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    A PROCESS FOR MAKING HIGH OCTANE GASOLINE
    8.
    发明申请
    A PROCESS FOR MAKING HIGH OCTANE GASOLINE 审中-公开

    公开(公告)号：WO2018118346A1

    公开(公告)日：2018-06-28

    申请号：PCT/US2017/063381

    申请日：2017-11-28

    申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

    发明人： WANG, Kun

    IPC分类号： C10G50/00 ,  C10L1/06 ,  C07C2/76 ,  C07C407/00

    摘要： A process for converting light paraffins to a high octane gasoline composition is disclosed. The process involves: (1) oxidation of iso-paraffins to alkyl hydroperoxides and alcohol; (2) conversion of the alkyl hydroperoxides and alcohol to dialkyl peroxides; and (3) radical coupling of iso-paraffins using the dialkyl peroxides as radical initiators, thereby forming gasoline-range molecules. Fractionation of the gasoline-range molecules can then be used to isolate high octane gasoline fractions having a road octane number [(RON+MON)/2] greater than 110.

    PRODUCTION OF TERT- BUTYL HYDROPEROXIDE SOLUTION AND PROCESS TO FORM PRODUCTS THEREFROM
    9.
    发明申请
    PRODUCTION OF TERT- BUTYL HYDROPEROXIDE SOLUTION AND PROCESS TO FORM PRODUCTS THEREFROM 审中-公开
    叔丁基氢过氧化物溶液的生产以及由此形成产品的过程

    公开(公告)号：WO2018071272A1

    公开(公告)日：2018-04-19

    申请号：PCT/US2017/055404

    申请日：2017-10-05

    申请人： LYONDELL CHEMICAL TECHNOLOGY, L. P.

    发明人： NGUYEN, Ha, H. ,  CHANG, Te ,  MCDOWELL, William, H.

    IPC分类号： C07C407/00 ,  C07C409/04

    摘要： A process for forming a concentrated solution, including distilling in a distillation zone comprised of 10 or more theoretical distillation stages, at a pressure of no greater than 300 mm Hg and a reflux ratio (D/L) of at least 1:1, an amount of an initial solution comprised of tert-butyl hydroperoxide (TBHP) in tert-butyl alcohol (TBA) having a TBHP concentration of up to 60 wt.% and a total impurity content greater than 0.01 wt.%, for a time and under distillation conditions to form a concentrated solution comprised of TBHP in TBA; and separating an overhead distillate from the distillation zone so that the concentrated solution thereafter has a TBHP concentration greater than 60 wt.%, a TBA concentration less than 40 wt.%, a water impurity content no greater than 0.1 wt.% and a total impurity content of no greater than 1 wt.%. Related epoxidation catalyst formation and epoxidation processes are also described.

    摘要翻译： 在不大于300mmHg的压力和回流比（D / L）下，形成浓缩溶液的方法，所述浓缩溶液包括在由10个或更多个理论蒸馏步骤组成的蒸馏区中蒸馏， （TBHP）的TBHP浓度最高达60重量％且总杂质含量大于0.01重量％的叔丁醇（TBA）中的初始溶液的量为至少1：1， 在蒸馏条件下一段时间以形成由TBA中的TBHP组成的浓溶液; 和从蒸馏区中分离塔顶馏出物，使得浓缩溶液此后具有大于60重量％的TBHP浓度，小于40重量％的TBA浓度，不大于0.1重量％的水杂质含量和总量 杂质含量不大于1重量％。 还描述了相关的环氧化催化剂形成和环氧化过程。

    GAS DISTRIBUTION IN OXIDATION REACTIONS
    10.
    发明申请
    GAS DISTRIBUTION IN OXIDATION REACTIONS 审中-公开
    气体分布在氧化反应中

    公开(公告)号：WO2017003644A1

    公开(公告)日：2017-01-05

    申请号：PCT/US2016/035825

    申请日：2016-06-03

    申请人： EXXONMOBIL CHEMICAL PATENTS INC.

    发明人： IGCI, Yesim ,  PATEL, Brian A. ,  CHANG, Min

    IPC分类号： C07C407/00

    CPC分类号： B01J8/22 ,  B01J4/004 ,  C07C407/00 ,  C07C409/14 ,  C07C2601/14

    摘要： Systems, methods, and apparatus for distribution of oxygen-containing gas within a gas-liquid oxidation reaction are provided herein. The invention is particularly suited for oxidation of liquid-phase organic reactants with oxidizing gas, such as the oxidation of cyclohexylbenzene to cyclohexylbenzene hydroperoxide using an oxygen-containing gas. The oxygen-containing gas is distributed through a gas distributor and into a liquid-phase reaction medium within an oxidation reactor. In some aspects, this achieves a high degree of uniformity of oxygen concentration within the liquid-phase reaction medium. The gas distributor is disposed within a lower portion of the reactor, and may comprise a network of conduits in fluid communication with each other, which are arranged within a plane that is substantially parallel to a bottom surface of the reactor. A plurality of orifices are disposed on the conduits, such that oxygen-containing gas flows through the conduits and into the liquid-phase reaction medium via the orifices.

    摘要翻译： 本文提供了用于在气液氧化反应中分配含氧气体的系统，方法和装置。 本发明特别适用于氧化气体的液相有机反应物，例如使用含氧气体将环己基苯氧化成环己基苯氢过氧化物。 含氧气体通过气体分配器分布到氧化反应器内的液相反应介质中。 在某些方面，这实现了液相反应介质中氧浓度的高度均匀性。 气体分配器设置在反应器的下部，并且可以包括彼此流体连通的管道网络，其布置在基本上平行于反应器的底表面的平面内。 多个孔口设置在导管上，使得含氧气体经由孔口流过导管并进入液相反应介质。