POLYMERIZATION PROCESS AND REACTOR FOR CONTROLLING MOLECULAR WEIGHT DISTRIBUTION AND COMONOMER COMPOSITION DISTRIBUTION

    公开(公告)号:WO2021122992A1

    公开(公告)日:2021-06-24

    申请号:PCT/EP2020/086768

    申请日:2020-12-17

    Applicant: BOREALIS AG

    Abstract: A reactor for the polymerization of olefins comprising a first inlet for introducing a first stream comprising monomer(s), catalyst(s) and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof, at least one outlet for withdrawing a product stream, characterized in that the reactor further comprises at least one second inlet for introducing a second stream comprising monomer(s), catalyst(s) and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof; and a process for polymerizing olefins in a reactor according to the present invention, comprising the steps of introducing monomer(s), catalyst(s), and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof as the first stream via the first inlet into the reactor forming a reaction mixture; polymerizing a polymer from the reaction mixture; withdrawing the product stream via the at least one outlet from the reactor; characterized in that the process comprises a further step of introducing a second stream comprising monomer(s), catalyst(s), and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof into the reactor via the at least one second inlet into the reactor.

    PROPYLENE COMPOSITION FOR FOAMING WITH IMPROVED MECHANICAL PROPERTIES

    公开(公告)号:WO2021104836A1

    公开(公告)日:2021-06-03

    申请号:PCT/EP2020/081415

    申请日:2020-11-09

    Applicant: BOREALIS AG

    Abstract: A polypropylene composition (C) comprising: i) from 55.0 to 95.0 wt.-% of a heterophasic propylene copolymer (HECO), ii) from 5.0 to 45.0 wt.-% of a copolymer (CP), preferably a random copolymer, of propylene and at least one comonomer selected from the group of C4-C10 alpha-olefins that has been synthesized in the presence of a single-site catalyst, wherein the polypropylene composition (C) has a melt flow rate MFR2 of from 1.0 to 30.0 g/10 min, and wherein the polypropylene composition (C) has a Charpy Notched Impact Strength NIS of greater than or equal to 16.0 kJ/m2.

    MIXED-PLASTIC POLYETHYLENE BLEND
    48.
    发明申请

    公开(公告)号:WO2021064127A1

    公开(公告)日:2021-04-08

    申请号:PCT/EP2020/077569

    申请日:2020-10-01

    Applicant: BOREALIS AG

    Abstract: A process for providing a mixed-plastic-polyethylene product blend having a melt flow rate of 0.1 to 0.45 g/10 min (ISO 1133, 2.16 kg load, 190°C), more preferably of from 0.2 to 0.45 g/10 min, from a mixed-plastic-polyethylene primary blend originating from 90 to 100 wt.-% from a waste stream, the process comprising: a) providing a mixed-plastic-polyethylene primary blend originating from 90 to 100 wt.-% from a waste stream having a melt flow rate (ISO 1133, 2.16 kg load, 190°C) of 0.50 to 1.4 g/10min and having a content of units derived from ethylene of 80 to 95 wt.-% as determined by quantitative 13C{1H}-NMR, b) providing a virgin high-density polyethylene (HDPE) having a melt flow rate (ISO 1133, 5.0 kg load, 190°C) within a range of from 0.001 up to 0.50 g/10 min, preferably within a range of from 0.001 up to 0.30 g/10 min, and having a density of from 945 to 958 kg/m³ c) melt compounding the mixed-plastic-polyethylene primary blend with 2.0 to 20 wt.-% of the virgin high-density polyethylene (HDPE) in an extruder with a screw speed of from 100 to 400 rpm and at a barrel temperature set in the range from 150°C to 250°C, thereby yielding the mixed-plastic-polyethylene product blend

    ZIEGLER-NATTA CATALYSTS FOR OLEFIN POLYMERIZATION

    公开(公告)号:WO2021064080A1

    公开(公告)日:2021-04-08

    申请号:PCT/EP2020/077471

    申请日:2020-10-01

    Applicant: BOREALIS AG

    Abstract: The present invention relates to substituted 2-isopropyl-1,3-dialkoxypropanes, and more particularly to their use as internal donors in Ziegler-Natta catalysts to obtain ethylene (co)polymers with desirable properties The present disclosure further concerns use of Ziegler-Natta catalyst components comprising said substituted 2-isopropyl-1,3- dimethoxypropanes and use of Ziegler-Natta catalysts in ethylene (co)polymerization comprising said Ziegler-Natta catalyst components.

    ZIEGLER-NATTA CATALYSTS FOR OLEFIN POLYMERIZATION

    公开(公告)号:WO2021064078A1

    公开(公告)日:2021-04-08

    申请号:PCT/EP2020/077468

    申请日:2020-10-01

    Applicant: BOREALIS AG

    Abstract: The present invention relates to optionally substituted 1,3-dimethoxypropanes and 3- methoxypropylamines, and more particularly to their use as internal donors in Ziegler-Natta catalysts to obtain polymers with desirable properties. The present disclosure further concerns Ziegler-Natta catalyst components comprising said optionally substituted 1,3- dimethoxypropanes and 3-methoxypropylamines, and Ziegler-Natta catalysts for olefin polymerization comprising said Ziegler-Natta catalyst components, as well as a method for preparing the same and their use in providing polyolefins.

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