公开(公告)号：WO2010141129A1

公开(公告)日：2010-12-09

申请号：PCT/US2010/025586

申请日：2010-02-26

Applicant: AIR PRODUCTS AND CHEMICALS, INC. ,  ZHENG, Shiying

Inventor： ZHENG, Shiying

IPC: C08L101/00 ,  H01B1/12 ,  H01L51/00

CPC classification number: H01L51/0036 ,  C08L65/00 ,  C08L101/005 ,  C08L101/10 ,  H01B1/122 ,  H01B1/125 ,  H01B1/127 ,  H01B1/128 ,  H01L51/0021 ,  H01L51/0035 ,  H01L51/0037 ,  H01L51/5203 ,  Y02E10/549 ,  C08L2666/14

Abstract: An aqueous dispersion and a method for making an aqueous dispersion. The dispersion including at least one conductive polymer, such as a polythienothiophene, at least one hyperbranched polymer and optionally at least one colloid-forming polymeric acid and one non-fluorinated polymeric acid. Devices utilizing layers formed of the aqueous dispersions are also disclosed.

Abstract translation: 水性分散体和水分散体的制造方法。 包括至少一种导电聚合物，如聚噻吩噻吩，至少一种超支化聚合物和任选的至少一种胶体形成聚合酸和一种非氟化聚合酸的分散体。 还公开了利用由水分散体形成的层的装置。

公开(公告)号：WO2005100466A1

公开(公告)日：2005-10-27

申请号：PCT/US2005/012717

申请日：2005-04-13

Applicant: ZYVEX CORPORATION ,  AIT-HADDOU, Hassan ,  RUTKOFSKY, Marni

Inventor： AIT-HADDOU, Hassan ,  RUTKOFSKY, Marni

IPC: C08K7/06

CPC classification number: H01B1/125 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C01B32/18 ,  C01B2202/02 ,  C01B2202/06 ,  C08G61/02 ,  C08K9/08

Abstract: Poly(aryleneethynylene) polymers for exfoliating and dispersing/solubilizing nanomaterial are provided herein. The poly(aryleneethynylene) polymers have unit monomer portions, each monomer portion having at least one electron donating substituent thereby forming an electron donor monomer portion, or at least one electron withdrawing substituent thereby forming an electron accepting monomer portion. Such polymers exfoliate and disperse nanomaterial without presonication of the nanomaterial.

Abstract translation: 本文提供了用于剥离和分散/增溶纳米材料的聚（亚芳基亚乙炔基）聚合物。 聚（亚芳基亚乙炔基）聚合物具有单元单体部分，每个单体部分具有至少一个给电子取代基，从而形成电子给体单体部分，或至少一个吸电子取代基，从而形成电子接受单体部分。 这种聚合物在纳米材料的预先分解的情况下剥离和分散纳米材料。

公开(公告)号：WO2005008684A1

公开(公告)日：2005-01-27

申请号：PCT/JP2004/010888

申请日：2004-07-23

Applicant: CANON KABUSHIKI KAISHA ,  MIYATA, Hirokatsu ,  NAKAMURA, Shinichi ,  KURIYAMA, Akira ,  OGAWA, Miki ,  KAWASHIMA, Yasuhiro

Inventor： MIYATA, Hirokatsu ,  NAKAMURA, Shinichi ,  KURIYAMA, Akira ,  OGAWA, Miki ,  KAWASHIMA, Yasuhiro

IPC: H01B1/12

CPC classification number: H01B1/127 ,  B82Y30/00 ,  H01B1/125 ,  Y10T428/24562 ,  Y10T428/24744

Abstract: The invention provides a structured material characterized in having, on a substrate (11), a layer (12) having tubular (13) pores positioned uniaxially parallel to the interface of the substrate and the layer and supporting a conductive polymer material (14,21) having a function of a surfactant (22) therein. The invention also provides a method for producing the above structure material characterized by the steps of providing a substrate having the anisotropy on a surface, applying a solution containing a surfactant having a functional group for polymerization in the molecular structure, a solvent therefor, and a solute different from the surfactant to the substrate, and a step of standing for a predetermined time for causing the surfactant to assemble in a predetermined direction based on the anisotropy of the substrate.

