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    METHODS FOR FORMING PEROXYFORMIC ACID AND USES THEREOF
    15.
    发明申请
    METHODS FOR FORMING PEROXYFORMIC ACID AND USES THEREOF 审中-公开
    用于形成过氧酸的方法及其用途

    公开(公告)号：WO2016100700A1

    公开(公告)日：2016-06-23

    申请号：PCT/US2015/066438

    申请日：2015-12-17

    Applicant: ECOLAB USA INC.

    Inventor： BALASUBRAMANIAN, Ramakrishnan ,  LI, Junzhong ,  STAUB, Richard ,  KEASLER, Victor ,  BENNETT, Brian ,  BREWSTER, Allison

    IPC: A01N37/00 ,  A01N37/16 ,  A61L2/18 ,  A23C7/02 ,  C02F1/72 ,  C07C407/00 ,  C07C409/24 ,  C07C409/26

    CPC classification number: C07C409/24 ,  A01N37/16 ,  A23L3/34635 ,  A23L3/3508 ,  A23V2002/00 ,  C07C407/00 ,  C07C407/006

    Abstract: The present invention relates generally to methods for forming peroxyformic acid, comprising contacting formic acid with hydrogen peroxide. The methods for forming peroxyformic acid can include adding formic acid with a relatively lower concentration of hydrogen peroxide, or adding formic acid to a peroxycarboxylic acid composition or forming composition to react with hydrogen peroxide in the compositions. The present invention also relates to peroxyformic acid formed by the above methods. The present invention further relates to the uses of peroxyformic acid for treating a variety of targets, e.g ., target water, including target water used in connection with oil- and gas-field operations. The present invention further relates to methods for reducing or removing H 2 S or iron sulfide in the treated water source, improving clarity of the treated water source, or reducing the total dissolved oxygen or corrosion in the treated water source, using peroxyformic acid, including peroxyformic acid generated in situ.

    Abstract translation: 本发明一般涉及形成过氧甲酸的方法，包括使甲酸与过氧化氢接触。 形成过氧甲酸的方法可以包括以较低浓度的过氧化氢加入甲酸，或将甲酸加入到过氧羧酸组合物中或形成组合物中以与组合物中的过氧化氢反应。 本发明还涉及通过上述方法形成的过氧甲酸。 本发明还涉及过氧甲酸用于处理各种靶物（例如目标水，包括与油气田操作有关的目标水）的用途。 本发明还涉及使用过氧甲酸（包括过氧甲酸）来减少或除去处理水源中的硫化氢或硫化铁的方法，提高处理水源的透明度或降低处理水源中的总溶解氧或腐蚀 原地生成。

    PROCESS FOR THE PREPARATION OF PEROXY ACIDS
    17.
    发明申请
    PROCESS FOR THE PREPARATION OF PEROXY ACIDS 审中-公开
    过氧化氢的制备方法

    公开(公告)号：WO2007031596A2

    公开(公告)日：2007-03-22

    申请号：PCT/FI2006/000303

    申请日：2006-09-13

    Applicant: KEMIRA OYJ ,  AKSELA, Reijo ,  RENVALL, Ilkka

    Inventor： AKSELA, Reijo ,  RENVALL, Ilkka

    IPC: A01N37/16 ,  C07C20060101 ,  C07C409/24 ,  C07C409/26 ,  C07C409/30

    CPC classification number: C07C409/24 ,  A01N37/02 ,  A01N37/16 ,  C07C407/00 ,  C07C409/26 ,  C07C409/30 ,  A01N37/04 ,  A01N37/06 ,  A01N37/10 ,  A01N37/36 ,  A01N59/00 ,  A01N2300/00

    Abstract: The present invention relates to a process for the preparation of a solution comprising a first peroxy acid comprising performic acid and a second peroxy acid, said process comprising forming a carboxylic acid solution comprising a first carboxylic acid comprising formic acid, a second carboxylic acid and hydrogen peroxide, wherein the amount of formic acid is from 0.5 to 20 % by weight of the amount of the second carboxylic acid, and allowing the components to react to form a solution comprising performic acid and said second peroxy acid, the amount of peroxy acids being at least 5 % by weight. The invention also relates to a storable solution comprising performic acid and said second peroxy acid. The solution can be used as a disinfecting agent for controlling micro-organisms.

    Abstract translation: 本发明涉及一种制备溶液的方法，所述溶液包含包含甲酸和第二过氧酸的第一过氧酸，所述方法包括形成羧酸溶液，所述羧酸溶液包含含有甲酸，第二羧酸和氢的第一羧酸 过氧化物，其中甲酸的量为第二羧酸的量的0.5至20重量％，并且使组分反应以形成包含甲酸和所述第二过氧酸的溶液，过氧酸的量为 至少5重量％。 本发明还涉及包含甲酸和所述第二过氧酸的可储存溶液。 该溶液可用作控制微生物的消毒剂。

    METHOD FOR THE CONTINUOUS PRODUCTION OF MIXTURES OF SUBSTANCES AND REACTION MIXTURES AND A DEVICE FOR CARRYING OUT SAID METHOD
    19.
    发明申请
    METHOD FOR THE CONTINUOUS PRODUCTION OF MIXTURES OF SUBSTANCES AND REACTION MIXTURES AND A DEVICE FOR CARRYING OUT SAID METHOD 审中-公开
    过程对于识别以及反应混合物的连续生产和实施设备将其

