 ,  B01J20/28083 ,  C07C7/12 ,  C07C15/44

    Abstract: The present invention includes a composition and process for separating p-isomers of vinylbenzenes from a mixture of isomers comprising the steps of: providing a porous microwaved Mg(II) 2,4-pyridinedicarboxylic acid coordination polymer having a 1-D pore structure and showing reversible soft-crystal behavior by preferentially binding p-isomers of vinylbenzene; adding a mixture of vinylbenzenes isomers to the porous microwaved Mg (II) 2,4- pyridinedicarboxylic acid coordination polymer; adsorbing the p-isomers of vinylbenzene from the mixture of vinylbenzenes isomers; selectively adsorb the p -isomers of vinylbenzene in the 1- D pore structure; removing the mixture of vinylbenzenes isomers; and desorbing the p -isomers of vinylbenzene from the 1-D pore structure to purify the p -isomers of vinylbenzene.

    Abstract translation: 本发明包括从异构体混合物中分离乙烯基苯的对异构体的组合物和方法，包括以下步骤：提供具有1-D孔结构的多孔微波Mg（II）2,4-吡啶二羧酸配位聚合物， 通过优先结合乙烯基苯的对 - 异构体可逆的软晶体行为; 向多孔微波Mg（II）2,4-吡啶二羧酸配位聚合物中加入乙烯基苯异构体的混合物; 从乙烯基苯异构体的混合物中吸附乙烯基苯的对异构体; 在1-D孔结构中选择性吸附乙烯基苯的对异构体; 除去乙烯基苯异构体的混合物; 并从1-D孔结构解吸乙烯基苯的对异构体，以纯化乙烯基苯的对异构体。

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