Abstract translation: 本发明提供了一种结构化材料，其特征在于在基底（11）上具有一层（12），该层具有与基底和该层的界面单轴平行的管状（13）孔，并支撑导电聚合物材料（14,21 ）具有表面活性剂（22）的功能。 本发明还提供了一种制造上述结构材料的方法，其特征在于以下步骤：在表面上提供具有各向异性的基材，涂布含有分子结构中具有聚合官能团的表面活性剂的溶液，其溶剂和 基于表面活性剂与基材不同的溶质，以及基于基板的各向异性而使表面活性剂以规定方向组装的规定时间的步骤。

公开(公告)号：WO02052659A1

公开(公告)日：2002-07-04

申请号：PCT/JP2001/011325

申请日：2001-12-25

IPC: C07F7/08 ,  C07F7/10 ,  C08F30/08 ,  C08F220/12 ,  C08G77/00 ,  C08G77/04 ,  C08G77/14 ,  C08G77/20 ,  C08G77/26 ,  C08G77/28 ,  C08G77/42 ,  C08J7/18 ,  C09D183/08 ,  C09K19/38 ,  G02F1/1337 ,  G09F9/30 ,  H01B1/12 ,  H01L31/08 ,  H01L51/00 ,  H01L51/05 ,  H01L51/10 ,  H01L51/30 ,  H01L51/40 ,  H01L51/42 ,  H05B33/08 ,  H01B7/00 ,  H01B13/00 ,  H01L29/786

CPC classification number: H01L51/0545 ,  B82Y10/00 ,  G02F1/133711 ,  G02F1/133719 ,  G02F1/13378 ,  G02F1/133784 ,  G02F1/133788 ,  G02F2001/133796 ,  G02F2202/027 ,  H01B1/12 ,  H01B1/125 ,  H01B1/127 ,  H01L51/0012 ,  H01L51/0075 ,  H01L51/0508 ,  H01L51/0595 ,  H01L51/42 ,  H01L51/428 ,  Y02E10/549 ,  Y02P70/521 ,  Y10S428/91 ,  Y10T428/10 ,  Y10T428/1005 ,  Y10T428/1014 ,  Y10T428/31663

Abstract: A conductive organic thin film which is made up of organic molecules each having at one end a terminal bonding group bonded to a substrate surface by covalent bonding and having a conjugated bond group which is present anywhere in the organic molecule and has been polymerized with other molecules and a polar functional group which contains no active hydrogen atom and is present anywhere between the terminal bonding group and the conjugated bond group, the organic molecules being oriented and the conjugated bond groups having been polymerized to form a polymer and a conductive network. The conductive organic thin film in an undoped state has a conductivity ( rho ) as measured at room temperature (25 DEG C) of 5.5x10 S/cm or higher, preferably 1x10 S/cm or higher. It has a far higher conductivity than metals such as gold and silver. In particular, a polypyrrole or polythienylene film formed by electrolytic oxidative polymerization and based on conjugated bonds has a high conductivity.

Abstract translation: 一种导电有机薄膜，其由有机分子组成，每个有机分子的一端具有通过共价键键合到基底表面的末端键合基团，并且具有存在于有机分子中任何地方并与其它分子聚合的共轭键基团 和不含活性氢原子的极性官能团，并且存在于末端键合基团和共轭键基团之间的任何位置，有机分子被取向并且共轭键基团已被聚合以形成聚合物和导电网络。 未掺杂状态的导电有机薄膜的室温（25℃）测得的电导率（rho）为5.5×10 5 S / cm以上，优选为1×10 7 S / cm以上。 它具有比诸如金和银的金属更高的导电性。 特别是，通过电解氧化聚合形成的基于共轭键的聚吡咯或聚噻吩基膜具有高导电性。

公开(公告)号：WO0105840A3

公开(公告)日：2001-07-19

申请号：PCT/ES0000260

申请日：2000-07-19

Applicant: UNIV VALENCIA POLITECNICA ,  ALVARO RODRIGUEZ MERCEDES ,  GARCIA GOMEZ HERMENEGILDO ,  GILBERT ANDREW ,  CARDIN DAVID

Inventor： ALVARO RODRIGUEZ MERCEDES ,  GARCIA GOMEZ HERMENEGILDO ,  GILBERT ANDREW ,  CARDIN DAVID

IPC: H01B1/12 ,  H01M4/137 ,  H01M4/60 ,  C08F38/02

CPC classification number: H01M4/137 ,  H01B1/124 ,  H01B1/125 ,  H01M4/604

Abstract: Material useful as electric conductor comprising a conductor polymer incorporated into channels within a porous support, wherein the polymer is polyacetylene or a polyacetylene derivative, the polymer being formed by polymerization of acetylenic monomer vapors which have been previously adsorbed in channels which are free of support structure director agent and which provide encapsulation of the polymer thereby protecting the polymer against oxidation by environmental oxygen; the support is a modified mesoporous aluminosilicate which has an average pore diameter between 2 nm and 100 nm such as hexagonal phase aluminosilicate of the type MCM-41 or cubic phase aluminosilicate of the type MCM-48. There is also disclosed a process for the preparation of such material and conductor materials, for example electrodes for batteries and conductor surfaces comprising such materials.