    公开(公告)号：WO02026459A1

    公开(公告)日：2002-04-04

    申请号：PCT/EP2001/009454

    申请日：2001-08-16

    IPC: B01F3/08 ,  B01F5/06 ,  C07C409/24 ,  C07C409/26 ,  G05D11/13 ,  B29B7/60 ,  B01F15/04

    CPC classification number: G05D11/132 ,  B01F3/088 ,  B01F5/0602 ,  B01F15/00136 ,  B01F15/00344 ,  B01F15/0479 ,  C07C407/00 ,  C07C409/26 ,  C07C409/24

    Abstract: The invention relates to a method for the continuous production of a mixture of substances or a reaction mixture formed by the reaction of components contained therein. The component fluxes drawn from a storage container (1, 2 or 3) or a distribution network (12) are respectively channelled via a control path (22, 23, 24, 25), each path comprising a flowmeter device (8, 9, 10, 11) and a control organ (34, 35, 36, 37). The mass fluxes of the individual components are controlled in proportion to the mass flux of a first component. The resultant controlled mass fluxes are introduced into a reservoir either directly, or once the individual mass fluxes have been partially or fully combined. The method and the device are particularly suitable for the on-site production of non-transportable mixtures of substances, or mixtures of substances that are costly to transport, such as highly concentrated peroxycarboxylic acid solutions.

    Abstract translation: 本发明涉及一种用于连续生产的物质的混合物，或通过反应包含形成在其中的组分的反应混合物。 由一个储存器（1，2或3）或配电网络（12）绘制成分流在每种情况下通过一个控制系统（22，23，24，25），每个具有一个流量测量装置（8，9，10，11）和控制构件 （34，35，36，37），引导。 各个组分的流速成比例地调节至体积参照的第一组件的电流的量。 将得到的调节质量流量被引入直接或单个质量的完全或部分合并流入容器之后。 该方法和装置特别适用于现场生产非/消耗输送性材料的混合物，如高浓度的Peroxycarbonsäurelösungen。

    PROCESS FOR PREPARING PEROXIDES USING MIXED ANHYDRIDES
    20.
    发明申请
    PROCESS FOR PREPARING PEROXIDES USING MIXED ANHYDRIDES 审中-公开
    使用混合无机物制备过氧化物的方法

    公开(公告)号：WO01027078A1

    公开(公告)日：2001-04-19

    申请号：PCT/EP2000/009927

    申请日：2000-10-09

    IPC: C07C407/00 ,  C07B61/00 ,  C07C68/02 ,  C07C69/96 ,  C07C409/24 ,  C07C409/34 ,  C07C409/38 ,  C08F4/32 ,  C08F4/34 ,  C08F20/00

    CPC classification number: C07C69/96 ,  C07C409/24 ,  C07C409/34 ,  C07C409/38 ,  C07C2601/14

    Abstract: The invention relates to a process for the preparation of a peracid, perester or diacylperoxide and is characterized in that a mixed anhydride of formula: R [C(O)OC(O)OR ]n or [R C(O)OC(O)O]pR is contacted with a hydroperoxide of formula: R [OOH]m in the presence of a base, wherein R represents a mono-, di-, tri- or tetravalent C1-C19 hydrocarbon group, optionally containing one or more hetero atoms, n is 1-4, R represents a C1-C20 hydrocarbon group, optionally containing one or more hetero atoms, R represents a C1-C19 hydrocarbon group, optionally containing one or more hetero atoms, R represents a di-, tri- or tetravalent C1-C20 hydrocarbon group, optionally containing one or more hetero atoms, p is 2-4, R represents hydrogen or a mono- or divalent C3-C18 tertiary alkyl or C2-C20 acyl group, in which the tertiary alkyl or acyl group may optionally contain one or more hetero atoms, m is 1 or 2, and if R represents hydrogen, m is 1, provided that if the hydroperoxide is an alpha , alpha -dihydroperoxyperoxide, the reaction is not carried out in an inert two-phase solvent system comprising a polar solvent and an polar solvent. The invention also relates to a hydroxyperacid, hydroxyperester, and hydroxydiacylperoxide obtainable by said process and the use of said hydroxyperoxides.

    Abstract translation: 本发明涉及一种制备过酸，过氧化物或二酰基过氧化物的方法，其特征在于下列结构式的混合酸酐：R 1 [C（O）OC（O）OR 2] n或[ 3 C（O）OC（O）O] p R 4在碱的存在下与式R 5 [OOH] m的氢过氧化物接触，其中R 1表示单，二 - ，三价或四价的C 1 -C 19烃基，任选地含有一个或多个杂原子，n为1-4，R 2表示任选含有一个或多个杂原子的C 1 -C 20烃基，R 3， 表示任选含有一个或多个杂原子的C 1 -C 19烃基，R 4表示二价，三价或四价C 1 -C 20烃基，任选地含有一个或多个杂原子，p为2-4，R 其中叔烷基或酰基可任选地含有一个或多个杂原子，m为1或2，并且如果R 1为氢或一或二价C 3 -C 18叔烷基或C 2 -C 20酰基， 5>表示氢，m为1，条件是如果水合 过氧化氢是α，α-二氢过氧化氢，该反应不是在包含极性溶剂和极性溶剂的惰性两相溶剂系统中进行的。 本发明还涉及通过所述方法和所述羟基过氧化物的使用可获得的羟基过酸，羟基过氧化物和羟基过氧化氢。

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