Abstract:
Extrusion coating polyethylene composition A), comprising a) 70 wt% - 98wt% of a high pressure low density polyethylene homopolymer, produced in a tubular reactor, having a melt index of 2 to 8 g/10 min according to ISO 1133 (190°C, 2.16 kg) and a density of 915 to 935 kg/m 3 according to ISO 1183 and b) 2 wt% - 30 wt of a long chain branched, low-density polyethylene, having a melt index MFR of 2.5 to 10.0 g/10 min according to ISO 1133 (190°C, 2.16 kg), a density of 910 to 935 kg/m 3 according to ISO 1183 and - a dynamic viscosity η 0.05 at a shear rate of 0.05 rad/s and a dynamic viscosity η 300 rad/s which satisfy the following relationship: η 300 ≤ 108 Pa*s + 0.0253* η 0.05 and/or - a phase shift δ 0.5 at a frequency of 0.5 rad/s and a phase shift δ 300 at a frequency of 300 rad/s, which satisfy the following relationship: tan δ 300 ≥ 0.45 + 0.164* tan δ 0.05 and its use.
Abstract translation:挤出涂覆聚乙烯组合物A),其包含a)70重量%至98重量%的在管式反应器中制备的高压低密度聚乙烯均聚物,根据ISO 1133(190°)具有2至8g / 10min的熔体指数 C,2.16kg),根据ISO 1183的密度为915至935kg / m 3,b)2重量%-30重量%的长链支化低密度聚乙烯,其熔体指数MFR为2.5至10.0g / 根据ISO 1133(190℃,2.16kg)10分钟,根据ISO 1183的密度为910至935kg / m 3,剪切速率为0.05rad / s时的动态粘度≥0.05,动态粘度≥300 满足以下关系的rad / s:在300rad / s的频率下的Δ300= 108Pa * s + 0.0253 *≤0.05和/或 - 在0.5rad / s的频率下的相移d0.5和300rad的频率的相移d300 / s,满足以下关系:tan d300 = 0.45 + 0.164 * tan d 0.05及其用途。
Abstract:
Two-component adhesion composition suitable for extrusion coating paper substrates which comprises a) from 70 to 98 wt% of high melt strength polypropylene (A) with a branching index g' of 0.9 or less and b) from 2 to 30 wt% of a component (B) selected from the group of (i) maleic anhydride-modified polypropylene (MAPP) (ii) maleic anhydride-modified polypropylene wax (iii) polypropylene homopolymer with high melt flow rate or (iv) ethylene-vinyl acetate-based hot melt adhesive and its use.
Abstract:
Soft polypropylene composition with improved optical and mechanical properties and especially improved resistance to steam sterilization, as well as to its manufacture and use and to articles made out of the new composition.
Abstract:
Catalyst system, the catalyst system comprising (i) at least one metallocene complex of formula (I), (I) wherein Mt1 is Hf, X is a sigma-donor ligand, R 1 , R 2 , R 3 are the same or different from each other and can be hydrogen or a saturated linear or branched C 1 -C 10 alkyl, whereby the alkyl group can optionally contain up to 2 heteroatoms belonging to groups 14-16 of the periodic table, or R 1 and R 2 or R 2 and R 3 can form a ring having 4 to 6 C-atoms and 1 to 3 double bonds, R 4 and R 5 are the same or different from each other and can be saturated linear or branched C 1 -C 10 alkyl, C 5 -C 10 aryl, C 6 -C 20 alkylaryl or C 6 -C 20 arylalkyl groups, which can optionally contain up to 2 heteroatoms belonging to groups 14-16 of the periodic table, n can be 1 to 5, Ar is a C 6 -C 20 -aryl or -heteroarylgroup, which can be unsubstituted or substituted by 1 to 5 linear or branched C 1 - C 10 alkyl group(s), and (ii) a boron containing cocatalyst.