Abstract translation: 可用作电导体的材料，其包含掺入到多孔载体内的通道中的导体聚合物，其中所述聚合物是聚乙炔或聚乙炔衍生物，所述聚合物通过先前吸附在不含支撑结构的通道中的炔属单体蒸气聚合而形成 并且提供聚合物的封装，从而保护聚合物免受环境氧的氧化; 载体是具有2nm和100nm之间的平均孔径的改性介孔硅铝酸盐，例如MCM-41型六方相铝硅酸盐或MCM-48型立方相硅铝酸盐。 还公开了用于制备这种材料和导体材料的方法，例如用于电池的电极和包括这种材料的导体表面。

公开(公告)号：WO98049690A1

公开(公告)日：1998-11-05

申请号：PCT/DE1998/001188

申请日：1998-04-29

IPC: C08F38/00 ,  C08K5/18 ,  C08L23/06 ,  C08L49/00 ,  H01B1/12 ,  C08F38/02

CPC classification number: H01B1/125 ,  C08F38/00 ,  C08K5/18 ,  C08L23/06 ,  C08L49/00

Abstract: The invention relates to permanently electrically conductive plastic made from a doped copolymer with 1-hexine and phenyl acetylene or pure poly-(1-hexine).

Abstract translation: 永久导电塑料从1-己炔和苯基乙炔或纯聚（1-己炔）的掺杂共聚物。

公开(公告)号：WO1997018944A1

公开(公告)日：1997-05-29

申请号：PCT/US1996018665

申请日：1996-11-22

Applicant: THE GOVERNMENT OF THE UNITED STATES OF AMERICA, represented by THE SECRETARY OF THE NAVY

Inventor： THE GOVERNMENT OF THE UNITED STATES OF AMERICA, represented by THE SECRETARY OF THE NAVY ,  CALVERT, Jeffrey, M. ,  SHASHIDHAR, Ranganathan ,  VARGO, Terrence, G. ,  CHEN, Mu-San

IPC: B32B03/00

CPC classification number: H05K3/02 ,  G02F1/133305 ,  G02F1/13439 ,  G03F7/00 ,  G03F7/0007 ,  H01B1/125 ,  H01B1/127 ,  H01B1/128 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13

Abstract: Patterned conducting polymer surfaces exhibiting excellent properties may be prepared by: (a) forming a surface of a conducting polymer on a surface of a substrate; (b) forming a surface of a blocking material on the surface of the conducting polymer in a patternwise fashion, to obtain a first patterned surface containing regions of exposed conducting polymer and regions of blocking material; (c) treating the first patterned surface with an agent which: (i) removes the conducting polymer from the regions of exposed conducting polymer; (ii) decreases the conductivity of the conducting polymer in the regions of exposed polymer; or (iii) increases the conductivity of the conducting polymer in the regions of exposed conducting polymer; and (d) removing the blocking material to obtain a second patterned surface containing an exposed pattern of conducting polymer.

Abstract translation: 表现出优异性能的图案化的导电聚合物表面可以通过以下步骤制备：（a）在基材的表面上形成导电聚合物的表面; （b）以图案方式在导电聚合物的表面上形成阻挡材料的表面，以获得含有暴露的导电聚合物区域和阻挡材料区域的第一图案化表面; （c）用试剂处理第一图案化表面：（i）从暴露的导电聚合物的区域去除导电聚合物; （ii）降低暴露聚合物区域中导电聚合物的导电性; 或（iii）增加导电聚合物在暴露的导电聚合物区域中的导电性; 和（d）去除阻挡材料以获得包含暴露的导电聚合物图案的第二图案化表面。

公开(公告)号：WO1995027288A1

公开(公告)日：1995-10-12

申请号：PCT/FR1994000366

申请日：1994-03-31

Applicant: PERTHUISOT, Olivier ,  PATTERN'O ,  TOMI, Pierre ,  VISKOV, Christian ,  PERICHAUD, Alain

Inventor： PERTHUISOT, Olivier ,  PATTERN'O

IPC: H01B01/12

CPC classification number: H05K9/0083 ,  C08F8/20 ,  C08F8/26 ,  C08F8/34 ,  C08F2810/20 ,  C08F2810/30 ,  H01B1/125 ,  H01B1/127 ,  H05B6/6402 ,  C08F114/06

Abstract: An electrically conductive plastic comprising dehydrochlorinated polyvinyl chloride functionalised by at least one aromatic compound with a structure imparting high conductivity in two spatial directions to the plastic. The aromatic compound may be sulphurised, e.g. selected from thiophene, thiazole, thiophenol and benzothiophene. The invention is useful in the field of plastics manufacturing.

