POLYMERIC AMMONIUM AND OR PHOSPHONIUM SALTS HAVING ADDED π-ELECTRONS AND HIGHER MOLECULAR WEIGHT AS ENHANCERS FOR CHEMILUMINESCENT SYSTEMS
    36.
    发明申请
    POLYMERIC AMMONIUM AND OR PHOSPHONIUM SALTS HAVING ADDED π-ELECTRONS AND HIGHER MOLECULAR WEIGHT AS ENHANCERS FOR CHEMILUMINESCENT SYSTEMS 审中-公开
    具有添加的π电子和高分子量的聚合氨和或磷酸盐作为增亮剂用于光致发光体系

    公开(公告)号:WO2003099802A1

    公开(公告)日:2003-12-04

    申请号:PCT/US2003/016584

    申请日:2003-05-23

    申请人: GIRI, Brij, Pal

    发明人: GIRI, Brij, Pal

    IPC分类号: C07D303/00

    摘要: A compound for enhancing the light output of a chemiluminescent system and, in particular, a stabilized, triggerable 1,2-dioxetane, is obtained by reacting a polyvinylbenzyl halide and a bilinker with either a trisubstituted amine or trisubstituted phosphine. A fluorescent molecule may be attached to polymer along with the trisubstituted amine or trisubstituted phosphine. Also, the benzyl halide may be reacted with a π-electron donor, such as a vinyl naphthalene or vinylanthracene to form a co-polymer which is polymerizable with the trisubstituted amine and/or trisubstituted phosphine. By controlling the reaction parameters it is possible to obtain either a water-soluble or partial water soluble or insoluble compound crosslink polymer.

    摘要翻译: 通过使聚乙烯基苄基卤化物和双头层与三取代的胺或三取代的膦反应来获得化学发光体系,特别是稳定的可触发的1,2-二氧杂环丁烷的光输出化合物。 荧光分子可以与三取代的胺或三取代的膦一起连接到聚合物上。 此外,苄基卤可以与π-电子给体如乙烯基萘或乙烯基蒽反应形成可与三取代的胺和/或三取代的膦一起聚合的共聚物。 通过控制反应参数,可以获得水溶性或部分水溶性或不溶性的化合物交联聚合物。

    高分子化合物の製造方法
    37.
    发明申请
    高分子化合物の製造方法 审中-公开
    生产高分子化合物的方法

    公开(公告)号:WO2003057762A1

    公开(公告)日:2003-07-17

    申请号:PCT/JP2002/013567

    申请日:2002-12-26

    IPC分类号: C08G85/00

    摘要: A process for production of high-molecular compounds, characterized by comprising the following steps (A) and (B): (A) the step of polymerizing one or more monomers represented by the general formula (1) under such conditions that X1 and X2 can react with each other to form a bond and thereby obtaining a polymer having Y reactive groups: X1 - Ar1 - X2 (1) (wherein X1 and X2 are respectively reactive groups which can react with each other to form a bond; Ar1 is arylene, a divalent heterocyclic group, or a divalent aromatic amine group; and Ar1 bears at least one Y reactive group substantially inert to X1 and X2), and (B) the step of reacting the Y-bearing polymer obtained in the step (A) with a compound having a Z reactive group which can react with the Y reactive group to form a bond.

    摘要翻译: 一种制备高分子化合物的方法,其特征在于包括以下步骤(A)和(B):(A)在X1和X2的条件下聚合一种或多种由通式(1)表示的单体的步骤 可以彼此反应形成键,从而得到具有Y反应性基团的聚合物:X1-Ar1-X2(1)(其中X1和X2分别是可以彼此反应形成键的反应性基团; Ar1​​是亚芳基 二价杂环基或二价芳香族胺基; Ar 1具有至少一个对X1和X2基本上惰性的Y反应性基团),和(B)使在步骤(A)中得到的含Y轴承聚合物反应的步骤, 具有可与Y反应性基团反应形成键的具有Z反应性基团的化合物。