Abstract:
Disentangled high or ultrahigh molecular weight polyethylene ((U)HMWPE) being produced with a Ziegler-Natta catalyst, characterized by (i) a factor for the normalized elastic modulus G' 0 /G' P of less than 0.95 determined in a dynamic time sweep measurement at 180°C with constant strain of 0.5% at fixed frequency of 10 rad/s for at least 3600s, whereby G' 0 is the elastic shear modulus measured at t0 directly after melting the sample and G' p is the maximum plateau modulus.
Abstract:
Ziegler-Natta polymerization catalyst composition for the (co)polymerization of ethylene, said catalyst composition comprising 1) a solid procatalyst formed by contacting at least: a) a Mg-alcoholate compound of the formula (I): Mg(OR 1 ) 2-n (R 1 )n, wherein each R 1 independently represents a C 1 -C 20 hydrocarbyl group and 0 ≤ n 2 ) m X 3-m , wherein each R 2 independently represents an alkyl of 1 to 6 carbon atoms; each X is independently a halogen; 0≤ m 1 -C 4 -alkyl) p -AI-X 3-p, wherein X is chlorine, bromine, iodine or fluorine and p is 1 or 2, whereby the composition shows increased comonomer sensitivity and its use for the production of an ethylene.
Abstract:
Composition comprising a water resistive and water vapour barrier polymer component, for example a PO barrier polymer component, preferably a PP barrier polymer component, an oxygen barrier polymer component, preferably an ethylene vinyl alcohol polymer component and/or a polyamide component, and an anisotropic mineral filler and its use.
Abstract:
High purity heterophasic polypropylene copolymers comprising (A) 73 to 98 wt% of a propylene homo- or copolymer matrix with an MFR 2 in accordance with ISO 1133 (230°C, 2.16 kg load) of ≥ 45 g/10 min and (B) 2 to 27 wt% of an elastomeric copolymer, comprising propylene in an amount of at least 50 wt% of component (B) and at least ethylene and/or one other C 4 to C 10 alpha olefin in an amount of up to 50 wt% of component (B), the heterophasic polypropylene copolymers being obtainable by a multistage polymerization process in the presence of a catalyst system comprising (i) a Ziegler-Natta procatalyst which contains a trans-esterification product of a lower alcohol and a phthalic ester and (ii) optionally an organometallic cocatalyst and (iii) an external donor represented by formula (I) Si(OCH 2 CH 3 ) 3 (NR 1 R 2 ) wherein R 1 and R 2 can be the same or different a represent a hydrocarbon group having 1 to 12 carbon atoms, their production and use.
Abstract:
The present invention is directed to a new heterophasic polypropylene composition showing a good balance between stiffness and impact at low haze, as well as to its use for injection molded articles. The present invention is also directed to provide such heterophasic polypropylene composition in a more simplified mode of production.
Abstract:
High density polyethylene blend, comprising (A) 55 to 99wt% of a high density multimodal polyethylene component having a density of at least 930 kg/m3, and (B) 1 to 45wt% of an ultra-high molecular weight polyethylene homo- or copolymer component having (i) an intrinsic viscosity of at least 15.0 dl/g (ii) an a nominal viscosity molecular weight (Mv) of at least 2.0*10 6 g/mol and (iii) a molecular weight of (M w ) of at least 0.7*10 6 g/mol, and wherein said blend has an MFR 21 of 0.05 to 10.0 g/10min and a density of at least 925 kg/m 3 .
Abstract translation:高密度聚乙烯共混物,包含(A)55至99重量%的密度为至少930kg / m 3的高密度多峰聚乙烯组分,和(B)1至45wt%的超高分子量聚乙烯均聚物或 共聚物组分具有(i)至少15.0dl / g的特性粘度(ii)至少2.0×10 6 g / mol的标称粘度分子量(Mv)和(iii)分子量(Mw)at 至少0.7 * 106g / mol,并且其中所述共混物具有0.05至10.0g / 10min的MFR 21和至少925kg / m 3的密度。