Abstract translation: 一种导电塑料，其包含由至少一种芳族化合物官能化的脱氯化氯化聚氯乙烯，所述芳族化合物具有向塑料两个空间方向赋予高导电性的结构。 芳族化合物可以被硫化，例如 选自噻吩，噻唑，苯硫酚和苯并噻吩。 本发明在塑料制造领域是有用的。

公开(公告)号：WO1991013680A1

公开(公告)日：1991-09-19

申请号：PCT/JP1991000333

申请日：1991-03-12

Applicant: EBARA CORPORATION ,  JAPAN as represented by DIRECTOR GENERAL OF ... ,  YABE, Akira; ,  NIINO, Hiroyuki; ,  SHIMOYAMA, Masashi

Inventor： EBARA CORPORATION ,  JAPAN as represented by DIRECTOR GENERAL OF ...

IPC: B01J19/12

CPC classification number: B29C70/882 ,  B01J19/121 ,  B01J19/122 ,  B29C59/16 ,  B29C2035/0838 ,  B29K2027/06 ,  B29K2027/08 ,  B29K2995/0005 ,  H01B1/125

Abstract: A thin electroconductive film is formed by irradiating a shaped article of chlorinated vinyl polymer (1) with a pulsed light (7) having a pulse duration of not greater than 100 nsec., a fluence of above about 15mJ/cm /pulse and below that at which the polymer is subject to ablation, a wavelength of from about 190 to about 300 nm, and repetition rate of above about 1 Hz and below that at which the polymer is subject to deformation and/or decomposition by a thermal effect, under vacuum or in an oxygen-free atmosphere (5) thereby irradiating the article with total photon numbers of at least 1 x 10 /cm without substantially causing photo-crosslinking, oxidation or cleavage of the backbone chain. The invention does not use materials other than the starting polymer such as solvents or strong bases that can contaminate the thin film during a dehydrochlorination, so there is no need to remove solvents after reaction and no residual salts will be formed in the dehydrochlorination.

Abstract translation: 通过用脉冲持续时间不大于100nsec的脉冲光（7）照射氯化乙烯基聚合物（1）的成形制品，高于约15mJ / cm 2 /脉冲的注量而形成薄的导电膜 低于聚合物可以消融的波长，波长为约190nm至约300nm，重复率高于约1Hz，低于聚合物通过热效应而变形和/或分解的重复率 在真空下或在无氧气氛（5）中，从而以至少1×10 18 / cm 2的总光子数照射物品，而基本上不引起主链的光交联，氧化或裂解。 本发明不使用起始聚合物以外的材料，例如在脱氯化氢中可能污染薄膜的溶剂或强碱，因此在反应后不需要除去溶剂，在脱氯化氢中不会形成残留的盐。

公开(公告)号：WO2016070880A1

公开(公告)日：2016-05-12

申请号：PCT/DK2015/050308

申请日：2015-10-09

Applicant: NKT CABLES GROUP A/S

Inventor： EFRAIMSSON, Lars ,  HAGMAN, Lars Ingvar ,  HANSSON, Ivars Lars Sune ,  ANDERSSON, Hans Christian ,  GLEICH, Dietmar ,  GATU, Anders Jonas ,  ASMOLA, Tommy K. Valdemar

IPC: H01B1/02 ,  H01B1/12

CPC classification number: H01B1/023 ,  C08L23/12 ,  C08L23/16 ,  C08L2203/202 ,  C08L2205/02 ,  H01B1/125 ,  H01B9/008 ,  H01R4/66 ,  H02G13/40

Abstract: The invention relates to a grounding conductor and an electrical system comprising such a grounding conductor (100) comprising a plurality of conductive aluminium strands (120) where each such strand is provided with at least one sheath (140) of an electrically conductive polymer material having a volume resistivity (ρ) below 100 Ω⋅cm. Elected for publication.

Abstract translation: 本发明涉及一种接地导体和电气系统，其包括这样的接地导体（100），该接地导体包括多个导电铝绞线（120），其中每个这样的绞线设置有导电聚合物材料的至少一个护套（140） 体积电阻率（ρ）低于100Ω·cm。 当选出版